Orthorhombic Phase of Crystalline Polyethylene: A Monte Carlo Study

In this paper we present a classical Monte Carlo simulation of the orthorhombic phase of crystalline polyethylene, using an explicit atom force field with unconstrained bond lengths and angles and periodic boundary conditions. We used a recently developed algorithm which apart from standard Metropolis local moves employs also global moves consisting of displacements of the center of mass of the whole chains in all three spatial directions as well as rotations of the chains around an axis parallel to the crystallographic c-direction. Our simulations are performed in the NpT ensemble, at zero pressure, and extend over the whole range of temperatures in which the orthorhombic phase is experimentally known to be stable (10 - 450 K). In order to investigate the finite-size effects in this extremely anisotropic crystal, we used different system sizes and different chain lengths, ranging from C_12 to C_96 chains, the total number of atoms in the super-cell being between 432 and 3456. We show here the results for structural parameters, such as the orthorhombic cell parameters a,b,c, and the setting angle of the chains, as well as internal parameters of the chains, such as the bond lengths and angles. Among thermodynamic quantities, we present results for thermal expansion coefficients, elastic constants and specific heat. We discuss the temperature dependence of the measured quantities as well as the related finite-size effects. In case of lattice parameters and thermal expansion coefficients, we compare our results to those obtained from other theoretical approaches as well as to some available experimental data. We also suggest some possible ways of extending this study.Comment: 27 pages, RevTex, 24 figures, submitted to Journal of Chemical Physic

Fast C-V method to mitigate effects of deep levels in CIGS doping profiles

In this work, methods to determine more accurate doping profiles in semiconductors is explored where trap-induced artifacts such as hysteresis and doping artifacts are observed. Specifically in CIGS, it is shown that this fast capacitance-voltage (C-V) approach presented here allows for accurate doping profile measurement even at room temperature, which is typically not possible due to the large ratio of trap concentration to doping. Using deep level transient spectroscopy (DLTS) measurement, the deep trap responsible for the abnormal C-V measurement above 200 K is identified. Importantly, this fast C-V can be used for fast evaluation on the production line to monitor the true doping concentration, and even estimate the trap concentration. Additionally, the influence of high conductance on the apparent doping profile at different temperature is investigated

An overview of tea research in Tanzania - with special reference to the Southern Highlands.

The history of tea development in Tanzania from the early part of this century to the present is summarised. Average yields of made tea from well managed estates in the Mufindi district have increased from around 600 kg ha-1 in the late 1950s to 3000 kg ha-1 at the present time: by comparison, yields from smallholder farms have remained much lower, averaging only 400-500 kg ha-1. There have been a large number of technical, economic and other changes over the last 30 to 40 years. The removal of shade trees, the use of herbicides, the application of NPK compound fertilisers, the introduction of irrigation (on some estates) and changes in harvesting policy have all contributed to the increases in yield. Financial and infrastructural problems have contributed to the low yields from many smallholders and others, and have limited the uptake of new technology. The contribution of research is reviewed, from the start of the Tea Research Institute of East Africa in Kenya in 1951, through to the development of the Marikitanda Tea Research Centre in Amani in 1967; the Ngwazi Tea Research Unit in Mufindi (1967 to 1970, and from 1986), and lastly the Kifyulilo Tea Research Station, also in Mufindi in 1986. The yield potential of well fertilized and irrigated clonal tea, grown at an altitude of 1800 m, is around 6000 kg ha-1. This potential is reduced by drought, lack of fertilizer, bush vacancies and inefficient harvesting practices. The corresponding potential yields at high (2200 m) and low (1200 m) altitude sites range from 3000-3500 kg ha-1 up to 9000-10000 kg ha-1 and are largely a function of temperature. The opportunities for increasing yields of existing tea, smallholder and estate, are enormous. Tea production in the Southern Highlands of Tanzania is about to expand rapidly. Good, appropriate research is needed to sustain this development over the long term, and suggestions on how best this is done in order to assist the large scale producers as well as the smallholders, are discussed

Structure and superconductivity of two different phases of Re3W

Two superconducting phases of Re(3)W have been found with different physical properties. One phase crystallizes in a noncentrosymmetric cubic (alpha-Mn) structure and has a superconducting transition temperature T(c) of 7.8 K. The other phase has a hexagonal centrosymmetric structure and is superconducting with a T(c) of 9.4 K. Switching between the two phases is possible by annealing the sample or remelting it. The properties of both phases of Re(3)W have been characterized by powder neutron diffraction, magnetization, and resistivity measurements. The temperature dependences of the lower and upper critical fields have been measured for both phases. These are used to determine the penetration depths and the coherence lengths for these systems

