12 research outputs found
Inorganic chemistry: Cation o' nine tails
- Author
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 05/08/2010
- Field of study
Ultrafast Coherent Spectroscopy
- Author
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Penzkofer
- A Penzkofer
- A Yariv
- AE Siegman
- AM Weiner
- AM Weiner
- AM Weiner
- B Dick
- BH Hesp
- BK Rhee
- C Flytzanis
- CB Harris
- CB Harris
- CB Harris
- CH Lee
- CL Schosser
- D Linde
- D Linde
- D Oxtoby
- DD Dlott
- DE Mccumber
- DJ Diestler
- DJ Diestler
- DP Weitekamp
- DW Oxtoby
- DW Oxtoby
- DW Phillion
- F Ho
- F Ho
- FM Kamga
- G Placzek
- GJ Small
- GM Gale
- GM Gale
- GM Gale
- GM Gale
- GM Gale
- H Graener
- H Graener
- H Graener
- H Paerschke
- HJ Hartmann
- HJ Hartmann
- HJ Hartmann
- HJ Hartmann
- HR Telle
- I.I. Abram
- ID Abella
- J Chesnoy
- J Kuhl
- J Kuhl
- J.C. Diels
- JA Giordmaine
- JG Fujimoto
- JL Skinner
- JP Heritage
- JP Riehl
- K Duppen
- K Duppen
- K Duppen
- K Duppen
- K Duppen
- KE Jones
- L Schultheis
- L Schultheis
- LW Molenkamp
- LW Molenkamp
- M Maier
- M van Exter
- MA Collins
- MC Nuss
- MD Crisp
- MG Sceats
- ML Geirnaert
- ML Geirnaert
- N Bloembergen
- N Bloembergen
- N Kohles
- NA Kurnit
- P de Bree
- PA Madden
- PD Maker
- PG Klemens
- PL Decola
- R Kubo
- R Leonhardt
- R Orbach
- R Trebino
- R Wertheimer
- R Wertheimer
- RF Loring
- RF Loring
- RF Loring
- RG Delle Valle
- RG Gordon
- RG Gordon
- RG Gordon
- RG Gordon
- RL Carman
- RM Hochstrasser
- RM Lynden-Bell
- RM Shelby
- RR Alfano
- S Bratos
- S Mukamel
- S Mukamel
- S Silvestri
- S Silvestri
- S Velsko
- S Velsko
- S Velsko
- S Velsko
- SA Akhmanov
- SF Fischer
- SF Fischer
- SM George
- SM George
- SM George
- TJ Kosic
- TJ Trout
- W Kaiser
- W Zinth
- W Zinth
- W Zinth
- W Zinth
- W Zinth
- W Zinth
- W Zinth
- W Zinth
- W. Zinth
- WE Bron
- WG Rothschild
- WG Rothschild
- WG Rothschild
- WH Hesselink
- WH Hesselink
- WH Hesselink
- WH Hesselink
- WH Hesselink
- YR Shen
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1988
- Field of study
Towards Selective Laser Photochemistry of Biomolecules
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1980
- Field of study
Studies of Nonequilibrium Dynamics in The Time Domain
- Author
- A Laubereau
- BKh Bairamov
- BKh Bairamov
- C Flytzanis
- C Flytzanis
- C Martinon
- D Linde von der
- DA Kleinman
- DV Kazakovtzev
- DV Kazakovtzev
- E Yablonovitch
- G Niklasson
- G Placzek
- GM Gale
- H Bilz
- HJ Maris
- J Kuhl
- J Ziman
- JA Armstrong
- JDN Cheeke
- JJ Wynn
- JM Calleja
- JW Tucker
- JY Wong
- M Born
- M Wagner
- MD Levenson
- MD Levenson
- MV Klein
- N Perrin
- P Baumgartner
- P Herth
- P Tua
- PC Kwok
- PD Maker
- PG Klemens
- PG Klemens
- PG Klemens
- R Orbach
- RG Gutfeld von
- RJ Gutfeld von
- T Timush
- TE Wilson
- W Demtroder
- W Eisenmenger
- W Eisenmenger
- W Kappus
- W Little
- W Zinth
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WE Bron
- WL Schaich
- WL Schaich
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1985
- Field of study
Emergence of californium as the second transitional element in the actinide series
- Author
- AL Spek
- B Weaver
- C Apostolidis
- E Galbis
- EI Solomon
- G Liu
- GK Liu
- GR Choppin
- I Castro-Rodriguez
- J Maly
- J Sytama
- JC Copeland
- JR Moore
- JR Peterson
- K Fajans
- K Fajans
- L Soderholm
- LA Riseberg
- MB Jones
- MB Jones
- MJ Polinski
- MJ Polinski
- ML Neidig
- N Edelstein
- N Edelstein
- N Kaltsoyannis
- P Lindqvist-Reis
- PG Laubereau
- RE Sykora
- RG Haire
- RG Haire
- RG Haire
- RM Diamond
- S Heathman
- S Hubert
- S Skanthakumar
- S Skanthakumar
- SG Minasian
- TH Bray
- WK Kot
- WT Carnall
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- Field of study
Organoactinide Chemistry: Properties of Compounds Having MetalâCarbon Bonds Only to Ï-Bonded Ligands
- Author
- A Avdeef
- A Dormond
- A Dormond
- A Spiegl
- A Streitwieser Jr
- A Streitwieser Jr
- A Streitwieser Jr
- A Streitwieser Jr
- A Streitwieser Jr
- A Streitwieser Jr.
