Phonon Linewidths and Electron Phonon Coupling in Nanotubes

We prove that Electron-phonon coupling (EPC) is the major source of broadening for the Raman G and G- peaks in graphite and metallic nanotubes. This allows us to directly measure the optical-phonon EPCs from the G and G- linewidths. The experimental EPCs compare extremely well with those from density functional theory. We show that the EPC explains the difference in the Raman spectra of metallic and semiconducting nanotubes and their dependence on tube diameter. We dismiss the common assignment of the G- peak in metallic nanotubes to a Fano resonance between phonons and plasmons. We assign the G+ and G- peaks to TO (tangential) and LO (axial) modes.Comment: 5 pages, 4 figures (correction in label of fig 3

Interações entre ácido indol butírico, uniconazol e dois tipos de substrato, no enraizamento de estacas caulinares de Sapium glandulatum (Vell Pax (resultados preliminares)).

Organizado por Patrícia Póvoa de Mattos, Celso Garcia Auer, Paulo César Botosso e Rejane Stumpf Sberze

Edge phonons in black phosphorus

Exfoliated black phosphorus has recently emerged as a new two-dimensional crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have potentially important applications in electronics, optoelectronics and photonics. Despite the fact that the edges of layered crystals host a range of singular properties whose characterization and exploitation are of utmost importance for device development, the edges of black phosphorus remain poorly characterized. In this work, the atomic structure and the behavior of phonons near different black phosphorus edges are experimentally and theoretically studied using Raman spectroscopy and density functional theory calculations. Polarized Raman results show the appearance of new modes at the edges of the sample, and their spectra depend on the atomic structure of the edges (zigzag or armchair). Theoretical simulations confirm that the new modes are due to edge phonon states that are forbidden in the bulk, and originated from the lattice termination rearrangements.Comment: 15 pages, 4 figure

Probing the Electronic Structure of Bilayer Graphene by Raman Scattering

The electronic structure of bilayer graphene is investigated from a resonant Raman study using different laser excitation energies. The values of the parameters of the Slonczewski-Weiss-McClure model for graphite are measured experimentally and some of them differ significantly from those reported previously for graphite, specially that associated with the difference of the effective mass of electrons and holes. The splitting of the two TO phonon branches in bilayer graphene is also obtained from the experimental data. Our results have implications for bilayer graphene electronic devices.Comment: 4 pages, 4 figure

Photonic entanglement with accelerated light

Accelerated light has been demonstrated with laser light and diffraction. Within the diffracting field it is possible to identify a portion that carries most of the beam energy, which propagates in a curved trajectory as it would have been accelerated by a gravitational field for instance. Here, we analyze the effects of this kind of acceleration over the entanglement between twin beams produced in spontaneous parametric down-conversion. Our results show that acceleration does not affect entanglement significantly, under ideal conditions. The optical scheme introduced can be useful in the understanding of processes in the boundary between gravitation and quantum physics.Comment: 5 pages, 3 figure

A study on dynamics of mechanical systems including joints with clearance and lubrication

In this work a methodology for the dynamical analysis of mechanical systems considering realistic joint characteristics, namely, joints with clearance and lubrication is presented. For the case of the joints with clearance modelled as a contact pair with dry contact, a technique using a continuous approach for the evaluation of the contact force is applied, in which the energy dissipation in form of hysteresis damping is considered. The friction forces are calculated using a modified Coulomb’s friction law. For the lubricated case, the hydrodynamic theory for dynamically loaded journal–bearings is used to compute the forces generated by lubrication action. The numerical results point out that the existence of dry joint clearances causes high peaks on the kinematic and dynamic system’s characteristics due to contact–impact forces when compared to those obtained with lubricated model. The performance of the lubricated joint is closer to that of an ideal joint.FEDER - Project POCTI/2001/EME/38281Fundação para a Ciência e a Tecnologia (FCT

Low frequency Raman studies of multi-wall carbon nanotubes: experiments and theory

In this paper, we investigate the low frequency Raman spectra of multi-wall carbon nanotubes (MWNT) prepared by the electric arc method. Low frequency Raman modes are unambiguously identified on purified samples thanks to the small internal diameter of the MWNT. We propose a model to describe these modes. They originate from the radial breathing vibrations of the individual walls coupled through the Van der Waals interaction between adjacent concentric walls. The intensity of the modes is described in the framework of bond polarization theory. Using this model and the structural characteristics of the nanotubes obtained from transmission electron microscopy allows to simulate the experimental low frequency Raman spectra with an excellent agreement. It suggests that Raman spectroscopy can be as useful regarding the characterization of MWNT as it is in the case of single-wall nanotubes.Comment: 4 pages, 2 eps fig., 2 jpeg fig., RevTex, submitted to Phys. Rev.