The Visibility of Galactic Bars and Spiral Structure At High Redshifts

We investigate the visibility of galactic bars and spiral structure in the distant Universe by artificially redshifting 101 B-band CCD images of local spiral galaxies from the Ohio State University Bright Spiral Galaxy Survey. Our artificially redshifted images correspond to Hubble Space Telescope I-band observations of the local galaxy sample seen at z=0.7, with integration times matching those of both the very deep Northern Hubble Deep Field data, and the much shallower Flanking Field observations. The expected visibility of galactic bars is probed in two ways: (1) using traditional visual classification, and (2) by charting the changing shape of the galaxy distribution in "Hubble space", a quantitative two-parameter description of galactic structure that maps closely on to Hubble's original tuning fork. Both analyses suggest that over 2/3 of strongly barred luminous local spirals i.e. objects classified as SB in the Third Reference Catalog) would still be classified as strongly barred at z=0.7 in the Hubble Deep Field data. Under the same conditions, most weakly barred spirals (classified SAB in the Third Reference Catalog) would be classified as regular spirals. The corresponding visibility of spiral structure is assessed visually, by comparing luminosity classifications for the artificially redshifted sample with the corresponding luminosity classifications from the Revised Shapley Ames Catalog. We find that for exposures times similar to that of the Hubble Deep Field spiral structure should be detectable in most luminous low-inclination spiral galaxies at z=0.7 in which it is present. [ABRIDGED]Comment: Accepted for publication in The Astronomical Journa

On the origin of the various types of radio emission in GRS 1915+105

We investigate the association between the radio ``plateau'' states and the large superluminal flares in GRS 1915+105 and propose a qualitative scenario to explain this association. We identify several candidate superluminal flare events from available monitoring data on this source and analyze the contemporaneous RXTE pointed observations. We detect a strong correlation between the average X-ray flux during the ``plateau'' state and the total energy emitted in radio during the subsequent radio flare. We find that the sequence of events is similar for all large radio flares with a fast rise and exponential decay morphology. Based on these results, we propose a qualitative scenario in which the separating ejecta during the superluminal flares are observed due to the interaction of the matter blob ejected during the X-ray soft dips, with the steady jet already established during the ``plateau'' state. This picture can explain all types of radio emission observed from this source in terms of its X-ray emission characteristics.Comment: Corrected typo in the author names, contents unchanged, accepted in Ap

Weber blockade theory of magnetoresistance oscillations in superconducting strips

Recent experiments on the conductance of thin, narrow superconducting strips have found periodic fluctuations, as a function of the perpendicular magnetic field, with a period corresponding to approximately two flux quanta per strip area [A. Johansson et al., Phys. Rev. Lett. {\bf 95}, 116805 (2005)]. We argue that the low-energy degrees of freedom responsible for dissipation correspond to vortex motion. Using vortex/charge duality, we show that the superconducting strip behaves as the dual of a quantum dot, with the vortices, magnetic field, and bias current respectively playing the roles of the electrons, gate voltage and source-drain voltage. In the bias-current vs. magnetic-field plane, the strip conductance displays what we term `Weber blockade' diamonds, with vortex conductance maxima (i.e., electrical resistance maxima) that, at small bias-currents, correspond to the fields at which strip states of $N$ and $N+1$ vortices have equal energy.Comment: 4+a bit pages, 3 figures, 1 tabl

Self-dual Maxwell Chern-Simons Solitons In 1+1 Dimensions

We study the domain wall soliton solutions in the relativistic self-dual Maxwell Chern-Simons model in 1+1 dimensions obtained by the dimensional reduction of the 2+1 model. Both topological and nontopological self-dual solutions are found in this case. A la BPS dyons here the Bogomol'ny bound on the energy is expressed in terms of two conserved quantities. We discuss the underlying supersymmetry. Nonrelativistic limit of this model is also considered and static, nonrelativistic self-dual soliton solutions are obtained.Comment: 18 pages RevTex, 2 figures included, to appear in Phys. Rev.

Eigenvalue Separation in Some Random Matrix Models

The eigenvalue density for members of the Gaussian orthogonal and unitary ensembles follows the Wigner semi-circle law. If the Gaussian entries are all shifted by a constant amount c/Sqrt(2N), where N is the size of the matrix, in the large N limit a single eigenvalue will separate from the support of the Wigner semi-circle provided c > 1. In this study, using an asymptotic analysis of the secular equation for the eigenvalue condition, we compare this effect to analogous effects occurring in general variance Wishart matrices and matrices from the shifted mean chiral ensemble. We undertake an analogous comparative study of eigenvalue separation properties when the size of the matrices are fixed and c goes to infinity, and higher rank analogues of this setting. This is done using exact expressions for eigenvalue probability densities in terms of generalized hypergeometric functions, and using the interpretation of the latter as a Green function in the Dyson Brownian motion model. For the shifted mean Gaussian unitary ensemble and its analogues an alternative approach is to use exact expressions for the correlation functions in terms of classical orthogonal polynomials and associated multiple generalizations. By using these exact expressions to compute and plot the eigenvalue density, illustrations of the various eigenvalue separation effects are obtained.Comment: 25 pages, 9 figures include