Competition from Cu(II), Zn(II) and Cd(II) in Pb(II) binding to Suwannee River Fulvic Acid

This is a study of trace metal competition in the complexation of Pb(II) by well-characterized humic substances, namely Suwannee River Fulvic Acid (SRFA) in model solutions. It was found that Cu(II) seems to compete with Pb(II) for strong binding sites of SRFA when present at the same concentration as Pb(II). However, Cd(II) and Zn(II) did not seem to compete with Pb(II) for strong binding sites of SRFA. These two metals did compete with Pb(II) for the weaker binding sites of SRFA. Heterogeneity of SRFA was found to play a crucial role in metal-SRFA interactions. The environmental significance of this research for freshwater is that even at relatively low Pb(II) loadings, the metals associated with lead in minerals, e.g. Cu(II), may successfully compete with Pb(II) for the same binding sites of the naturally occurring organic complexants, with the result that some of the Pb(II) may exist as free Pb2+ ions, which has been reported to be one of the toxic forms of Pb in aquatic environment

The effect of Pressure in Higher Dimensional Quasi-Spherical Gravitational Collapse

We study gravitational collapse in higher dimensional quasi-spherical Szekeres space-time for matter with anisotropic pressure. Both local and global visibility of central curvature singularity has been studied and it is found that with proper choice of initial data it is possible to show the validity of CCC for six and higher dimensions. Also the role of pressure in the collapsing process has been discussed.Comment: 11 pages, 6 figures, RevTeX styl

Impurity Effects and Spin Polarizations in a Narrow Quantum Hall System

The temperature dependence of electron spin polarization for a narrow quantum Hall system shows behavior analogous to that of a two-dimensional system at major filling factors. At the lowest half-filled quantum Hall state for which no two-dimensional analog exists, we find a stable spin partially-polarized system. Periodic Gaussian repulsive impurities (antidots) in such a system leads to novel spin transitions at $\nu=\frac13$ and $\nu=\frac12$ and the pair-correlation functions provide clues about nature of different ground states in the system. These results can be explored in optical spectroscopy and optically pumped NMR Knight shift measurements.Comment: 4 pages, REVTEX, and 4 .ps file

Determinant Quantum Monte Carlo Study of the Screening of the One Body Potential near a Metal-Insulator Transition

In this paper we present a determinant quantum monte carlo study of the two dimensional Hubbard model with random site disorder. We show that, as in the case of bond disorder, the system undergoes a transition from an Anderson insulating phase to a metallic phase as the onsite repulsion U is increased beyond a critical value U_c. However, there appears to be no sharp signal of this metal-insulator transition in the screened site energies. We observe that, while the system remains metallic for interaction values upto twice U_c, the conductivity is maximal in the metallic phase just beyond U_c, and decreases for larger correlation.Comment: 6 pages, 10 eps figures, Revtex

CP1CP^{1} model with Hopf interaction: the quantum theory

The $CP^1$ model with Hopf interaction is quantised following the Batalin-Tyutin (BT) prescription. In this scheme, extra BT fields are introduced which allow for the existence of only commuting first-class constraints. Explicit expression for the quantum correction to the expectation value of the energy density and angular momentum in the physical sector of this model is derived. The result shows, in the particular operator ordering that we have chosen to work with, that the quantum effect has a divergent contribution of ${\cal O} (\hbar^2)$ in the energy expectation value. But, interestingly the Hopf term, though topological in nature, can have a finite ${\cal O} (\hbar)$ contribution to energy density in the homotopically nontrivial topological sector. The angular momentum operator, however, is found to have no quantum correction, indicating the absence of any fractional spin even at this quantum level. Finally, the extended Lagrangian incorporating the BT auxiliary fields is computed in the conventional framework of BRST formalism exploiting Faddeev-Popov technique of path integral method.Comment: LaTeX, 28 pages, no figures, typos corrected, journal ref. give