Tracing the origin of oxide inclusions in continuously casted steel using stable oxygen isotopes : An interdisciplinary approach

A detailed mineralogical, chemical, and isotope study was conducted on refractories and slags used in the continuous casting steelmaking process. The aim of this study was to trace the origin of non-metallic inclusions and SEN-precipitates (clogging) in continuously casted steels. It was especially focussed on the thermochemical behaviour of basic sprayable disposable tundish lining, which are composed of forsteritic olivine and periclase. The results of the mineralogical study clearly indicated that the fayalite component of the forsteritic olivine is reduced to iron metal. Ferrous iron is substituted by Mg 0 , which is released by evaporation of periclase at high temperatures and reducing conditions. The periclase evaporating reaction also released oxygen gas. The oxygen isotope composition as measured in SEN-precipitates match the isotope composition of the periclase. It was therefore concluded that periclase in conjunction with olivine may be, at least partly, responsible for the formation of non-metallic inclusions in low alloyed, Al-killed, and continuously casted steels. Manganese occured in concentrations up to 1.3 wt.% in the casted steel melts. Mn leaves the steel melt and infiltrates the silica-rich tundish slag as well as the tundish lining. The result are high Mn-concentrations in the tundish slag and the formation of tephroititc olivine in the tundish lining. Spinel forms where tundish slag infiltrated the tundish lining. Corrosion of forsteritic olivine in the tundish lining by slag was never observed, but overgrowths of Mn-rich olvine over forsterite was abundant

Revisiting equilibrium condensation and rocky planet compositions: Introducing the ECCOplanets code

We introduce ECCOplanets, an open-source Python code that simulates condensation in the protoplanetary disk. Our aim is to analyse how well a simplistic model can reproduce the main characteristics of rocky planet formation. For this purpose, we revisited condensation temperatures ($T_c$) as a means to study disk chemistry, and explored their sensitivity to variations in pressure (p) and elemental abundance pattern. We also examined the bulk compositions of rocky planets around chemically diverse stars. Our T-p-dependent chemical equilibrium model is based on a Gibbs free energy minimisation. We derived condensation temperatures for Solar System parameters with a simulation limited to the most common chemical species. We assessed their change ($\Delta T_c$) as a result of p-variation between $10^{-6}$ and 0.1 bar. To analyse the influence of the abundance pattern, key element ratios were varied, and the results were validated using solar neighbourhood stars. To derive the bulk compositions of planets, we explored three different planetary feeding-zone (FZ) models and compared their output to an external n-body simulation. Our model reproduces the external results well in all tests. For common planet-building elements, we derive a Tc that is within $\pm5$ K of literature values, taking a wider spectrum of components into account. The Tc is sensitive to variations in p and the abundance pattern. For most elements, it rises with p and metallicity. The tested pressure range ($10^{-6} - 0.1$ bar) corresponds to $\Delta T_c \approx +350$ K, and for -0.3 $\leq$ [M/H] $\leq$ 0.4 we find $\Delta T_c \approx +100$ K. An increase in C/O from 0.1 to 0.7 results in a decrease of $\Delta T_c \approx -100$ K. Other element ratios are less influential. Dynamic planetary accretion can be emulated well with any FZ model. Their width can be adapted to reproduce gradual changes in planetary composition

Detecting and analysing geomorphological structures in images of comet 67P/Churyumov-Gerasimenko using Fourier transform

We present a method for automatised detection and analysis of quasi-periodic lineament structures from images at pixel-precision. The method exploits properties of the images' frequency domain found by using the Fourier transform. We developed this method with the goal of detecting lineament structures in an image of the Hathor cliff of comet 67P/Churyumov-Gerasimenko, which are caused by layerings and furrows in the nucleus material. Using our method, we determined the orientation and wavelength-range of these structures. The detected layering edges have similar orientations, spatial separations of 9-20 m, and are ubiquitous throughout the image. We suggest that the layerings are a global feature of the comet nucleus that provide information about formation and evolution of comet 67P. The furrows are non-uniformly distributed throughout the image. Their orientation is broadly parallel to the direction of the local gravity vector at the Hathor cliff, with spacings similar to that of the layering structures. The furrows are interpreted as signatures of local down-slope movement of cliff material. We demonstrate that the developed method is broadly applicable to the detection and analysis of various kinds of quasi-periodic structures like geological layering, folding and faulting, and texture analysis in general. In order to facilitate the application of our method, this paper is accompanied by a demo program written in Matlab

Metasomatic Reactions between Archean Dunite and Trondhjemite at the Seqi Olivine Mine in Greenland

