Very long distance connection of gigawatt size offshore wind farms: extra high-voltage ac versus high-voltage dc cost comparison

This study presents a cost comparison between commercially available high-voltage DC (HVDC) and extra high-voltage AC shore connection (±320 kV voltage source converter and 420 kV-50 Hz single-core and three-core cables), for a 1 GW offshore wind farm cluster, considering transmission distances up to 400 km. The HVDC system is a point-to-point connection whereas multiple AC intermediate compensating stations are envisaged for AC when needed. Capital costs are evaluated from recently awarded contracts, operating costs include energy losses and missed revenues due to transmission system unavailability, both estimated using North Sea wind production curves. Optimal AC intermediate compensation, if any, and reactive profiles are also taken into account. Resultsshow that HVDC has lower transmission losses at distances in excess of 130 km; however, due to the combined effect of lower AC capital cost and unavailability, using three-core aluminium cables can be more convenient up to 360 km distance

Exploiting the potential of chemical looping processes for industrial decarbonization and waste to energy conversion. Process design and experimental evaluations

The impact of anthropogenic activities on the environment is leading to climate changes and exceptional meteorological phenomena all over the world. To address this negative trend, the scientific community agrees that the environmental impact from fossil fuels-based power production must be mitigated by the integration with alternative and sustainable technologies, such as renewable energy. However, the time required for the complete development and diffusion of such technology poses the urgency of finding a midterm solution to significantly reduce CO2 emissions. Carbon capture, utilization, and storage (CCUS) technologies represent an interesting option to mitigate CO2 emissions. CCUS involves (among other possible applications) the separation of the CO2 content from industrial off-gases, its transport and storage or its reconversion to a chemical/fuel. Chemical looping can be considered as an oxyfuel combustion where the oxygen supply comes from the lattice oxygen atoms of a solid. It is based on gas-solid reactions where a solid also known as oxygen carrier, generally a metal oxide, undergoes successive reduction and oxidation steps. In the reduction step, normally occurring at high temperatures (700-1000 °C), the oxygen carrier interacts with a reducing agent, such as coal, natural gas, syngas etc. and loses part of its oxygen atoms. By controlling the degree of reduction of the oxygen carrier is thus possible to achieve a complete oxidation of the reducing agent (the fuel) to CO2 and H2O (chemical looping combustion) or a partial oxidation to a syngas (chemical looping reforming and gasification). In these latter case, the introduction of external CO2 and H2O can be of help to support the reforming or gasification processes. The oxygen carrier in the reduced phase is then sent to an air reactor, where it reacquires the oxygen atoms by an exothermic reaction with air. This process presents several advantages according to the specific application. In chemical looping combustion, intrinsic separation of N2 and CO2 is achieved, because the two streams are involved in two different reaction steps. This largely simplifies the CO2 separation effort for storage or utilization purposes. On the other hand, in chemical looping reforming it is possible to achieve autothermal operation thanks to the exothermicity of the oxidation step in the air reactor, as well as high reforming efficiencies. Similarly, in chemical looping gasification the resulting syngas is characterized by no N2 dilution, lower tar release and possibility of autothermal operation. These benefits enhance the energy efficiency of the process, leading to a better energy utilisation. In this work, strategies for the decarbonisation and circularity of the industrial and power sector are proposed based on the synthesis of hydrogen and hydrogen-derived fuels. In particular, the potential of chemical looping technology is deeply studied aiming at exploiting its ability to reconvert or valorise CO2 or waste streams to a syngas and then to a liquid fuel/chemical, such as methanol or ammonia. This task is carried out through modelling and experimental evaluations. The modelling activities mainly concern design of process schemes involving the chemical looping section for waste or CO2 reconversion and the liquid fuel synthesis section. The experimental evaluations are focused on two crucial that have been limitedly discussed in the literature: the thermochemical syngas production step by oxidation with CO2 and H2O streams, the effect of high-pressure operation on the redox abilities of a typical iron and nickel-based oxygen carrier. In Chapter 1, a general overview on the main research developments on chemical looping technology is provided. A section is reserved for each chemical looping variant, i.e. combustion, reforming and gasification, and a general description of each process is provided along with the summary of the main research achievements. Subsequently, the technology is divided by application in power production and chemicals production. Main findings from techno-economic assessment and process designs are discussed in comparison with benchmark technologies and other clean pathways. In Chapter 2 steel mills are taken as an example of the hard-to-abate industry. A H2-based decarbonization strategy is proposed and assessed by Aspen Plus simulation. The strategy starts from an initial configuration that is characterized by a typical blast furnace-basic oxygen furnace steel mill and consider the introduction of direct reduction – electric arc furnace lines, that are more efficient and involve natural gas as reducing agent rather than coke. Sensitivity analyses are carried out to assess the effect of the introduction of H2/CH4 blendings in the direct reduction plant and of the utilization of scrap material in the electric arc furnace. The impact of each configuration on the CO2 emissions and the energy flows of the plant is assessed by mass and energy balances. The results indicate a promising decarbonization potential of the introduced technologies but require large investments to increase the renewable sources penetration in the energy mix and large availability of H2. Therefore, alternative pathways for an earlier decarbonization of hard-to-abate industries and for large scale syngas/H2 production need to be considered. In Chapter 3, a novel process scheme is proposed involving chemical looping for syngas production. The CO2 content in blast furnace gases is separated with a calcium looping cycle and subsequently injected with H2O into the oxidation reactor of a chemical looping cycle. Assuming an inlet stream of pure CO2, mass balances on the chemical looping plant are carried out to compare the performance of nickel ferrites and iron oxides in terms of required oxygen carrier flow rate to process 1 t/h of CO2. Computational fluid dynamics simulations with integrated reaction kinetics are then carried out to validate the assumptions on the oxygen carrier conversion and syngas compositions. In Chapter 4 and 5, experimental evaluations are carried out on two crucial aspects for the successful operation of a chemical looping plant aiming at syngas production. In Chapter 4, the syngas productivity by CO2 and H2O splitting over a Fe bed is investigated. This is a very important step, and the effect of various parameters was considered. Firstly, the CO2 splitting is analysed for different temperatures with an inlet flow rate of 1 NL/min to ensure a substantial dissociation of the CO2. Subsequently, combined streams of CO2 and H2O are evolved in the reactor. The effect of the total flow rate, reactants molar ratio and bed height is investigated and from the results, the optimal syngas composition is identified. SEM and XRD are used to assess the morphological evolution and the phase changes of the material during the test. On the contrary, in Chapter 5 the effect of high-pressure operation on the redox abilities of two NiFe aluminates is assessed. The aluminates present similar Fe loadings, but different Ni loadings. High pressure operation is crucial for the development of this technology because it facilitates downstream processing of the syngas to liquid fuels. For a comparative analysis, preliminary tests at low pressure are carried out at three temperatures. Subsequently, the effect of reactants flow rate, temperature, total pressure, gas composition is analysed at high pressure conditions. Finally, long term tests are performed both at ambient and high-pressure conditions. Material characterization by SEM, XRD and H2-TPR is used to support the comparative analysis. In Chapter 6, a techno-economic analysis on a process scheme encompassing methanol and ammonia production from chemical looping gases is carried out. Chemical looping hydrogen production is a very versatile technology and allows for the combined production of power and H2 or syngas. With proper calibration of the flow rates, a stream of high purity N2 can also be obtained at the air reactor outlet and used for ammonia synthesis. Back up with an alkaline electrolyser is considered for the supply of the required amount of hydrogen. Sensitivity analyses are carried out on the chemical looping plant to evaluate the effect of fuel flow rate, steam flow rate, and oxygen carrier inlet temperature to the fuel reactor. Subsequently, a techno-economic analysis is carried out evaluating several parameters among which: the specific CO2 emissions, the energy intensity, and the levelized cost of methanol and ammonia. Finally, a comparison with benchmark technologies and other clean alternatives is presented. In this way, the benefits as well as the drawbacks of chemical looping in terms of environmental and economic parameters are assessed and the missing elements to reach industrial competitivity are clarified

