39 research outputs found
Histoire de la Hongrie médiévale: Des Angevins aux Habsbourgs
Écrit par trois des meilleurs historiens hongrois, le second tome de cette Histoire de la Hongrie médiévale montre comment s\u27est constituée l\u27identité hongroise dans les deux derniers siècles du Moyen Âge. Le royaume s\u27intègre alors dans la chrétienté latine et il connaît un développement rapide de la culture écrite. Ce livre est essentiel pour comprendre l\u27histoire de l\u27Europe du Centre-Est
Structural and magnetic properties of CoPt mixed clusters
In this present work, we report a structural and magnetic study of mixed
Co58Pt42 clusters. MgO, Nb and Si matrix can be used to embed clusters,
avoiding any magnetic interactions between particles. Transmission Electron
Microscopy (TEM) observations show that Co58Pt42 supported isolated clusters
are about 2nm in diameter and crystallized in the A1 fcc chemically disordered
phase. Grazing Incidence Small Angle X-ray Scattering (GISAXS) and Grazing
Incidence Wide Angle X-ray Scattering (GIWAXS) reveal that buried clusters
conserve these properties, interaction with matrix atoms being limited to their
first atomic layers. Considering that 60% of particle atoms are located at
surface, this interactions leads to a drastic change in magnetic properties
which were investigated with conventional magnetometry and X-Ray Magnetic
Circular Dichro\"{i}sm (XMCD). Magnetization and blocking temperature are
weaker for clusters embedded in Nb than in MgO, and totally vanish in silicon
as silicides are formed. Magnetic volume of clusters embedded in MgO is close
to the crystallized volume determined by GIWAXS experiments. Cluster can be
seen as a pure ferromagnetic CoPt crystallized core surrounded by a
cluster-matrix mixed shell. The outer shell plays a predominant role in
magnetic properties, especially for clusters embedded in niobium which have a
blocking temperature 3 times smaller than clusters embedded in MgO
High-order Dy multipole motifs observed in DyB2C2 with resonant soft x-ray Bragg diffraction
Resonant soft x-ray Bragg diffraction at the Dy M4,5 edges has been exploited
to study Dy multipole motifs in DyB2C2. Our results are explained introducing
the intra-atomic quadrupolar interaction between the core 3d and valence 4f
shell. This allows us to determine for the first time higher order multipole
moments of dysprosium electrons and to draw their precise charge density.
The Dy hexadecapole and hexacontatetrapole moment have been estimated at -20%
and +30% of the quadrupolar moment, respectively. No evidence for the lock-in
of the orbitals at T_N has been observed, in contrast to earlier suggestions.
The multipolar interaction and the structural transition cooperate along c but
they compete in the basal plane explaining the canted structure along [110].Comment: 4 pages, 3 figure
Application of relativistic scattering theory of x rays to diffraction anomalous fine structure in Cu
We apply our recent first-principles formalism of magnetic scattering of circularly polarized x rays to a single Cu crystal. We demonstrate the ability of our formalism to interpret the crystalline environment related near-edge fine structure features in the resonant x-ray scattering spectra at the Cu K absorption edge. We find good agreement between the computed and measured diffraction anomalous fine structure features of the x-ray scattering spectra
Advanced glycation inhibition and protection against endothelial dysfunction induced by coumarins and procyanidins from Mammea neurophylla.
Advanced glycation end-products (AGEs) are associated with many pathogenic disorders such as pathogenesis of diabetes or endothelial dysfunction leading to cardiovascular events. Therefore, the identification of new anti-AGE molecules or extracts aims at preventing such pathologies. Many Clusiaceae and Calophyllaceae species are used in traditional medicines to treat arterial hypertension as well as diabetes. Focusing on these plant families, an anti-AGE plant screening allowed us to select Mammea neurophylla for further phytochemical and biological studies. Indeed, both DCM and MeOH stem bark extracts demonstrated in vitro their ability to prevent inflammation in endothelial cells and to reduce vasoconstriction. A bioguided fractionation of these extracts allowed us to point out 4-phenyl- and 4-(1-acetoxypropyl)coumarins and procyanidins as potent inhibitors of AGE formation, potentially preventing endothelial dysfunction. The fractionation steps also led to the isolation of two new compounds, namely neurophyllols A and B from the DCM bark extract together with thirteen known mammea A and E coumarins (mammea A/AA, mammea A/AB, mammea A/BA, mammea A/BB, mammea A/AA cycloD, mammea A/AB cycloD, disparinol B, mammea A/AB cycloE, ochrocarpin A, mammea A/AA cycloF, mammea A/AB cycloF, mammea E/BA, mammea E/BB) as well as δ-tocotrienol, xanthones (1-hydroxy-7-methoxyxanthone, 2-hydroxyxanthone) and triterpenes (friedelin and betulinic acid). During this study, R,S-asperphenamate, previously described from fungal origin was also purified
Charge transport and magnetization profile at the interface between a correlated metal and an antiferromagnetic insulator
A combination of spectroscopic probes was used to develop a detailed
experimental description of the transport and magnetic properties of
superlattices composed of the paramagnetic metal CaRuO and the
antiferromagnetic insulator CaMnO. The charge carrier density and Ru
valence state in the superlattices are not significantly different from those
of bulk CaRuO. The small charge transfer across the interface implied by
these observations confirms predictions derived from density functional
calculations. However, a ferromagnetic polarization due to canted Mn spins
penetrates 3-4 unit cells into CaMnO, far exceeding the corresponding
predictions. The discrepancy may indicate the formation of magnetic polarons at
the interface.Comment: 4 pages, 3 figure
Structural study of an amorphous NiZr2 alloy by anomalous wide angle X-ray scattering and Reverse Monte Carlo simulations
The local atomic structure of an amorphous NiZr2 alloy was investigated using
the anomalous wide-angle x-ray scattering (AWAXS), differential anomalous
scattering (DAS) and reverse Monte Carlo (RMC) simulations techniques. The
AWAXS measurements were performed at eight different incident photon energies,
including some close to the Ni and Zr K edges. From the measurements eight
total structure factor S(K,E) were derived. Using the AWAXS data four
differential structure factors DSFi(K,Em,En) were derived, two about the Ni and
Zr edges. The partial structure factors SNi-Ni(K), SNi-Zr(K) and SZr-Zr(K) were
estimated by using two different methods. First, the S(K,E) and DSFi(K,Em,En)
factors were combined and used in a matrix inversion process. Second, three
S(K,E) factors were used as input data in the RMC technique. The coordination
numbers and interatomic distances for the first neighbors extracted from the
partial structure factors obtained by these two methods show a good agreement.
By using the three-dimensional structure derived from the RMC simulations, the
bond-angle distributions were calculated and they suggest the presence of
distorted triangular-faced polyhedral units in the amorphous NiZr2 structure.
We have used the Warren chemical short-range order parameter to evaluate the
chemical short-range order for the amorphous NiZr2 alloy and for the NiZr2
compound. The calculated values show that the chemical short-range order found
in these two materials is similar to that found in a solid solution.Comment: Submitted to Phys. Rev. B, 8 figure
Interpretation of Differential Anomalous X-Ray Scattering Data for Amorphous Cd-As
The computational procedure, based on Warren's exact method for an amorphous sample with more than one atom, was developed to obtain the short-range order structural parameters from the differential anomalous X-ray scattering data, collected using the synchrotron radiation. The experimental differential radial distribution functions were fitted with the true distribution functions expressed in an analytical form and broadened by convolution with the pair functions. It was found that atoms in the amorphous Cd-As films remain almost tetrahedrally coordinated and the investigated alloys are chemically ordered