Studio di conglomerati bituminosi con granulato di gomma proveniente da pneumatici dismessi

La ricerca di conglomerati bituminosi di elevate prestazioni sovente si associa allo studio delle implicazioni ambientali che la produzione, la posa in opera e l’esercizio di tali materiali comportano. Un aspetto assai importante, in tal senso, è l’opportunità che alcune modalità produttive offrono in termini di un ridotto consumo di inerti e del contestuale impiego di materiali destinati a discarica che, invece, vengono inseriti in processi di riciclaggio. È questo il caso della gomma proveniente dal riciclaggio industriale di pneumatici dismessi che, negli Stati Uniti ed in Canada, è divenuta una fonte sostanziosa per la realizzazione di conglomerati bituminosi. La presente ricerca, dopo una preliminare e sintetica descrizione del granulato di gomma e delle sue proprietà chimico-fisiche, si propone di evidenziare sperimentalmente il comportamento meccanico di conglomerati bituminosi per strati di base confezionati in laboratorio con l’aggiunta di questo componente, mediante i noti processi Dry e Wet, elaborati e combinati secondo opportuni criteri metodologici. In particolare l’indagine verte su prove inserite nell’attuale normativa italiana, con l’obiettivo di pervenire ad un quadro rappresentativo dell’influenza del granulato sulle caratteristiche meccaniche analizzate

Trabajadores Agricolas de Temporada: Inestabilidad laboral y negociacion colectiva

50 p.El presente trabajo analiza el actual régimen jurídico de los trabajadores agrícolas de temporada, particularmente, la estabilidad laboral y la desprotección de los derechos colectivos de los temporeros. Asimismo, conoceremos el derecho comparado español, que establece el régimen jurídico de los trabajadores fijos discontinuos, con el objeto de cotejar ambas realidades y encontrar una solución a los problemas que aquejan al desamparado colectivo de trabajadores agrícolas temporales. Finalmente, la investigación pretende contribuir al mejoramiento tanto de las condiciones de trabajo, como de la eficacia en el ejercicio de los derechos colectivos de los temporeros agrícolas

A dissipated energy comparison to evaluate fatigue resistance using 2PB

Flexural fatigue due to repeated traffic loading is a process of cumulative damage and one of the main failure modes of flexible pavement structures. Typically, micro-cracks originate at the bottom of an asphalt concrete layer due to horizontal tensile strains. Micro-cracking starts to propagate towards the upper layers under repeated loading which can lead to pavement failure. Different approaches are usually used to characterise fatigue resistance in asphalt mixtures including the phenomenological approach, the fracture mechanics approach and the dissipated energy approach. This paper presents a comparison of fatigue resistance calculated for different dissipated energy models using 2 Point Bending (2PB) at IFSTTAR in Nantes. 2PB tests have been undertaken under different loading and environmental conditions in order to evaluate the properties of the mixtures (stiffness, dissipated energy, fatigue life and healing effect)

Gravitational radiation reaction and inspiral waveforms in the adiabatic limit

We describe progress evolving an important limit of binary orbits in general relativity, that of a stellar mass compact object gradually spiraling into a much larger, massive black hole. These systems are of great interest for gravitational wave observations. We have developed tools to compute for the first time the radiated fluxes of energy and angular momentum, as well as instantaneous snapshot waveforms, for generic geodesic orbits. For special classes of orbits, we compute the orbital evolution and waveforms for the complete inspiral by imposing global conservation of energy and angular momentum. For fully generic orbits, inspirals and waveforms can be obtained by augmenting our approach with a prescription for the self force in the adiabatic limit derived by Mino. The resulting waveforms should be sufficiently accurate to be used in future gravitational-wave searches.Comment: Accepted for publication in Phys. Rev. Let

Monitoring Micelle Formation in Mixtures of Linear and Foldon-capped Polypeptides with Light Scattering Spectroscopy

Elastin-like polypeptide (ELP) polymers are ideal for producing environmentally responsive micellar systems because they exhibit a transition from being water-soluble at low temperatures to phase-separated at high temperatures. For application development of drug delivery vehicles and biosensing nanoparticles, it is important to prepare spherical micelles of controlled diameter and shape. Since at a given salt concentration, the headgroup area for each foldon should be constant, the size of the micelles is expected to be proportional to the volume of the linear ELP available per foldon headgroup. Therefore, adding linear ELPs to a system of ELP-foldon should result in changes of the micelle volume. At higher salts the electrostatic repulsion between headgroups is shielded, reducing the effective size of foldon headgroups, increasing the packing factor of micelles which leads to formation of non-spherical micelles. The effects of addition of linear ELPs on size, shape, and molecular weight of micelles at different salt concentrations were studied by a combination of Depolarized Dynamic Light Scattering (DDLS) and Static Light Scattering (SLS) Spectroscopies. The initial results on 50 μM ELPfoldon samples (at 25 mM salt) show that the apparent hydrodynamic radius of mixed micelles increases more than 5-fold as the amount of linear ELP raised from 0 to 50 μM. The size increase is accompanied by significant increase in depolarized scattering indicating the growing geometrical anisotropy of the micelles with increase of added linear ELP. In addition, the increase of the amount of linear ELP in the mixed micelles significantly increased the relative molecular weight of the micelles.https://engagedscholarship.csuohio.edu/u_poster_2014/1024/thumbnail.jp