A metasomatic zone formed between the contact of a 2940 ± 5 Ma intrusive trondhjemite sheet in the Archean dunite of the Seqi Ultramafic Complex, SW Greenland, consists of three distinct mineral zones dominated by (1) talc, (2) anthophyllite, and (3) phlogopite. These zones supposedly resulted from a process of dissolution of olivine by silica rich fluid residual from the trondhjemite magma, with crystallization of secondary minerals along a compositional gradient in the fluid phase. A zircon crystal inclusion in a large (4 cm) olivine porphyroblast was dated in situ via LA-ICP-MS U–Pb isotope analysis, yielding a weighted mean 207Pb/206Pb age of 2963 ± 1 Ma, which coincides with granulite facies metamorphism and potential dehydration. Considering phase relations appropriate for the dunite composition, we deduced the talc forming conditions to be at temperatures of 600–650 °C and at a pressure below 1 GPa. This is supported by oxygen isotope data for talc, anthophyllite and phlogopite in the metasomatic zone, which suggests formation in the temperature range of 600–700 °C from fluids that had a δ18O of ~8‰ and a Δ’17O0.528 of about −40 ppm, i.e., from fluids that could have been derived from the late stage trondhjemite sheet

Analysis of layering-related linear features on comet 67P/Churyumov-Gerasimenko

We analysed layering-related linear features on the surface of comet 67P/Churyumov-Gerasimenko (67P) to determine the internal configuration of the layerings within the nucleus. We used high-resolution images from the OSIRIS Narrow Angle Camera onboard the Rosetta spacecraft, projected onto the SHAP7 shape model of the nucleus, to map 171 layering-related linear features which we believe to represent terrace margins and strata heads. From these curved lineaments, extending laterally to up to 1925 m, we extrapolated the subsurface layering planes and their normals. We furthermore fitted the lineaments with concentric ellipsoidal shells, which we compared to the established shell model based on planar terrace features. Our analysis confirms that the layerings on the comet's two lobes are independent from each other. Our data is not compatible with 67P's lobes representing fragments of a much larger layered body. The geometry we determined for the layerings on both lobes supports a concentrically layered, `onion-shell' inner structure of the nucleus. For the big lobe, our results are in close agreement with the established model of a largely undisturbed, regular, concentric inner structure following a generally ellipsoidal configuration. For the small lobe, the parameters of our ellipsoidal shells differ significantly from the established model, suggesting that the internal structure of the small lobe cannot be unambiguously modelled by regular, concentric ellipsoids and could have suffered deformational or evolutional influences. A more complex model is required to represent the actual geometry of the layerings in the small lobe

Definition of the term "creativity" in the works of foreign authors

The universal general theory of creativity does not exist. Creativity has been analyzed by scientists for hundreds years. The term "creativity" in translation from Latin (creatio) means "creation". "Creativity" is a process of creative activity of a person. This activity is resultants a new innovative product. Creativity is manifestation of the creator. The creator is the person who induces creative activity. The creator is responsible for the product he has created. The most well- known researchers of "creativity" are J. Guilford (1953) and E. Torrance (1988). Other authors claim that there are three aspects of creativity: person, process and product (N.Aderson (1990), T. Amabile (1998), E.Barron (1981), R.Woodman (1993), N.King (1990), etc.)."Creativity" is an ability of a person to use knowledge, skills and abilities for creation of a product for a short time. Progressive way of development demands product creativity, as it is essential for further success of extension

In search of the Earth-forming reservoir: Mineralogical, chemical, and isotopic characterizations of the ungrouped achondrite NWA 5363/NWA 5400 and selected chondrites

High-precision isotope data of meteorites show that the long-standing notion of a “chondritic uniform reservoir” is not always applicable for describing the isotopic composition of the bulk Earth and other planetary bodies. To mitigate the effects of this “isotopic crisis” and to better understand the genetic relations of meteorites and the Earth-forming reservoir, we performed a comprehensive petrographic, elemental, and multi-isotopic (O, Ca, Ti, Cr, Ni, Mo, Ru, and W) study of the ungrouped achondrites NWA 5363 and NWA 5400, for both of which terrestrial O isotope signatures were previously reported. Also, we obtained isotope data for the chondrites Pillistfer (EL6), Allegan (H6), and Allende (CV3), and compiled available anomaly data for undifferentiated and differentiated meteorites. The chemical compositions of NWA 5363 and NWA 5400 are strikingly similar, except for fluid mobile elements tracing desert weathering. We show that NWA 5363 and NWA 5400 are paired samples from a primitive achondrite parent-body and interpret these rocks as restite assemblages after silicate melt extraction and siderophile element addition. Hafnium-tungsten chronology yields a model age of 2.2 ± 0.8 Myr after CAI, which probably dates both of these events within uncertainty. We confirm the terrestrial O isotope signature of NWA 5363/NWA 5400; however, the discovery of nucleosynthetic anomalies in Ca, Ti, Cr, Mo, and Ru reveals that the NWA5363/NWA 5400 parent-body is not the “missing link” that could explain the composition of the Earth by the mixing of known meteorites. Until this “missing link” or a direct sample of the terrestrial reservoir is identified, guidelines are provided of how to use chondrites for estimating the isotopic composition of the bulk Earth