Tower grounding improvement versus line surge arresters: comparison of remedial measures for high-BFOR subtransmission lines

This paper presents a technical/economic comparison between remedial measures aimed at improving the lightning performance of an existing Italian three-phase 150-kV overhead line. The line is characterized by a very high back-flashover rate (BFOR), due to large grounding resistance values. Two countermeasures are proposed: grounding system improvement with additional vertical rods and line metal oxide surge arrester (MOSA) installation on one or all phases. A Monte Carlo ATP-EMTP procedure developed by the authors, which takes into account both the tower grounding nonlinear transient response due to soil ionization and MOSA nonlinear response, has been applied to evaluate and compare the effectiveness of the proposed countermeasures. The installation of MOSA on all phases is technically the best option, but it is relatively expensive. Tower grounding improvement and MOSA installation on the lower phase yield very similar BFORs: the economic comparison strongly depends on tower's accessibility and soil nature

Finding the Right Words

In Summer 2021, UCO Chambers Library's catalogers crafted an inclusive metadata statement. Our presentation will provide an overview of the process, recommendations for creating your own statement, and the challenges of important terminology being misappropriated as buzzwords (e.g. "decolonizing" the catalog)N

Mr. J. P. Palone to Mr. Meredith (26 September 1962)

https://egrove.olemiss.edu/mercorr_pro/1272/thumbnail.jp

Drafting the inclusive metadata statement

Offensive/outdated terminology in library cataloging standards has been discussed for some years now, particularly around the subject heading “illegal aliens.” A recent trend in library cataloging and technical services departments has been to create public statements that acknowledging these problems to their communities and actions that have been or will be taken to address offensive/outdated terminology found in our standards. The professional catalogers at the University of Central Oklahoma teamed up in summer 2021 to create such a statement, and this lightning talk will address why we created this statement, how we structured this statement, and our own steps for transforming words into actions.Max Chambers Librar

The Creation of the Tribal Nations of Oklahoma Metadata Database

In the closing discussions of last year's symposium the impromptu creation of the Metadata Justice Collective occurred. Those that volunteered to chair, Megan Macken, Lulu Zilinskas, and Kaitlyn Palone, met shortly thereafter about possible projects that could use collaborative work. Megan presented the idea to create a database of Oklahoma Tribal Nation preferred names. The speakers presented on how this work was accomplished, problems encountered, and plans for future

Comparative Analysis of Stiffness of Lingual Appliances: An in Vitro Study

Objective: To analyze and compare the stiffness of different lingual appliances with different archwires. Material and Methods: The three-point bending test was used to analyze the stiffness of the lingual archwires for the different lingual systems: eBrace, Harmony, Incognito, and STb. The deflection load curve of each archwire was obtained to evaluate how the section, the material and the manufacturer affect the elasticity and stiffness characteristics of the wires. The comparison of the stiffness between different systems was carried out through a factor variance analysis with three factors (manufacturer, cross-section, and material), followed by the post-hoc Tuckey test. Results: An increase in the system's rigidity was reported as the wire section increases, regardless of the manufacturer. The stainless steel archwires have ever higher stiffness values than NiTi and TMA. The STb wires of CuNiTi material, by virtue of the characteristics of the thermal wires, have flatter and lower load-deflection curves than the NiTi wires of other manufacturers. Conclusion: Archwires section and material showed a significant influence on the stiffness of the lingual systems. Archwires of the same section and material but different manufacturers show different load-deflection curves of stiffness