The Excess Far-Infrared Emission of AGN in the Local Universe

We have cross-correlated the Sloan Digital Sky Survey (SDSS) second data release spectroscopic galaxy sample with the IRAS faint-source catalogue (FSC). Optical emission line ratios are used to classify the galaxies with reliable IRAS 60 and 100 microns detections into AGN and normal star-forming galaxies. We then create subsamples of normal galaxies and AGN that are very closely matched in terms of key physical properties such as stellar mass, redshift, size, concentration and mean stellar age (as measured by absorption line indicators in the SDSS spectra). We then quantify whether there are systematic differences between the IR luminosities of the galaxies and the AGN in the matched subsamples. We find that the AGN exhibit a significant excess in far-IR emission relative to the star-forming galaxies in our sample. The excesses at 60 and 100 microns are 0.21 +/- 0.03 dex and 0.12 +/- 0.035 dex in log[L(60)/M*] and log[L(100)/M*], respectively. We then discuss whether the far-IR excess is produced by radiation from the active nucleus that is absorbed by dust or alternatively, by an extra population of young stars that is not detectable at optical wavelengths.Comment: 12 pages, 14 figures, accepted by MNRA

Chemical abundances and properties of the ionized gas in NGC 1705

We obtained [O III] narrow-band imaging and multi-slit MXU spectroscopy of the blue compact dwarf (BCD) galaxy NGC 1705 with FORS2@VLT to derive chemical abundances of PNe and H II regions and, more in general, to characterize the properties of the ionized gas. The auroral [O III]\lambda4363 line was detected in all but one of the eleven analyzed regions, allowing for a direct estimate of their electron temperature. The only object for which the [O III]\lambda4363 line was not detected is a possible low-ionization PN, the only one detected in our data. For all the other regions, we derived the abundances of Nitrogen, Oxygen, Neon, Sulfur and Argon out to ~ 1 kpc from the galaxy center. We detect for the first time in NGC 1705 a negative radial gradient in the oxygen metallicity of -0.24 \pm 0.08 dex kpc^{-1}. The element abundances are all consistent with values reported in the literature for other samples of dwarf irregular and blue compact dwarf galaxies. However, the average (central) oxygen abundance, 12 + log(O/H)=7.96 \pm 0.04, is ~0.26 dex lower than previous literature estimates for NGC 1705 based on the [O III]\lambda4363 line. From classical emission-line diagnostic diagrams, we exclude a major contribution from shock excitation. On the other hand, the radial behavior of the emission line ratios is consistent with the progressive dilution of radiation with increasing distance from the center of NGC 1705. This suggests that the strongest starburst located within the central $\sim$150 pc is responsible for the ionization of the gas out to at least $\sim$1 kpc. The gradual dilution of the radiation with increasing distance from the center reflects the gradual and continuous transition from the highly ionized H II regions in the proximity of the major starburst into the diffuse ionized gas.Comment: Accepted for publication on A

PNe and H II regions in the starburst irregular galaxy NGC 4449 from LBT MODS data

We present deep 3500$-$10000 $\AA$ spectra of H II regions and planetary nebulae (PNe) in the starburst irregular galaxy NGC 4449, acquired with the Multi Object Double Spectrograph at the Large Binocular Telescope. Using the "direct" method, we derived the abundance of He, N, O, Ne, Ar, and S in six H II regions and in four PNe in NGC 4449. This is the first case of PNe studied in a starburst irregular outside the Local Group. Our H II region and PN sample extends over a galacto-centric distance range of $\approx$2 kpc and spans $\approx$0.2 dex in oxygen abundance, with average values of $12+\log(O/H)=8.37 \pm 0.05$ and $8.3 \pm 0.1$ for H II regions and PNe, respectively. PNe and H II regions exhibit similar oxygen abundances in the galacto-centric distance range of overlap, while PNe appear more than $\sim$1 dex enhanced in nitrogen with respect to H II regions. The latter result is the natural consequence of N being mostly synthesized in intermediate-mass stars and brought to the stellar surface during dredge-up episodes. On the other hand, the similarity in O abundance between H II regions and PNe suggests that NGC 4449' s interstellar medium has been poorly enriched in $\alpha$ elements since the progenitors of the PNe were formed. Finally, our data reveal the presence of a negative oxygen gradient for both H II regions and PNe, whilst nitrogen does not exhibit any significant radial trend. We ascribe the (unexpected) nitrogen behaviour as due to local N enrichment by the conspicuous Wolf-Rayet population in NGC 4449.Comment: Accepted for publication on Ap

Oxygen and silicon abundances in Cygnus OB2: Chemical homogeneity in a sample of OB slow rotators