The Ksar Ghilane 002 shergottite-The 100th registered Martian meteorite fragment

We report on the discovery of a new shergottite from Tunisia, Ksar Ghilane (KG) 002. This single stone, weighing 538 g, is a coarse-grained basaltic shergottite, mainly composed of maskelynitized plagioclase (approximately 52 vol%) and pyroxene (approximately 37 vol%). It also contains Fe-rich olivine (approximately 4.5 vol%), large Ca-phosphates, including both merrillites and Cl-apatites (approximately 3.4 vol%), minor amounts of silica or SiO_2-normative K-rich glass, pyrrhotite, Ti-magnetite, ilmenite, and accessory baddeleyite. The largest crystals of pyroxene and plagioclase reach sizes of approximately 4 to 5 mm. Pyroxenes (Fs_(26–96)En_(5–50)Wo_(2–41)). They typically range from cores of about Fs_(29)En_(41)Wo_(30) to rims of about Fs_(68)En_(14)Wo_(17). Maskelynite is Ab_(41–49)An_(39–58)Or_(1–7) in composition, but some can be as anorthitic as An_(93). Olivine (Fa_(91–96)) occurs mainly within symplectitic intergrowths, in paragenesis with ilmenite, or at neighboring areas of symplectites. KG 002 is heavily shocked (S5) as indicated by mosaic extinction of pyroxenes, maskelynitized plagioclase, the occurrence of localized shock melt glass pockets, and low radiogenic He concentration. Oxygen isotopes confirm that it is a normal member of the SNC suite. KG 002 is slightly depleted in LREE and shows a positive Eu anomaly, providing evidence for complex magma genesis and mantle processes on Mars. Noble gases with a composition thought to be characteristic for Martian interior is a dominant component. Measurements of ^(10)Be, ^(26)Al, and ^(53)Mn and comparison with Monte Carlo calculations of production rates indicate that KG 002 has been exposed to cosmic rays most likely as a single meteoroid body of 35–65 cm radius. KG 002 strongly resembles Los Angeles and NWA 2800 basaltic shergottites in element composition, petrography, and mineral chemistry, suggesting a possible launch-pairing. The similar CRE ages of KG 002 and Los Angeles may suggest an ejection event at approximately 3.0 Ma

The polymict carbonaceous breccia aguas zarcas: A potential analog to samples being returned by the OSIRIS‐REx and hayabusa2 missions

Abstract On April 23, 2019, a meteorite fall occurred in Aguas Zarcas, Costa Rica. According to the Meteoritical Bulletin, Aguas Zarcas is a brecciated CM2 chondrite dominated by two lithologies. Our X‐ray computed tomography (XCT) results show many different lithologies. In this paper, we describe the petrographic and mineralogical investigation of five different lithologies of the Aguas Zarcas meteorite. The bulk oxygen isotope compositions of some lithologies were also measured. The Aguas Zarcas meteorite is a breccia at all scales. From two small fragments, we have noted five main lithologies, including (1) Met‐1: a metal‐rich lithology; (2) Met‐2: a second metal‐rich lithology which is distinct from Met‐1; (3) a brecciated CM lithology with clasts of different petrologic subtypes; (4) a C1/2 lithology; and (5) a C1 lithology. The Met‐1 lithology is a new and unique carbonaceous chondrite which bears similarities to CR and CM chondrite groups, but is distinct from both based on oxygen isotope data. Met‐2 also represents a new type of carbonaceous chondrite, but it is more similar to the CM chondrite group, albeit with a very high abundance of metal. We have noted some similarities between the Met‐1 and Met‐2 lithologies and will explore possible genetic relationships. We have also identified a brecciated CM lithology with two primary components: a chondrule‐poor lithology and a chondrule‐rich lithology showing different petrologic subtypes. The other two lithologies, C1 and C1/2, are very altered and possibly related to the CM chondrite group. In this article, we describe all the lithologies in detail and attempt a classification of each in order to understand the origin and the history of formation of the Aguas Zarcas parent body