The Upper Cretaceous-Paleogene from the Río Bueno area, Atlantic coast of the Isla Grande de Tierra del Fuego

A composite section, 1400 m thick, is established for the Upper Cretaceous-Paleogene strata in the fold and thrust belt of the Andes Fueguinos, south of 54° 30′S. The basal Policarpo Formation, > 350 m thick, consists of tuffaceous sandstones and bioturbated sandstones and siltstones. The ammonites Maorites densicostatus and Diplomoceras sp.; foraminifera common to the Gaudryina healyi Zone; and the dynocysts Manumiella seelandica and Operculodium cf. azcaratei indicate a Maastrichtian age. The Paleocene to lower Eocene include four new formations. The Cabo Leticia Formation, c.150 m, Paleocene, consists of gravity flows deposits: brecchias; conglomerates; and massive, tuffaceous sandstones. La Barca Formation, c. 220 m, includes two members: LB1, tuffaceous sandstones and intercalated carbonaceous siltstones; and LB2, black mudstones with Palaeocystodinium golzowense and Spiroplectammina spectabilis. P. golzowense and the Bulimina karpatica Assemblage in LB1 indicate a late Paleocene age. Punta Noguera Formation, 380 m, is dominated by glauconite rich, massive, tuffaceous sandstones with interbedded turbidite packages. The dynocyst group Apectodinium, Deflandrea robusta, Palaeocystodinium sp., and Odontodinium askinae; the foraminifera Alabamina creta, Charltonina acutimarginata, Valvulineria teurensis and the first ocurrence of Elphidium and Cribrorotalia suggest an age near the Paleocene/Eocene boundary. The Cerro Ruperto Formation, 200 m, is dominated by glauconite rich, silty very fine sandstones and siltstones; dominance of Deflandrea dartmooria indicate an early Eocene age. Resting on angular unconformity, the Río Bueno Formation, c. 60-80 m, consists of carbonate rocks; its member RB1, rhythmically bedded grainstones, with the planktic foraminifera Planorotalites australiformis and Subbotina linaperta is of early middle Eocene age; and its member RB2, regular alternation of grainstones and bioturbated marls and micrites, with Elphidium saginatum and Bulimina cf. bortonica, is assigned to the mid middle Eocene. The sedimentary and stratigraphic features of the Maastrichtian/Eocene have a strong tectonic control, suggesting that the foreland phase of evolution of the basin has been active at least since the Maastrichtian.Fil:Olivero, E.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Malumián, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Scasso, R.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina

Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)

In this paper, an interdisciplinary investigation was carried out to study if Santa Maria tricolor style vessels were used as culinary equipment in a 14th century ad domestic cooking space in El Colorado (Yocavil valley, Catamarca, Northwest Argentina) and to question the long-established idea that Santa Maria vessels were exclusively funerary objects. The combined use of gas chromatography (GC-FID), gas chromatography–mass spectrometry (GC-MS), and high-performance liquid chromatography coupled to electrospray ionization and quadrupole time-of-flight mass spectrometry (HPLC-ESI-Q-TOF) to study residual lipids from Santa Maria style vessels provided valuable information on their ancient use. Also, an ordinary striated style ceramic pot with distinct visible soot marks, as well as sediments from the cooking area, was studied for comparative purposes. Fatty acid, sterol, and acylglyceride profiles were characterized, and markers of food sources were searched in the complex mixtures. We identified intact triacylglycerides (TAGs) in the archaeological samples, even unsaturated, indicating exceptional preservation of lipids in the ceramic matrixes. Cholesterol or cholesterol oxidation products were observed in all ceramic containers, as well as plant sterols (stigmasterol, sitosterol) in two containers. Markers for ruminant lipids, such as TAGs that contain odd-chain fatty acids, were found, supported by the identification of odd-chain and branched-chain fatty acids with GC-FID and GC-MS. This evidence contributes to the hypothesis that Santa Maria vessels were used for culinary purposes in this archaeological domestic cooking space.Laboratorio de Etnobotánica y Botánica Aplicad

Special Issue on on Non-destructive Techniques for Cultural Heritage

Proceedings of the symposium \u201cNon-Destructive Techniques for Cultural Heritage\u201d held in Buenos Aires on the 12th of October 2018 with special focus on the study and preservation of Cultural Heritage (CH)