Probabilistic Phase Space Trajectory Description for Anomalous Polymer Dynamics

It has been recently shown that the phase space trajectories for the anomalous dynamics of a tagged monomer of a polymer --- for single polymeric systems such as phantom Rouse, self-avoiding Rouse, Zimm, reptation, and translocation through a narrow pore in a membrane; as well as for many-polymeric system such as polymer melts in the entangled regime --- is robustly described by the Generalized Langevin Equation (GLE). Here I show that the probability distribution of phase space trajectories for all these classical anomalous dynamics for single polymers is that of a fractional Brownian motion (fBm), while the dynamics for polymer melts between the entangled regime and the eventual diffusive regime exhibits small, but systematic deviations from that of a fBm.Comment: 8 pages, two figures, 3 eps figure files, minor changes, supplementary material included moved to the appendix, references expanded, to appear in J. Phys.: Condens. Matte

Pore-blockade Times for Field-Driven Polymer Translocation

We study pore blockade times for a translocating polymer of length $N$, driven by a field $E$ across the pore in three dimensions. The polymer performs Rouse dynamics, i.e., we consider polymer dynamics in the absence of hydrodynamical interactions. We find that the typical time the pore remains blocked during a translocation event scales as $\sim N^{(1+2\nu)/(1+\nu)}/E$, where $\nu\simeq0.588$ is the Flory exponent for the polymer. In line with our previous work, we show that this scaling behaviour stems from the polymer dynamics at the immediate vicinity of the pore -- in particular, the memory effects in the polymer chain tension imbalance across the pore. This result, along with the numerical results by several other groups, violates the lower bound $\sim N^{1+\nu}/E$ suggested earlier in the literature. We discuss why this lower bound is incorrect and show, based on conservation of energy, that the correct lower bound for the pore-blockade time for field-driven translocation is given by $\eta N^{2\nu}/E$, where $\eta$ is the viscosity of the medium surrounding the polymer.Comment: 14 pages, 6 figures, slightly shorter than the previous version; to appear in J. Phys.: Cond. Ma

An Elementary Proof of Lyapunov Exponent Pairing for Hard-Sphere Systems at Constant Kinetic Energy

The conjugate pairing of Lyapunov exponents for a field-driven system with smooth inter-particle interaction at constant total kinetic energy was first proved by Dettmann and Morriss [Phys. Rev. E {\bf 53}, R5545 (1996)] using simple methods of geometry. Their proof was extended to systems interacting via hard-core inter-particle potentials by Wojtkowski and Liverani [Comm. Math. Phys. {\bf 194}, 47 (1998)], using more sophisticated methods. Another, and somewhat more direct version of the proof for hard-sphere systems has been provided by Ruelle [J. Stat. Phys. {\bf 95}, 393 (1999)]. However, these approaches for hard-sphere systems are somewhat difficult to follow. In this paper, a proof of the pairing of Lyapunov exponents for hard-sphere systems at constant kinetic energy is presented, based on a very simple explicit geometric construction, similar to that of Ruelle. Generalizations of this construction to higher dimensions and arbitrary shapes of scatterers or particles are trivial. This construction also works for hard-sphere systems in an external field with a Nos\'e-Hoover thermostat. However, there are situations of physical interest, where these proofs of conjugate pairing rule for systems interacting via hard-core inter-particle potentials break down.Comment: 16 pages, 4 figures, to appear in J. Stat. Phy

Fluctuating Fronts as Correlated Extreme Value Problems: An Example of Gaussian Statistics

