3,933 research outputs found

    The Potential of Visible Spectroscopy as a Tool for the In-Line Monitoring of Lignin Methylolation

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    Out of the 50 to 70 million tons of lignin that are produced annually, only 1 to 2% are used for value-added products. Currently, 90% of the total market of this compound corresponds to lignosulphonates (LS). The most successful industrial attempts to use lignin for wood adhesives rely on using it as a partial substitute in phenolformaldehyde or ureaformaldehyde resins. However, lignins aromatic ring presents a low number of reactive sites. Several methods have been proposed to improve its reactivity, such as prior methylolation with formaldehyde. Off-line methods are commonly applied to monitor this reactions progress, but this introduces a significant delay in the analysis. This study proposes a new method for in-line monitoring of the methylolation reaction using visible spectroscopy. In order to monitor the reaction progress, principal component analysis was applied to the spectra, and the obtained scores were analyzed. When these results were plotted against those obtained by the off-line methods, a satisfactory regression was obtained at 50 °C (R2 = 0.97) and 60 °C (R2 = 0.98) for two different LS samples. Therefore, it was concluded that visible spectroscopy is a promising technique for studying lignin methylolation.</jats:p

    Charge-density waves in one-dimensional Hubbard superlattices

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    We study the formation of charge density waves (CDW's) in one-dimensional Hubbard superlattices, modeled by a repeated pattern of repulsive (U>0) and free (U=0) sites. By means of Lanczos diagonalizations for the ground state, we calculate the charge structure factor. Our results show that while the superlattice structure affects the modulation of the charge density waves, the periodicity can still be predicted through an effective density. We also show that, for a fixed repulsive layer thickness, the periodicity of the CDW is an oscillatory function of the free layer thickness.Comment: 4 pages, 4 figure

    The Schwarzschild-de Sitter solution in five-dimensional general relativity briefly revisited

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    We briefly revisit the Schwarzschild-de Sitter solution in the context of five-dimensional general relativity. We obtain a class of five-dimensional solutions of Einstein vacuum field equations into which the four-dimensional Schwarzschild-de Sitter space can be locally and isometrically embedded. We show that this class of solutions is well-behaved in the limit of lambda approaching zero. Applying the same procedure to the de Sitter cosmological model in five dimensions we obtain a class of embedding spaces which are similarly well-behaved in this limit. These examples demonstrate that the presence of a non-zero cosmological constant does not in general impose a rigid relation between the (3+1) and (4+1)-dimensional spacetimes, with degenerate limiting behaviour.Comment: 7 page

    Teegi: Tangible EEG Interface

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    We introduce Teegi, a Tangible ElectroEncephaloGraphy (EEG) Interface that enables novice users to get to know more about something as complex as brain signals, in an easy, en- gaging and informative way. To this end, we have designed a new system based on a unique combination of spatial aug- mented reality, tangible interaction and real-time neurotech- nologies. With Teegi, a user can visualize and analyze his or her own brain activity in real-time, on a tangible character that can be easily manipulated, and with which it is possible to interact. An exploration study has shown that interacting with Teegi seems to be easy, motivating, reliable and infor- mative. Overall, this suggests that Teegi is a promising and relevant training and mediation tool for the general public.Comment: to appear in UIST-ACM User Interface Software and Technology Symposium, Oct 2014, Honolulu, United State

    The 2020 IDS release of the Antwerp COR*-database. Evaluation, development and transformation of a pre-existing database

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    The Antwerp COR*-IDS database 2020 is a transformed and harmonized historical demographic database in a cross-nationally comparable format designed to be open and easy to use for international researchers. The database is constructed from the 2010 release of the Antwerp COR*-historical demographic database, which was created using a letter sample of the whole district of Antwerp (Flanders, Belgium). It has a total sample size of +/- 33,000 residents of Antwerp. The sample spans nearly seven decades. The data is collected from historical records: including population registers and vital registration records covering births, marriages, in/external migrations and deaths. The database covers up to three linked generations (in some cases more), and contains micro-data on individual level life courses, and relationships deriving from addressbased household composition methods. An important characteristic is the sample's large migrant population, including the timings of their demographic events and living arrangements, whilst resident in the district of Antwerp. In addition, the sample also contains a large array of occupational level information. This paper presents the processes, methodologies and documentation regarding the evaluation and development of a pre-existing historical database. This includes the systematic evaluation of the original samples, methodologies for address based reconstructing of households, and the geocoding of a historical database which took place during the current development of this new version of the database.info:eu-repo/semantics/publishedVersio

    Virtual Meson Cloud of the Nucleon and Intrinsic Strangeness and Charm

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    We have applied the Meson Cloud Model (MCM) to calculate the charm and strange antiquark distribution in the nucleon. The resulting distribution, in the case of charm, is very similar to the intrinsic charm momentum distribution in the nucleon. This seems to corroborate the hypothesis that the intrinsic charm is in the cloud and, at the same time, explains why other calculations with the MCM involving strange quark distributions fail in reproducing the low x region data. From the intrinsic strange distribution in the nucleon we have extracted the strangeness radius of the nucleon, which is in agreement with other meson cloud calculations.Comment: 9 pages RevTex, 4 figure

    Potencial de sequestro do carbono em solo pela incorporação de carvão das cascas de frutos da castanha-do-Brasil.

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    Utilizou-se um ensaio de respirometria para estimar o potencial de sequestro de carbono no solo pela incorporação de carvão das cascas de frutos da castanha-do-brasil. Os carvões produzidos a 350ºC, 450ºC e 550°C foram adicionados ao solo contendo microorganismos e paralelamente em meio abiótico, cujos frascos foram vedados para quantificação da evolução do carvão em CO2. O ensaio foi monitorado por 182 dias verificando-se taxas decrescentes de CO2, cujas curvas apresentaram formato logarítmico. Observou-se que no processo abiótico a formação de CO2 é superior quando comparada ao processo biótico, e que o carvão produzido a 550°C apresenta maior taxa de mineralização que os demais carvões. Além disso, verifica-se que todas as amostras de carvão possuem estabilidade no solo a longo prazo
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