Cygnus OB2 is a rich OB association in the Galaxy which has experienced intense star formation in the last 20-25 Myr. Its stellar population shows a correlation between age and Galactic longitude. Exploring the chemical composition of its stellar content we will be able to check the degree of homogeneity of the natal molecular cloud and possible effects of self-enrichment processes. Our aim is to determine silicon and oxygen abundances for a sample of eight early-type slow rotators in Cygnus OB2 in order to check possible inhomogeneities across the whole association and whether there exists a correlation of chemical composition with Galactic longitude. We have performed a spectroscopic analysis of a sample of late O and early B stars with low rotational velocity, which have been chosen so as to cover the whole association area. We have carried out an analysis based on equivalent widths of metal lines, the wings of the H Balmer lines and FASTWIND stellar atmosphere models to determine their stellar fundamental parameters as well as the silicon and oxygen surface abundances. We derive a rather homogeneous distribution of silicon and oxygen abundances across the region, with average values of 12+log(Si/H)=7.53$\pm$0.08 dex and 12+log(O/H)=8.65$\pm$0.12 dex. We find a homogeneous chemical composition in Cygnus OB2 with no clear evidence for significant chemical self-enrichment, despite indications of strong stellar winds and possible supernovae during the history of the region. Comparison with different scenarios of chemical enrichment by stellar winds and supernovae point to star forming efficiencies not significantly above 10%. The degree of homogeneity that we find is consistent with the observed Milky Way oxygen gradient based on HII regions. We also find that the oxygen scatter within Cygnus OB2 is at least of the same order than among HII regions at similar Galactocentric distance.Comment: 15 pages, 7 figures, accepted for publication in Astronomy & Astrophysic

Cu-catalyzed Si-NWS grown on “carbon paper” as anodes for Li-ion cells

The very high theoretical capacity of the silicon (4200mAh/g more than 10 times larger than graphite), environmental-friendly, abundant and low-cost, makes it a potential candidate to replace graphite in high energy density Li-ion batteries. As a drawback, silicon suffers from huge volume changes (300%) on alloying and dealloying with Li, leading a structural deformation that induces disruption. The use of nanostructured silicon materials has been shown to be an effective way to avoid this mechanical degradation of the active material. In this paper the synthesis of silicon nanowires, grown on a highly porous 3D-like carbon paper substrate by CVD using Cu as the catalyst, is presented. The use of carbon paper allows to achieve remarkable loadings of active material (2-5 mg/cm2) and, consequently, high capacity densities. The silicon electrode was investigated both morphologically and electrochemically. To improve the electrochemical performance various strategies have been carried out. It was observed that a very slow first cycle (C/40), which helps the formation of a stable solid electrolyte interphase on the silicon surface, improves the performance of the cells; nevertheless, their cycle life has been found not fully satisfactory. Morphological analysis of the Si-NWs electrodes before and after cycling showed the presence of a dense silicon layer below the nanowires which could reduce the electrical contact between the active material and the substrate

The excess far-infrared emission of active galactic nuclei in the local Universe

We have cross-correlated the Sloan Digital Sky Survey (SDSS) second data release spectroscopic galaxy sample with the IRAS Faint Source Catalogue (FSC). Optical emission line ratios are used to classify the galaxies with reliable IRAS 60- and 100-μm detections into active galactic nuclei (AGN) and normal star-forming galaxies. We then create subsamples of normal galaxies and AGN that are very closely matched in terms of key physical properties such as stellar mass, redshift, size, concentration and mean stellar age (as measured by absorption line indicators in the SDSS spectra). We then quantify whether there are systematic differences between the infrared (IR) luminosities of the galaxies and the AGN in the matched subsamples. We find that the AGN exhibit a significant excess in far-infrared (FIR) emission relative to the star-forming galaxies in our sample. The excesses at 60 and 100 μm are 0.21 ± 0.03 and 0.12 ± 0.035 dex in log L60/M★ and log L100/M★, respectively. We then discuss whether the FIR excess is produced by radiation from the active nucleus that is absorbed by dust or, alternatively, by an extra population of young stars that is not detectable at optical wavelength

Technetium nitrido-peroxo complexes: An unexplored class of coordination compounds

The purpose of this work was to further expand the chemistry of mixed technetium nitrido-peroxo complexes, a still poorly explored class of compounds containing the Tc(VII) moiety, [99gTc][Tc(N)(O2)2]. A number of novel complexes of the formula [99gTc][Tc(N)(O2)2(L)] with bidentate ligands (L) (where L = deprotonated alanine, glycine, proline) were prepared by reacting a solution of nitrido-technetic(VI) acid with L in the presence of a source of H2O2. Alternatively, the complex [99gTc][Tc(N)(O2)2X]- (X = Cl, Br) was used as a precursor for substitution reactions where the halogenide ion was replaced by the bidentate ligand. The new complexes were characterized by elemental analysis and mass spectroscopy. The preparation of the analogous [99mTc][Tc(N)(O2)2] moiety, radiolabeled with the metastable isomer Tc-99m, was also studied at a no-carrier-added level, using S-methyl-N-methyl-dithiocarbazate as the donor of the nitrido nitrogen atoms