- A Streitwieser Jr.
- A Zalkin
- A Zalkin
- A Zalkin
- AE Gebala
- AF Reid
- AW Spiegl
- B Kanellakopulos
- B Kanellakopulos
- B Kanellakopulos
- B Kanellakopulos
- C LeVanda
- C LeVanda
- C Wong
- CA Harmon
- CA Secaur
- CB Grant
- CC Chang
- CC Chang
- CM Fendrick
- CW Eigenbrot Jr
- DC Moody
- DF Slarks
- DF Starks
- DG Kalina
- DG Karrakcr
- DG Karraker
- DG Karraker
- DG Karraker
- DG Karraker
- DG Karraker
- E Cernia
- E Fukishima
- EA Mintz
- EO Fischer
- EO Fischer
- EO Fischer
- EO Fischer
- EO Fischer
- F BaumgÀrtner
- F BaumgÀrtner
- F BaumgÀrtner
- F BaumgÀrtner
- F BaumgÀrtner
- F BaumgÀrtner
- F BaumgÀrtner
- F Benetollo
- F Billiau
- FA Cotton
- G Bombieri
- G Brandi
- G Lugli
- G Lugli
- G Wilke
- H Gilman
- H-D Amberger
- H-D Amberger
- H-D Amberger
- H-D Amberger
- H-D Amberger
- HJ Wasserman
- I FragalĂ
- I FragalĂ
- J Goffart
- J Goffart
- J Goffart
- J Goffart
- J Goffart
- J Goffart
- J Goflart
- J Leong
- J Meunier-Piret
- J Meunier-Piret
- JA Butcher
- JA Connor
- JC Green
- JC Green
- JD Jamerson
- JD Jamerson
- JG Brennan
- JH Burns
- JH Burns
- JM Manriquez
- JP Collman
- JP Solar
- JP Solar
- JT Miller
- JW Bruno
- KD Warren
- KO Hodgson
- KO Hodgson
- KW Bagnali
- KW Bagnall
- KW Bagnall
- L Doretti
- LJ Nugent
- LK Templeton
- LT Reynolds
- M Brunelli
- M Cesari
- MR Duttera
- MR Spirlet
- N Edelstein
- N Rösch
- N Rösch
- N Rösch
- NC Vanderhooft
- P Laubereau
- P Laubereau
- P Laubereau
- P Reeb
- P Zanella
- P Zanella
- PG Laubereau
- PJ Fagan
- PJ Fagan
- PJ Fagan
- R Ammon von
- R Ammon von
- R Ammon von
- RD Ernst
- RD Ernst
- RD Fischer
- RD Fischer
- RD Rieke
- RF Dallinger
- RG Finke
- RG Finke
- RG Hayes
- RR Ryan
- TH Cymbaluk
- TH Cymbaluk
- TJ Marks
- TJ Marks
- TJ Marks
- TJ Marks
- TJ Marks
- TJ Marks
- TJ Marks
- VI Telânoi
- WD Luke
- WD Luke
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1986
- Field of study
Unusual structure, bonding and properties in a californium borate
- Author
- A Ruiz-MartĂnez
- A Ruiz-MartĂnez
- A SchÀfer
- AD Becke
- AE Reed
- AF Campos
- AL Spek
- B Silvi
- BA Hess
- BO Roos
- C Apostolidis
- David A. Dixon
- E Galbis
- Edward B. Garner
- Evgeny V. Alekseev
- F Aquilante
- F Weinhold
- Guokui Liu
- I Castro-Rodriguez
- J Legendziewicz
- Jared T. Stritzinger
- JH Burns
- JP Perdew
- JP Perdew
- Justin N. Cross
- Kenneth L. Knappenberger
- L Li
- Laura Gagliardi
- Lynda Soderholm
- M Kohout
- Matthew J. Polinski
- Michael Shatruk
- MJ Polinski
- ML Neidig
- N Douglas
- N Kaltsoyannis
- Nora Planas
- P Lindqvist-Reis
- PG Laubereau
- PR Fields
- RE Sykora
- RĂ©mi Maurice
- S Skanthakumar
- S Skanthakumar
- S. Skanthakumar
- Shelley M. Van Cleve
- T Tsuchiya
- T. Gannon Parker
- Thomas D. Green
- Thomas E. Albrecht-Schmitt
- U Staub
- Wulf Depmeier
- X Cao
- X Cao
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/2014
