Properties of carbon fibers with various coatings

It is shown that all high modulus carbon fibers are durable with respect to thermal oxidation in air. Among the more widely used and economical materials with low modulus, Celion displays particularly good oxidative durability at high temperatures. This contrast to other materials is due to the low content of Natrium and Kalium in Celion carbon fibers. It is also noted that improved characteristics are attained in Celion carbon fiber/polyimide systems when fibers are used with high temperature resistant polyimide coatings

Reverse Shock Emission as a Probe of GRB Ejecta

We calculate the reverse shock (RS) synchrotron emission in the optical and the radio wavelength bands from electron-positron pair enriched gamma-ray burst ejecta with the goal of determining the pair content of GRBs using early time observations. We take into account an extensive number of physical effects that influence radiation from the reverse-shock heated GRB ejecta. We find that optical/IR flux depends very weakly on the number of pairs in the ejecta, and there is no unique signature of ejecta pair enrichment if observations are confined to a single wavelength band. It may be possible to determine if the number of pairs per proton in the ejecta is > 100 by using observations in optical and radio bands; the ratio of flux in the optical and radio at the peak of each respective reverse-shock light curve is dependent on the number of pairs per proton. We also find that over a large parameter space, RS emission is expected to be very weak; GRB 990123 seems to have been an exceptional burst in that only a very small fraction of the parameter space produces optical flashes this bright. Also, it is often the case that the optical flux from the forward shock is brighter than the reverse shock flux at deceleration. This could be another possible reason for the paucity of prompt optical flashes with a rapidly declining light curve at early times as was seen in 990123 and 021211. Some of these results are a generalization of similar results reported in Nakar & Piran (2004).Comment: 12 pages, 6 figures, 2 tables, accepted to MNRA

Effects of fiber/matrix interactions on the properties of graphite/epoxy composites

A state-of-the-art literature review of the interactions between fibers and resin within graphite epoxy composite materials was performed. Emphasis centered on: adhesion theory; wetting characteristics of carbon fiber; load transfer mechanisms; methods to evaluate and measure interfacial bond strengths; environmental influence at the interface; and the effect of the interface/interphase on composite performance, with particular attention to impact toughness. In conjunction with the literature review, efforts were made to design experiments to study the wetting behavior of carbon fibers with various finish variants and their effect on adhesion joint strength. The properties of composites with various fiber finishes were measured and compared to the base-line properties of a control. It was shown that by tailoring the interphase properties, a 30% increase in impact toughness was achieved without loss of mechanical properties at both room and elevated temperatures

The effect of training with weightlifting catching or pulling derivatives on squat jump and countermovement jump force–time adaptations

The purpose of this study was to examine the changes in squat jump (SJ) and countermovement jump (CMJ) force−time curve characteristics following 10 weeks of training with either load-matched weightlifting catching (CATCH) or pulling derivatives (PULL) or pulling derivatives that included force- and velocity-specific loading (OL). Twenty-five resistance-trained men were randomly assigned to the CATCH, PULL, or OL groups. Participants completed a 10 week, group-specific training program. SJ and CMJ height, propulsion mean force, and propulsion time were compared at baseline and after 3, 7, and 10 weeks. In addition, time-normalized SJ and CMJ force−time curves were compared between baseline and after 10 weeks. No between-group differences were present for any of the examined variables, and only trivial to small changes existed within each group. The greatest improvements in SJ and CMJ height were produced by the OL and PULL groups, respectively, while only trivial changes were present for the CATCH group. These changes were underpinned by greater propulsion forces and reduced propulsion times. The OL group displayed significantly greater relative force during the SJ and CMJ compared to the PULL and CATCH groups, respectively. Training with weightlifting pulling derivatives may produce greater vertical jump adaptations compared to training with catching derivatives

Exposure of Larvae of the Solitary Bee Osmia bicornis to the Honey Bee Pathogen Nosema ceranae Affects Life History

Wild bees are important pollinators of wild plants and agricultural crops and they are threatened by several environmental stressors including emerging pathogens. Honey bees have been suggested as a potential source of pathogen spillover. One prevalent pathogen that has recently emerged as a honey bee disease is the microsporidian Nosema ceranae. While the impacts of N. ceranae in honey bees are well documented, virtually nothing is known about its effects in solitary wild bees. The solitary mason bee Osmia bicornis is a common pollinator in orchards and amenable to commercial management. Here, we experimentally exposed larvae of O. bicornis to food contaminated with N. ceranae and document spore presence during larval development. We measured mortality, growth parameters, and timing of pupation in a semi-field experiment. Hatched individuals were assessed for physiological state including fat body mass, wing muscle mass, and body size. We recorded higher mortality in the viable-spore-exposed group but could only detect a low number of spores among the individuals of this treatment. Viable-spore-treated individuals with higher head capsule width had a delayed pupation start. No impact on the physiological status could be detected in hatched imagines. Although we did not find overt evidence of O. bicornis infection, our findings indicate that exposure of larvae to viable N. ceranae spores could affect bee development

