The colloidal chemistry of ceramic clays

The colloidal chemistry and mineralogy of two argil minerals were studied. Deposits of kaolin and of ceramic clays in the United States and England are discussed for the probable mechanism of formation. The structural modifications of the bed, original material associated with the clays and the proper use of flocculants are discussed

The role of water in slip casting

Slips and casting are considered in terms of physical and colloidal chemistry. Casting slips are polydisperse suspensions of lyophobic particles in water, whose degree of coagulation is controlled by interaction of flocculating and deflocculating agents. Slip casting rate and viscosity are functions of temperature. Slip rheology and response to deflocculating agents varies significantly as the kinds and amounts of colloid modifiers change. Water is considered as a raw material. Various concepts of water/clay interactions and structures are discussed. Casting is a de-watering operation in which water moves from slip to cast to mold in response to a potential energy termed moisture stress. Drying is an evaporative process from a free water surface

Laser phase noise effects on the dynamics of optomechanical resonators

We investigate theoretically the influence of laser phase noise on the cooling and heating of a generic cavity optomechanical system. We derive the back-action damping and heating rates and the mechanical frequency shift of the radiation pressure-driven oscillating mirror, and derive the minimum phonon occupation number for small laser linewidths. We find that in practice laser phase noise does not pose serious limitations to ground state cooling. We then consider the effects of laser phase noise in a parametric cavity driving scheme that minimizes the back-action heating of one of the quadratures of the mechanical oscillator motion. Laser linewidths narrow compared to the decay rate of the cavity field will not pose any problems in an experimental setting, but broader linewidths limit the practicality of this back-action evasion method.Comment: 9 pages, 7 figure

Response and Recovery of the Comanche Carbonate Platform Surrounding Multiple Cretaceous Oceanic Anoxic Events, Northern Gulf of Mexico

The ubiquity of carbonate platforms throughout the Cretaceous Period is recognized as a product of high eustatic sea-level and a distinct climatic optimum induced by rapid sea-floor spreading and elevated levels of atmospheric carbon-dioxide. Notably, a series of global oceanic anoxic events (OAEs) punctuate this time-interval and mark periods of significantly reduced free oxygen in the world's oceans. The best records of these events are often from one-dimensional shelf or basin sections where only abrupt shifts between oxygenated carbonates and anoxic shales are recorded. The Comanche Platform of central Texas provides a unique opportunity to study these events within a well-constrained stratigraphic framework in which their up-dip and down-dip sedimentologic effects can be observed and the recovery of the platform to equilibrium states can be timed and understood. Stable isotope data from whole cores in middle Hauterivian through lower Campanian mixed carbonate-siliciclastic strata are used to construct a 52-myr carbon isotope reference profile for the northern Gulf of Mexico. Correlation of this composite curve to numerous global reference profiles permits identification of several anoxic events and allows their impact on platform architecture and fades distribution to be documented. Oceanic anoxic events la, 1b, 1d, and 2 occurred immediately before, after, or during shale deposition in the Pine Island Member, Bexar Member, Del Rio Formation, and Eagle Ford Group, respectively. Oceanic anoxic event 3 corresponds to deposition of the Austin Chalk Group. Platform drowning on three occasions more closely coincided with globally recognized anoxic sub-events such as the Fallot, Albian-Cenomanian, and Mid-Cenomanian events. This illustrates that the specific anoxic event most affecting a given carbonate platform varied globally as a function of regional oceanographic circumstances. Using chemo- and sequence-stratigraphic observations, a four-stage model is proposed to describe the changing fades patterns, fauna, sedimentation accumulation rates, platform architectures, and relative sea-level trends of transgressive-regressive composite sequences that developed in response to global carbon-cycle perturbations. The four phases of platform evolution include the equilibrium, crisis, anoxic, and recovery stages. The equilibrium stage is characterized by progradational shelf geometries and coralrudist phototrophic faunal assemblages. Similar phototrophic fauna typify the crisis stage; however, incipient biocalcification crises of this phase led to retrogradational shelf morphologies, transgressive facies patterns, and increased clay mineral proportions. Anoxic stages of the Comanche Platform were coincident with back-ground deposition of organic-rich shale on drowned shelves and heterotrophic fauna dominated by oysters or coccolithophorids. Eustatic peaks of this stage were of moderate amplitude (similar to 30 m), yet relative sea-level rises were greatly enhanced by reduced sedimentation rates. In the recovery stage, heterotrophic carbonate factories re-established at the shoreline as progradational ramp systems and sediment accumulation rates slowly increased as dysoxia diminished. Full recovery to equilibrium conditions may or may not have followed. Geochemical and stratigraphic trends present in the four stages are consistent with increased volcanism along mid-ocean ridges and in large-igneous provinces as primary drivers of Cretaceous OAEs and the resulting transgressive-regressive composite sequences. (C) 2014 Elsevier Ltd. All rights reserved.BHP-BillitonReservoir Characterization Research Laboratory, the Bureau of Economic GeologyJackson School of Geosciences at the University of Texas at AustinBureau of Economic Geolog