- Field of study
The participation of the valence orbitals of actinides in bonding has been debated for decades. Recent experimental and computational investigations demonstrated the involvement of 6p, 6d and/or 5f orbitals in bonding. However, structural and spectroscopic data, as well as theory, indicate a decrease in covalency across the actinide series, and the evidence points to highly ionic, lanthanide-like bonding for late actinides. Here we show that chemical differentiation between californium and lanthanides can be achieved by using ligands that are both highly polarizable and substantially rearrange on complexation. A ligand that suits both of these desired properties is polyborate. We demonstrate that the 5f, 6d and 7p orbitals are all involved in bonding in a Cf(III) borate, and that large crystal-field effects are present. Synthetic, structural and spectroscopic data are complemented by quantum mechanical calculations to support these observations
Curium
- Author
- A Aziz
- AA Elesin
- AA Elesin
- AA Elesin
- AA Zeitsev
- AB Shalinets
- AD Jones
- AS Saprykin
- AV Davydov
- AV Stepanov
- B Désiré
- B Erdmann
- B Kanellakopulos
- B Kannelakopulos
- BB Cunningham
- BB Cunningham
- BF Myasoedov
- BF Myasoedov
- BM Bansal
- C Keller
- C Keller
- C Keller
- C Keller
- CB Finch
- CF Baes
- D Brown
- D Damien
- D Damien
- DA Damien
- DE Hobart
- DE Hobart
- DK Fujita
- DL Raschclla
- E Akatsu
- F BaumgÀrtner
- F Weigel
- F Weigel
- F Weigel
- FL Oetting
- For a review of curium chemistry in the nuclear fuel cycle see Keller, O. L.
- GA Burney
- GA Burney
- GH Thompson
- GN Kazantsev
- GR Choppin
- GT Seaborg
- GT Seaborg
- GV Ionova
- H Diamond
- HA Friedman
- HD Harmon
- HJ Groh
- HO Haug
- HO Haug
- HP Holcomb
- I Grenthe
- I StroĆski
- IA Lebedev
- IA Lebedev
- ID Eubanks
- J Akatsu
- J Burnett
- J Fuger
- J Ward
- JC Sullivan
- JC Wallmann
- JC Wallmann
- JE Bigelow
- JH Burns
- JH Miles
- JJ Katz
- JK Gibson
- JM Fournier
- JN Stevenson
- JN Stevenson
- JN Stevenson
- JP Charvillat
- JP Charvillat
- JP Charvillat
- JR Peterson
- JR Peterson
- JR Peterson
- JS Coleman
- JW Ward
- K Buijs
- KW Bagnall
- KW Bagnall
- L Brewer
- L Eyring
- LB Asprey
- LB Asprey
- LB Asprey
- LB Asprey
- LB Asprey
- LB Werner
- LJ Nugent
- LJ Nugent
- LJ Nugent
- LP Varga
- LP Varga
- LR Morss
- LV Sudakov
- M Abraham
- M Abraham
- M Noé
- M Pages
- M Ward
- Mikheev. N. B
- N Edelstein
- N Edelstein
- NE Bibler
- PG Huray
- PG Laubereau
- PG Laubereau
- PK Khopkar
- PK Khopkar
- PK Smith
- PRV Rao
- R Schenkel
- RA Penneman
- RD Baybarz
- RD Baybarz
- RD Baybarz
- RD Baybarz
- RD Baybarz
- RG Carvalho de
- RG Gutmacher
- RG Haire
- RG Haire
- S Hubert
- SA Marei
- SA Marei
- SE Nave
- SE Nave
- SH Eberle
- SP Tanner
- T Moeller
- TD Chikalla
- TK Keenan
- TK Keenan
- TK Keenan
- TK Keenan
- TK Keenan
- TK Keenan
