Nano-building block based-hybrid organic–inorganic copolymers with self-healing properties

New dynamic materials, that can repair themselves after strong damage, have been designed by hybridization of polymers with structurally well-defined nanobuilding units. The controlled design of cross-linked poly(n-butyl acrylate) (pBuA) has been performed by introducing a very low amount of a specific tin oxo-cluster. Sacrificial domains with non-covalent interactions (i.e. ionic bonds) developed at the hybrid interface play a double role. Such interactions are strong enough to cross-link the polymer, which consequently exhibits rubber-like elasticity behavior and labile enough to enable, after severe mechanical damage, dynamic bond recombination leading to an efficient healing process at room temperature. In agreement with the nature of the reversible links at the hybrid interface, the healing process can speed up considerably with temperature. 1H and 119Sn PFG NMR has been used to evidence the dynamic nature of these peculiar cross-linking nodes

Invertébrés marins du lagon Néo calédonien : 3. Etude structurale de trois nouveaux diterpènes isolés du pennatulaire Cavernulina grandiflora

Three new diterpenes, related to stylatulide but non-balogenated, have been isolated from a new species of sea-pen, Cavernulina grandiflora : cavernuline (1) O-deacetylpropionyl cavernuline (5) and cavernulinine (6). The structures are proposed on the basis of spectral evidence

Measurement and Control of the Beam Energy for the SPIRAL2 Accelerator

WEPF32, http://accelconf.web.cern.ch/AccelConf/ibic2013/International audienceThe first part of the SPIRAL2 facility, which entered last year in the construction phase at GANIL in France, will be composed of an ion source, a deuteron/proton source, a RFQ and a superconducting linear accelerator delivering high intensities, up to 5 mA and 40MeV for the deuteron beams. As part of theMEBT commissioning, the beam energy will be measured on the BTI (Bench of Intermediate Test) at the exit of the RFQ. At the exit of the LINAC, the system has to measure but also control the beam energy. The control consists in ensuring that the beam energy is under a limit by taking account of the measurement uncertainty. The energy is measured by a method of time of flight, the signal is captured by non-intercepting capacitive pick-ups. This paper presents also the results obtained in terms of uncertainties and dynamics of measures

Hodge polynomials of some moduli spaces of Coherent Systems

When $k<n$, we study the coherent systems that come from a BGN extension in which the quotient bundle is strictly semistable. In this case we describe a stratification of the moduli space of coherent systems. We also describe the strata as complements of determinantal varieties and we prove that these are irreducible and smooth. These descriptions allow us to compute the Hodge polynomials of this moduli space in some cases. In particular, we give explicit computations for the cases in which $(n,d,k)=(3,d,1)$ and $d$ is even, obtaining from them the usual Poincar\'e polynomials.Comment: Formerly entitled: "A stratification of some moduli spaces of coherent systems on algebraic curves and their Hodge--Poincar\'e polynomials". The paper has been substantially shorten. Theorem 8.20 has been revised and corrected. Final version accepted for publication in International Journal of Mathematics. arXiv admin note: text overlap with arXiv:math/0407523 by other author