High resolution bubble sizing through detection of the subharmonic response with a two frequency excitation technique

Sizing bubbles in fluid using a two-frequency excitation technique is not prone to the same drawbacks of some other sizing methods—it has a global maximum at the bubble resonance frequency and allows good spatial resolution. The bubble is insonated with a high fixed imaging signal and a variable pumping signal tuned to the resonant frequency of the bubble, which are coupled at resonance by the high-amplitude oscillation of the bubble wall, with the formation of sum-and-difference terms. This paper examines both the resonance and off-resonance behavior of such combination frequency signals. A coupling of the subharmonic bubble response with the imaging frequency is shown to be a much more accurate and unambiguous detector of the bubble resonance than couplings involving the fundamental resonance. The characteristics of this subharmonic signal are examined using an automated sizing method, and the dependence of the response on the pumping signal amplitude and the frequency step size between two successive pumping frequencies is examined. The location of a definite subharmonic threshold is reported and quantified both for single bubbles held on a wire and for free rising bubbles moving through the focus of the transducers. This amplitude is found to be orders of magnitude lower than that predicted by traditional volumetric pulsation models, but agrees very closely with the theoretical onset of surface wave

Regional financialisation and financial systems convergence: Evidence from Italy

The term ‘financialisation’ has now entered the lexicon of academics and policy makers, though there is still no agreement on its meaning and significance. One of the earlier definitions was in relation to the growing weight of financial motives, financial actors and markets in the operation of modern economies, both at the national and international level, from the early 1980s until today. Building on this definition, this paper sheds further light on the implications of spatial financialisation, which has been associated with the over and under-extension of credit across and within countries and evolving financial instability. The paper’s primary contribution is to extend in a robust manner a powerful panel data convergence testing methodology to analyse the spatial scale and temporal evolution of Italian regional lending conditions. The paper concludes that financial divergence has broadly increased in Italian regions. Furthermore, we are able to link regional financialisation to the growing north–south divide in a significant and meaningful way. As a result, the ability of southern regions in Italy to absorb adverse macroeconomic and financial shocks has been weakened. Relevant regional financial policies have thereby become very important. This is the author accepted manuscript. The final version is available from SAGE Publications via https://doi.org/10.1177/0308518X1666419

A Sensitive Faraday Rotation Setup Using Triple Modulation

The utilization of polarized targets in scattering experiments has become a common practice in many major accelerator laboratories. Noble gases are especially suitable for such applications, since they can be easily hyper-polarized using spin exchange or metastable pumping techniques. Polarized helium-3 is a very popular target because it often serves as an effective polarized neutron due to its simple nuclear structure. A favorite cell material to generate and store polarized helium-3 is GE-180, a relatively dense aluminosilicate glass. In this paper, we present a Faraday rotation method, using a new triple modulation technique, where the measurement of the Verdet constants of SF57 flint glass, pyrex glass, and air were tested. The sensitivity obtained shows that this technique may be implemented in future cell wall characterization and thickness measurements. We also discuss the first ever extraction of the Verdet constant of GE-180 glass for four wavelength values of 632 nm, 773 nm, 1500 nm, and 1547 nm, whereupon the expected 1/{\lambda}^{2} dependence was observed.Comment: 4 pages, 2 figures Updated version for RSI submissio

Tunable Transient Decay Times in Nonlinear Systems: Application to Magnetic Precession

The dynamical motion of the magnetization plays a key role in the properties of magnetic materials. If the magnetization is initially away from the equilibrium direction in a magnetic nanoparticle, it will precess at a natural frequency and, with some damping present, will decay to the equilibrium position in a short lifetime. Here we investigate a simple but important situation where a magnetic nanoparticle is driven non-resonantly by an oscillating magnetic field, not at the natural frequency. We find a surprising result that the lifetime of the transient motion is strongly tunable, by factors of over 10,000, by varying the amplitude of the driving field.Comment: EPL Preprin