- V Scherer
- VA Gubanov
- VB Dedov
- VB Dedov
- VF Peretrukhin
- VG Polyukhov
- VI Spitsyn
- VM Nikolaev
- VM Radchenko
- VN Kosyakov
- W MĂŒller
- W MĂŒller
- WC Mosley
- WH Hale Jr
- WH Zachariasen
- WJ Kerrigan
- YA Barbanel
- YS Korotkin
- YY Chu
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1986
- Field of study
Unusual structure, bonding and properties in a californium borate
- Author
- A Ruiz-MartĂnez
- A Ruiz-MartĂnez
- A SchÀfer
- AD Becke
- AE Reed
- AF Campos
- AL Spek
- B Silvi
- BA Hess
- BO Roos
- C Apostolidis
- David A. Dixon
- E Galbis
- Edward B. Garner
- Evgeny V. Alekseev
- F Aquilante
- F Weinhold
- Guokui Liu
- I Castro-Rodriguez
- J Legendziewicz
- Jared T. Stritzinger
- JH Burns
- JP Perdew
- JP Perdew
- Justin N. Cross
- Kenneth L. Knappenberger
- L Li
- Laura Gagliardi
- Lynda Soderholm
- M Kohout
- Matthew J. Polinski
- Michael Shatruk
- MJ Polinski
- ML Neidig
- N Douglas
- N Kaltsoyannis
- Nora Planas
- P Lindqvist-Reis
- PG Laubereau
- PR Fields
- RE Sykora
- RĂ©mi Maurice
- S Skanthakumar
- S Skanthakumar
- S. Skanthakumar
- Shelley M. Van Cleve
- T Tsuchiya
- T. Gannon Parker
- Thomas D. Green
- Thomas E. Albrecht-Schmitt
- U Staub
- Wulf Depmeier
- X Cao
- X Cao
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- Field of study
Optical Nonlinearities with Ultrashort Pulses
- Author
- A Berg
- A Fendt
- A Hasegawa
- A Hasegawa
- A Hasegawa
- A Jena
- A Kumar
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Laubereau
- A Migus
- A Mokhtari
- A Penzkofer
- A Penzkofer
- A Penzkofer
- A Penzkofer
- A Szöke
- A Yariv
- A. Penzkofer
- AA Babin
- AA Gulamov
- AE Kaplan
- AG Maaswinkel
- AH Kung
- AJ Campillo
- AJ Campillo
- AJ Demaria
- Akhmanov
- AL Harris
- AL Smirl
- AL Smirl
- AM Johnson
- AM Malvezzi
- AM Weiner
- AM Weiner
- AM Weiner
- AR Chraplyvy
- AR Chraplyvy
- AT Ferguson
- Auston
- B Dick
- B Kopainsky
- B.I. Greene
- B.I. Greene
- BA Medvedev
- BB Boyko
- BS Wherrett
- BY Zeldovich
- C Flytzanis
- C Flytzanis
- C Kolmeder
- C Lin
- C Lin
- CA Moore
- CA Schwartz
- CC Shih
- CK Chen
- CK Chen
- CK Wu
- CL Tang
- CV Shank
- CV Shank
- D Anderson
- D Auston
- D Cotter
- D Grischkowsky
- D Linde
- D Linde
- D Mestdagh
- D Narayana
- D Reiser
- D Ricard
- D Welford
- DB Mcdonald
- DC Jeanmaire
- DC Nguyen
- DG Sarkisyan
- DJ Bradley
- DK Sharma
- DM Bloom
- DM Bloom
- DN Christodoulides
- DN Rao
- DS Chemla
- E Bourkoff
- E Garmire
- E Pochon
- EM Dianov
- EO Göbel
- EP Ippen
- EP Ippen
- EP Ippen
- F Demartini
- F Hache
- F Wondrazek
- FA Hopf
- FM Mitschke
- FS Felber
- G SzabĂł
- G Yang
- G. Eyring
- G.D. Boyd
- G.P. Agrawal
- GA Dychyus
- GA Fanas
- GA Kenney-Wallace
- GF Albrecht
- GI Kachen
- GI Onishchukov
- GL Brekhovskikh
- GM Carter
- GM Gandelman
- GR Jacobovitz
- GR Olbright
- GS Agarwal
- GV Krivoshtshekov
- GV Mironov
- H Graener
- H Nakatsuka
