On the exceptional damage-tolerance of gradient metallic materials

An experimental study is described on the fracture toughness and micro-mechanisms associated with the initiation and propagation of cracks in metallic nickel containing marked gradients in grain size, ranging from ∼30 nm to ∼4 μm. Specifically, cracks are grown in a gradient structured (GS) nickel with grain-size gradient ranging from the coarse macro-scale to nano-scale (CG → NG) and vice versa (NG → CG), with the measured crack-resistance R-curves compared to the corresponding behavior in uniform nano-grained (NG) and coarse-grained (CG) materials. It is found that the gradient structures display a much-improved combination of high strength and toughness compared to uniform grain-sized materials. However, based on J-integral measurements in the gradient materials, the crack-initiation toughness is far higher for cracks grown in the direction of the coarse-to-nano grained gradient than vice versa, a result which we ascribe primarily to excessive crack-tip blunting in the coarse-grained microstructure. Both gradient structures, however, display marked rising R-curve behavior with exceptional crack-growth toughnesses exceeding 200 MPa.m½

Comparison of Proanthocyanidins with Different Polymerisation Degrees among Berry Skins of ‘Shiraz’, ‘Cabernet Sauvignon’, and ‘Marselan’

Proanthocyanidins in grape berries are synthesised mainly before véraison, and very little attention ispaid to the evolution of proanthocyanidins (PAs) in grapes from véraison to harvest. The present studyfocused on the changes of flavan-3-ols with different degrees of polymerisation in grape skins and thedifference in proanthocyandin composition of ‘Shiraz’, ‘Cabernet Sauvignon’ and ‘Marselan’ grapes (Vitisvinifera L.). The results show that the content of flavan-3-ols, the percentage of prodelphinidins (%P)and mean degree polymerisation (mDP) found in ‘Cabernet Sauvignon’ berry skins at post-véraison werehigher than those in ‘Shiraz’ and ‘Marselan’ skins. Only monomeric, dimeric, trimeric and polymericflavan-3-ols were detected in the three grape cultivars. Polymers with more than tenfold flavan-3-ol unitsaccounted for a relatively high proportion in grape berry skins, and the content in the three cultivarsdeclined continuously during ripening. Principal component analysis showed that proanthocyanidincontent, composition and mDP at grape harvest stage depended strongly on grape cultivar. This studyprovides some useful information for understanding the accumulation of PAs during berry maturationand this information can be used to improve wine quality

Planar model system of the Phillips (Cr/SiO₂) catalyst based on a well-defined thin silicate film

The Phillips catalyst (Cr/SiO2) is successfully used in the large-scale production of polyethylene and has attracted a great interest in catalytic community over the last sixty years. However, the atomic structure of the active site(s) and the reaction mechanism remain controversial, in particular due to the structural complexity and surface heterogeneity of the amorphous silica. In this work, we used a well-defined, atomically flat silicate bilayer film grown on Ru(0001) as a support offering the opportunity to investigate mechanistic aspects at the atomic scale. To fabricate a planar Cr/SiO2 model system suitable for surface science studies, chromium was deposited using physical vapor deposition onto the hydroxylated silica film surface. Structural characterization and adsorption studies were performed by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD). Hydroxyls groups seem to serve as anchoring cites to Cr ad-atoms. As monitored by IRAS, hydroxyls consumption correlated with the appearance of the new band at ~1007 cm-1 typical for Cr=O vibrations. In addition, CO titration experiments suggested also the presence of "naked" Cr, which transforms into mono- and di-oxo chromyl species and their aggregation upon oxidation treatments. TPD experiments of ethylene adsorption at low temperatures under UHV conditions showed the formation of butane as one of the main products. The resultant surfaces are thermally stable, at least, up to 400 K which allows to investigate ethylene polymerization further under more realistic conditions

A Note on Gauss-Bonnet Holographic Superconductors

We present an analytic treatment near the phase transition for the critical temperature of (3+1)-dimensional holographic superconductors in Einstein-Gauss-Bonnet gravity with backreaction. We find that the backreaction makes the critical temperature of the superconductor decrease and condensation harder. This is consistent with previous numerical results.Comment: 6 pages, typos corrected, references added, published versio

Analytic study of Gauss-Bonnet holographic superconductors in Born-Infeld electrodynamics

Using Sturm-Liouville (SL) eigenvalue problem, we investigate several properties of holographic s-wave superconductors in Gauss-Bonnet gravity with Born-Infeld electrodynamics in the probe limit. Our analytic scheme has been found to be in good agreement with the numerical results. From our analysis it is quite evident that the scalar hair formation at low temperatures is indeed affected by both the Gauss-Bonnet as well as the Born-Infeld coupling parameters. We also compute the critical exponent associated with the condensation near the critical temperature. The value of the critical exponent thus obtained indeed suggests a universal mean field behavior.Comment: 9 pages, Latex, minor modifications, To appear in JHE

ACO-RR: Ant Colony Optimization Ridge Regression in Reuse of Smart City System

© 2019, Springer Nature Switzerland AG. With the rapid development of artificial intelligence, governments of different countries have been focusing on building smart cities. To build a smart city is a system construction process which not only requires a lot of human and material resources, but also takes a long period of time. Due to the lack of enough human and material resources, it is a key challenge for lots of small and medium-sized cities to develop the intelligent construction, compared with the large cities with abundant resources. Reusing the existing smart city system to assist the intelligent construction of the small and medium-sizes cities is a reasonable way to solve this challenge. Following this idea, we propose a model of Ant Colony Optimization Ridge Regression (ACO-RR), which is a smart city evaluation method based on the ridge regression. The model helps small and medium-sized cities to select and reuse the existing smart city systems according to their personalized characteristics from different successful stories. Furthermore, the proposed model tackles the limitation of ridge parameters’ selection affecting the stability and generalization ability, because the parameters of the traditional ridge regression is manually random selected. To evaluate our model performance, we conduct experiments on real-world smart city data set. The experimental results demonstrate that our model outperforms the baseline methods, such as support vector machine and neural network

Object Picture of Quasinormal Modes for Stringy Black Holes

We study the quasinormal modes (QNMs) for stringy black holes. By using numerical calculation, the relations between the QNMs and the parameters of black holes are minutely shown. For (1+1)-dimensional stringy black hole, the real part of the quasinormal frequency increases and the imaginary part of the quasinormal frequency decreases as the mass of the black hole increases. Furthermore, the dependence of the QNMs on the charge of the black hole and the flatness parameter is also illustrated. For (1+3)-dimensional stringy black hole, increasing either the event horizon or the multipole index, the real part of the quasinormal frequency decreases. The imaginary part of the quasinormal frequency increases no matter whether the event horizon is increased or the multipole index is decreased.Comment: 4 pages, 5 figure