DNA fingerprinting analysis of coagulase negative staphylococci implicated in catheter related bloodstream infections

AIMS: The epidemiological assessment of cases of coagulase negative staphylococcal catheter related bloodstream infection. METHODS: Two hundred and thirty patients with suspected catheter related bloodstream infection were evaluated over a two year period. Central venous catheters were cultured both endoluminally and extraluminally. Peripheral blood, catheter hubs, skin entry, and skin control sites were also cultured. Pulsed field gel electrophoresis (PFGE) was used to DNA fingerprint coagulase negative staphylococci isolated from patients with presumptive catheter related bloodstream infection. RESULTS: Sixty cases of catheter related bloodstream infection were identified, 21 of which were attributed to coagulase negative staphylococci. Two hundred and ninety four separate isolates of coagulase negative staphylococci from the 21 cases of catheter related bloodstream infection were subjected to PFGE (mean of 14 for each case). Catheter related bloodstream infection was only confirmed by PFGE analysis in 16 of the 21 cases because in the remaining five cases peripheral blood and central venous catheter coagulase negative staphylococci isolates were different. Skin entry, control skin, and central venous catheter hub isolates matched peripheral blood isolates in six, four, and seven cases, respectively. Coagulase negative staphylococci isolates could not be cultured from the patients’ own skin in seven cases of catheter related bloodstream infection. Central venous catheter lumens were colonised in all cases of catheter related bloodstream infection compared with 44–81% of cases that had positive external surface catheter tip cultures, depending on the threshold used to define significant growth. CONCLUSIONS: Catheter related bloodstream infection as a result of coagulase negative staphylococci may be over stated in about a quarter of cases, unless a discriminatory technique is used to fingerprint isolates. No single, simplistic route of bacterial contamination of central venous catheters was identified, but endoluminal catheter colonisation is invariably present in cases of catheter related bloodstream infection. The use of central venous catheters as a means of access for monitoring and as a route of administration of drugs has become almost mandatory in patients with serious illnesses. Infections of central venous catheters are common and coagulase negative staphylococci remain the most frequent pathogens—for example, 37% of 1267 isolates in one meta-analysis.Controversy remains over the source of, and route of access by, these bacteria to the central venous catheters. Recent developments, such as catheters with antimicrobial properties, are an important advance, but until such issues are resolved it remains unclear how best to reduce the risk of catheter related bloodstream infection. “Pulsed field gel electrophoresis is well recognised as the gold standard for fingerprinting coagulase negative staphylococci” Because there are at least 33 distinct coagulase negative staphylococci species that have been identified, and because methods that use phenotyping alone cannot accurately distinguish between strains of coagulase negative staphylococci, DNA fingerprinting is required to clarify the epidemiology of coagulase negative staphylococci catheter related bacterial bloodstream infection. Despite the accepted difficulties in determining the relatedness of coagulase negative staphylococci, diagnostic laboratories routinely rely on limited information from phenotypic tests to compare isolates fro

A structural systematic study of three isomers of difluoro-N-(4-pyridyl)benzamide

The isomers 2,3-, (I), 2,4-, (II), and 2,5-difluoro-N-(4-pyridyl)benzamide, (III), all with formula C₁₂H₈F₂N₂O, all exhibit intramolecular C-H...O=C and N-H...F contacts [both with S(6) motifs]. In (I), intermolecular N-H...O=C interactions form one-dimensional chains along [010] [N...O = 3.0181 (16) Å], with weaker C-H...N interactions linking the chains into sheets parallel to the [001] plane, further linked into pairs via C-H...F contacts about inversion centres; a three-dimensional herring-bone network forms via C-H...π(py) (py is pyridyl) interactions. In (II), weak aromatic C-H...N(py) interactions form one-dimensional zigzag chains along [001]; no other interactions with H...N/O/F < 2.50 Å are present, apart from long N/C-H...O=C and C-H...F contacts. In (III), N-H...N(py) interactions form one-dimensional zigzag chains [as C(6) chains] along [010] augmented by a myriad of weak C-H...π(arene) and O=C...O=C interactions and C-H...O/N/F contacts. Compound (III) is isomorphous with the parent N-(4-pyridyl)benzamide [Noveron, Lah, Del Sesto, Arif, Miller & Stang (2002). J. Am. Chem. Soc. 124, 6613-6625] and the three 2/3/4-fluoro-N-(4-pyridyl)benzamides [Donnelly, Gallagher & Lough (2008). Acta Cryst. C64, o335-o340]. The study expands our series of fluoro(pyridyl)benzamides and augments our understanding of the competition between strong hydrogen-bond formation and weaker influences on crystal packing