- H Souma
- H. Puell
- H.R. Telle
- H.R. Telle
- HG Winful
- HJ Eichler
- HJ Hartmann
- HJ Hartmann
- HJ Hartmann
- HJ Hartmann
- HJ Hartmann
- HJ Lehmeier
- HM Gibbs
- HP Weber
- HS Kwok
- I Freund
- I Ledoux
- IV Tomov
- J Buchert
- J Comly
- J Etchepare
- J Etchepare
- J Herrmann
- J Janszky
- J Kuhl
- J.F. Reintjes
- JA Giordmaine
- JA Giordmaine
- JA Giordmaine
- JA Giordmaine
- JA Goldstone
- JA Goldstone
- JA Goldstone
- JC Diels
- JE Golub
- JE Rothenberg
- JE Rothenberg
- JF Reintjes
- JF Reintjes
- JH Glownia
- JH Hunt
- JL Ferrier
- JL Oudar
- JM Halbout
- JM Hicks
- JN Elgin
- JO Tocho
- JO Tocho
- JP Gordon
- JP Gordon
- JP Heritage
- JP Heritage
- JP Herman
- JP Lavoine
- JR Taylor
- JW Shelton
- JW Shelton
- K Darée
- K Miyazaki
- K Rzazewski
- K Shimoda
- K Tai
- K Tai
- K Tajima
- K.A. Nelson
- K.L. Sala
- K.M. Leung
- Kaplan
- KJ Blow
- KL Sala
- KM Pokhsraryan
- KN Drabovich
- Kung
- L.F. Mollenauer
- LA Hallidy
- LA Luigiato
- LE Brus
- LF Mollenauer
- LM Johnson
- LS Telegin
- M Berg
- M Chatelet
- M Cronin-Golomb
- M Dagenais
- M Fleischmann
- M Matsuoka
- M Nakazawa
- M Piché
- M Thalhammer
- M. Maier
- M.D. Duncan
- MA Duguay
- Marburger
- ME Mack
- Medvedev
- MH Hutchinson
- MJ Colles
- MJ Colles
- MM Robinson
- N Bloembergen
- N Bloembergen
- N Bloembergen
- N Bloembergen
- N Fabricius
- N Kohles
- N Kohles
- N Tan
- NB Bloembergen
- NK Dutta
- NN Rozanov
- NN Rozanov
- O Rahn
- P Franken
- P Hu
- P Roussignol
- P. Ye
- PA Apanasevich
- PA Apanasevich
- PA Madden
- PB Corkum
- PB Corkum
- PD Maker
- PG Kryukov
- PK Shukla
- PK Wai
- PL Liu
- PN Prasad
- PW Smith
- PW Smith
- PW Smith
- R Beach
- R Beach
- R Bonafacio
- R Bonafacio
- R Bonifacio
- R Bonifacio
- R Danelyus
- R Danelyus
- R Trebino
- R Wyatt
- R Wyatt
- R Wyatt
- RB Weisman
- RC Miller
- RH Stolen
- RH Stolen
- RL Byer
- RL Carman
- RL Carman
- RL Carman
- RL Fork
- RR Alfano
- RS Adrain
- RS Craxton
- RT Deck
- RU Orlov
- RW Boyd
- RW Hellwarth
- RW Hellwarth
- RY Chiao
- S Asaka
- S Desilvestri
- SA Akhmanov
- SA Akhmanov
- SA Akhmanov
- SA Akhmanov
- SA Arakelyan
- SA Magnitskii
- SA Magnitskii
- SB Papernyl
- SE Harris
- Shapiro
- SJ Garth
- SL Jensen
- SL Mccall
- SL Mccall
- SL Palfrey
- SL Shapiro
- SO Sapondzhyan
- T Bischofsberger
- T Bischofsberger
- T Elsaesser
- T Elsaesser
- T Elsaesser
- T Kurobori
- T Srinivasan
- T Yajima
- T Yajima
- T Yajima
- T Yajima
- TA Rabson
- TF Heinz
- TF Heinz
- TI Kosic
- V Benza
- V Kabelka
- V.L. Boichenko
- VD Volosov
- VE Neef
- VE Zakharov
- VT Atanesyan
- W Alexiewicz
- W Kranitzky
- W Leupacher
- W Seka
- W Zinth
- W Zinth
- W.J. Tomlinson
- W.L. Smith
- WF Hagen
- WH Glenn
- WH Lowdermilk
- WM Dennis
- WM Dennis
- Y Fuji
- Y Takagi
- Y Tanaka
- Y Tanaka
- YN Karamzin
- Z Vardeny
- ZI Ivanova
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/1988
- Field of study