In this paper, we view fluctuating fronts made of particles on a one-dimensional lattice as an extreme value problem. The idea is to denote the configuration for a single front realization at time $t$ by the set of co-ordinates $\{k_i(t)\}\equiv[k_1(t),k_2(t),...,k_{N(t)}(t)]$ of the constituent particles, where $N(t)$ is the total number of particles in that realization at time $t$. When $\{k_i(t)\}$ are arranged in the ascending order of magnitudes, the instantaneous front position can be denoted by the location of the rightmost particle, i.e., by the extremal value $k_f(t)=\text{max}[k_1(t),k_2(t),...,k_{N(t)}(t)]$. Due to interparticle interactions, $\{k_i(t)\}$ at two different times for a single front realization are naturally not independent of each other, and thus the probability distribution $P_{k_f}(t)$ [based on an ensemble of such front realizations] describes extreme value statistics for a set of correlated random variables. In view of the fact that exact results for correlated extreme value statistics are rather rare, here we show that for a fermionic front model in a reaction-diffusion system, $P_{k_f}(t)$ is Gaussian. In a bosonic front model however, we observe small deviations from the Gaussian.Comment: 6 pages, 3 figures, miniscule changes on the previous version, to appear in Phys. Rev.

Front Propagation and Diffusion in the A <--> A + A Hard-core Reaction on a Chain

We study front propagation and diffusion in the reaction-diffusion system A $\leftrightharpoons$ A + A on a lattice. On each lattice site at most one A particle is allowed at any time. In this paper, we analyze the problem in the full range of parameter space, keeping the discrete nature of the lattice and the particles intact. Our analysis of the stochastic dynamics of the foremost occupied lattice site yields simple expressions for the front speed and the front diffusion coefficient which are in excellent agreement with simulation results.Comment: 5 pages, 5 figures, to appear in Phys. Rev.

Long-time-tail Effects on Lyapunov Exponents of a Random, Two-dimensional Field-driven Lorentz Gas

We study the Lyapunov exponents for a moving, charged particle in a two-dimensional Lorentz gas with randomly placed, non-overlapping hard disk scatterers placed in a thermostatted electric field, $\vec{E}$. The low density values of the Lyapunov exponents have been calculated with the use of an extended Lorentz-Boltzmann equation. In this paper we develop a method to extend these results to higher density, using the BBGKY hierarchy equations and extending them to include the additional variables needed for calculation of Lyapunov exponents. We then consider the effects of correlated collision sequences, due to the so-called ring events, on the Lyapunov exponents. For small values of the applied electric field, the ring terms lead to non-analytic, field dependent, contributions to both the positive and negative Lyapunov exponents which are of the form ${\tilde{\epsilon}}^{2} \ln\tilde{\epsilon}$, where $\tilde{\epsilon}$ is a dimensionless parameter proportional to the strength of the applied field. We show that these non-analytic terms can be understood as resulting from the change in the collision frequency from its equilibrium value, due to the presence of the thermostatted field, and that the collision frequency also contains such non-analytic terms.Comment: 45 pages, 4 figures, to appear in J. Stat. Phy

Asymptotic Scaling of the Diffusion Coefficient of Fluctuating "Pulled" Fronts

We present a (heuristic) theoretical derivation for the scaling of the diffusion coefficient $D_f$ for fluctuating ``pulled'' fronts. In agreement with earlier numerical simulations, we find that as $N\to\infty$, $D_f$ approaches zero as $1/\ln^3N$, where $N$ is the average number of particles per correlation volume in the stable phase of the front. This behaviour of $D_f$ stems from the shape fluctuations at the very tip of the front, and is independent of the microscopic model.Comment: Some minor algebra corrected, to appear in Rapid Comm., Phys. Rev.

Field dependent collision frequency of the two-dimensional driven random Lorentz gas

In the field-driven, thermostatted Lorentz gas the collision frequency increases with the magnitude of the applied field due to long-time correlations. We study this effect with computer simulations and confirm the presence of non-analytic terms in the field dependence of the collision frequency as predicted by kinetic theory.Comment: 6 pages, 2 figures. Submitted to Phys. Rev.

Validity of the Brunet-Derrida formula for the speed of pulled fronts with a cutoff

We establish rigorous upper and lower bounds for the speed of pulled fronts with a cutoff. We show that the Brunet-Derrida formula corresponds to the leading order expansion in the cut-off parameter of both the upper and lower bounds. For sufficiently large cut-off parameter the Brunet-Derrida formula lies outside the allowed band determined from the bounds. If nonlinearities are neglected the upper and lower bounds coincide and are the exact linear speed for all values of the cut-off parameter.Comment: 8 pages, 3 figure