Gravitational wave snapshots of generic extreme mass ratio inspirals

Using black hole perturbation theory, we calculate the gravitational waves produced by test particles moving on bound geodesic orbits about rotating black holes. The orbits we consider are generic - simultaneously eccentric and inclined. The waves can be described as having radial, polar, and azimuthal "voices", each of which can be made to dominate by varying eccentricity and inclination. Although each voice is generally apparent in the waveform, the radial voice is prone to overpowering the others. We also compute the radiative fluxes of energy and axial angular momentum at infinity and through the event horizon. These fluxes, coupled to a prescription for the radiative evolution of the Carter constant, will be used in future work to adiabatically evolve through a sequence of generic orbits. This will enable the calculation of inspiral waveforms that, while lacking certain important features, will approximate those expected from astrophysical extreme mass ratio captures sufficiently well to aid development of measurement algorithms on a relatively short timescale.Comment: Minor changes in response to comments from readers, referees, and editors. Final version, as it will appear in Physical Review D. Raw data and a small program which will convert the data into waveforms lasting for arbitrary lengths of time can be found at http://gmunu.mit.edu/sdrasco/snapshot

Controlling Micelle Formation Using Mixtures of Linear and Foldon-capped Polypeptides (ELP): Measurements with UV-vis Spectroscopy

Polymer surfactants developed in our lab have a protein headgroup (foldon) and three elastin-like polypeptide (ELP) tails. They can form micelles smaller than 30 nm, which may be useful in developing targeted drug delivery vehicles. Specifically, ELPs are capped with foldon, which is a 27 amino acid sequence that folds as a homotrimer, resulting in a three-armed star polypeptide. This structure has been shown to form micelles above the transition temperature (Tt) of the ELP. The salt concentration affects the interaction between the headgroups affecting how the micelles assemble. At low salt concentrations the ELP-foldon will form spherical micelles; whereas, at higher salt concentrations the micelles are non-spherical, as is demonstrated by light scattering. When linear ELP is mixed with ELP foldon, it is expected that the ELP-foldon will stabilize small droplets of linear ELP in the form of a microemulsion. Different ratios of ELP-foldon to linear ELP were prepared and their transition behavior was characterized using turbidity measured with UV-vis spectroscopy. The turbidity increased at the Tt of the ELP, and then dropped substantially at the Tt of the ELPfoldon. Increased concentration of the linear ELP increased the measured turbidity level after both transitions, suggesting an increase in aggregate size. Light scattering was utilized to further characterize the size and shape of the aggregates formed.https://engagedscholarship.csuohio.edu/u_poster_2014/1013/thumbnail.jp

Axiomatic approach to radiation reaction of scalar point particles in curved spacetime

Several different methods have recently been proposed for calculating the motion of a point particle coupled to a linearized gravitational field on a curved background. These proposals are motivated by the hope that the point particle system will accurately model certain astrophysical systems which are promising candidates for observation by the new generation of gravitational wave detectors. Because of its mathematical simplicity, the analogous system consisting of a point particle coupled to a scalar field provides a useful context in which to investigate these proposed methods. In this paper, we generalize the axiomatic approach of Quinn and Wald in order to produce a general expression for the self force on a point particle coupled to a scalar field following an arbitrary trajectory on a curved background. Our equation includes the leading order effects of the particle's own fields, commonly referred to as ``self force'' or ``radiation reaction'' effects. We then explore the equations of motion which follow from this expression in the absence of non-scalar forces.Comment: 17 pages, 1 figur

Fatigue resistance: is it possible having a unique response?

The mechanical characterisation of the asphalt concrete in terms of both the fatigue resistance and the stiffness modulus is necessary to use any design method of the flexible road pavements. Different kinds of test are usually used in experimental work such as bending tests, uniaxial tests, etc., but sometimes they do not give the same answer. In this paper mechanical characterization was carried out by means of fatigue tests undertaken with two most used testing machines for asphalt material: two point bending (2PB) test at IFSTTAR in Nantes (France) and four point bending (4PB) test at University of Palermo, in Palermo (Italy). Different strain controlled tests were undertaken for the same material under the same loading conditions, frequency and temperature (15 Hz and 20˚C), according to the European standard 12697 part 24 and 26. The first results of this interlaboratory activity are showed in this paper