2,504 research outputs found
Strong enhancement of superconductivity at high pressures within the charge-density-wave states of 2H-TaS 2 and 2H-TaSe 2
We present measurements of the superconducting and charge density wave
critical temperatures (Tc and TCDW) as a function of pressure in the transition
metal dichalchogenides 2H-TaSe2 and 2H-TaS2. Resistance and susceptibility
measurements show that Tc increases from temperatures below 1 K up to 8.5 K at
9.5 GPa in 2H-TaS2 and 8.2 K at 23 GPa in 2H-TaSe2. We observe a kink in the
pressure dependence of TCDW at about 4 GPa that we attribute to the lock-in
transition from incommensurate CDW to commensurate CDW. Above this pressure,
the commensurate TCDW slowly decreases coexisting with superconductivity within
our full pressure range.Comment: Published in Phys. Rev B 93, 184512 (2016
Far-infrared vibrational properties of linear C60 polymers: A comparison between neutral and charged materials
We report the far-infrared transmittance spectrum of a pure phase of the orthorhombic high-temperature and high-pressure C-60 polymer and compare the results with a previously published spectrum of the charged RbC60 orthorhombic polymer. Assignments for both spectra are made with the aid of first-principles quantum molecular dynamics simulations of the two materials. We find that the striking spectral differences between the neutral and charged linear fullerene polymers can be fully accounted for by charge effects on the C-60 ball
New Superhard Phases for 3D C60-based Fullerites
We have explored new possible phases of 3D C60-based fullerites using
semiempirical potentials and ab-initio density functional methods. We have
found three closely related structures - two body centered orthorhombic and one
body centered cubic - having 52, 56 and 60 tetracoordinated atoms per molecule.
These 3D polymers result in semiconductors with bulk moduli near 300 GPa, and
shear moduli around 240 GPa, which make them good candidates for new low
density superhard materials.Comment: To be published in Physical Review Letter
Novel Phases of Planar Fermionic Systems
We discuss a {\em family} of planar (two-dimensional) systems with the
following phase strucure: a Fermi liquid, which goes by a second order
transition (with non classical exponent even in mean-field) to an intermediate,
inhomogeneous state (with nonstandard ordering momentum) , which in turn goes
by a first order transition to a state with canonical order parameter. We
analyze two examples: (i) a superconductor in a parallel magnetic field (which
was discussed independently by Bulaevskii)for which the inhomogeneous state is
obtained for where is the critical temperature (in Kelvin) of the superconductor
without a field and is measured in Tesla, and (ii) spinless (or, as is
explained, spin polarized) fermions near half-filling where a similar, sizeable
window (which grows in size with anisotropy) exists for the intermediate CDW
phase at an ordering momentum different from . We discuss the
experimental conditions for realizing and observing these phases and the
Renormalization Group approach to the transitions.Comment: ([email protected],[email protected]) 29 p Latex 4 figs
uuencoded separatel
Vibrational spectra of C60C8H8 and C70C8H8 in the rotor-stator and polymer phases
C60-C8H8 and C70-C8H8 are prototypes of rotor-stator cocrystals. We present
infrared and Raman spectra of these materials and show how the rotor-stator
nature is reflected in their vibrational properties. We measured the
vibrational spectra of the polymer phases poly(C60C8H8) and poly(C70C8H8)
resulting from a solid state reaction occurring on heating. Based on the
spectra we propose a connection pattern for the fullerene in poly(C60C8H8),
where the symmetry of the C60 is D2h. On illuminating the C60-C8H8 cocrystal
with green or blue light a photochemical reaction was observed leading to a
similar product to that of the thermal polymerization.Comment: 26 pages, 8 figures, to appear in Journal of Physical Chemistry B 2nd
version: minor changes in wording, accepted version by journa
First order transition and phase separation in pyrochlores with colossal-magnetoresistance
TlMnO pyrochlores present colossal magnetoresistance (CMR)
around the long range ferromagnetic ordering temperature (T). The
character of this magnetic phase transition has been determined to be first
order, by purely magnetic methods, in contrast to the second order character
previously reported by Zhao et al. (Phys. Rev. Lett. 83, 219 (1999)). The
highest CMR effect, as in TlCdMnO, corresponds to a
stronger first order character. This character implies a second type of
magnetic interaction, besides the direct superexchange between the Mn
ions, as well as a phase coexistence. A model is proposed, with a complete
Hamiltonian (including superexchange and an indirect interaction), which
reproduce the observed phenomenology.Comment: 6 pages. Figures include
Band-structure trend in hole-doped cuprates and correlation with Tcmax
By calculation and analysis of the bare conduction bands in a large number of
hole-doped high-temperature superconductors, we have identified the energy of
the so-called axial-orbital as the essential, material-dependent parameter. It
is uniquely related to the range of the intra-layer hopping. It controls the Cu
4s-character, influences the perpendicular hopping, and correlates with the
observed Tc at optimal doping. We explain its dependence on chemical
composition and structure, and present a generic tight-binding model.Comment: 5 pages, Latex, 5 eps figure
Far-infrared study of the Jahn-Teller distorted C60 monoanion in C60 tetraphenylphosphoniumiodide
We report high-resolution far-infrared transmission measurements on C(60)-tetraphenylphosphoniumiodide as a function of temperature. In the spectral region investigated (20-650 cm(-1)), we assign intramolecular modes of the C(60) monoanion and identify low-frequency combination modes. The well-known F(1u)(1) and F(1u)(2) modes are split into doublers at room temperature, indicating a D(5d) or D(3d) distorted ball. This result is consistent with a dynamic Jahn-Teller effect in the strong-coupling limit or with a static distortion stabilized by low-symmetry perturbations. The appearance of silent odd modes is in keeping with symmetry reduction of the hall, while activation of even modes is attributed to interband electron-phonon coupling and orientational disorder in the fulleride salt. Temperature dependences reveal a weak transition in the region 125-150 K in both C(60)(-) and counterion modes, indicating a bulk, rather than solely molecular, effect. Anomalous softening (with decreasing temperature) in several modes may correlate with the radial character of those vibrations. [S0163-1829(98)03245-7]
High temperature superconductivity (Tc onset at 34K) in the high pressure orthorhombic phase of FeSe
We have studied the structural and superconducting properties of tetragonal
FeSe under pressures up to 26GPa using synchrotron radiation and diamond anvil
cells. The bulk modulus of the tetragonal phase is 28.5(3)GPa, much smaller
than the rest of Fe based superconductors. At 12GPa we observe a phase
transition from the tetragonal to an orthorhombic symmetry. The high pressure
orthorhombic phase has a higher Tc reaching 34K at 22GPa.Comment: 15 pages, 4 figure
- âŠ