Nanoscale roughness and morphology affect the IsoElectric Point of titania surfaces

We report on the systematic investigation of the role of surface nanoscale roughness and morphology on the charging behaviour of nanostructured titania (TiO2) surfaces in aqueous solutions. IsoElectric Points (IEPs) of surfaces have been characterized by direct measurement of the electrostatic double layer interactions between titania surfaces and the micrometer-sized spherical silica probe of an atomic force microscope in NaCl aqueous electrolyte. The use of a colloidal probe provides well-defined interaction geometry and allows effectively probing the overall effect of nanoscale morphology. By using supersonic cluster beam deposition to fabricate nanostructured titania films, we achieved a quantitative control over the surface morphological parameters. We performed a systematical exploration of the electrical double layer properties in different interaction regimes characterized by different ratios of characteristic nanometric lengths of the system: the surface rms roughness Rq, the correlation length {\xi} and the Debye length {\lambda}D. We observed a remarkable reduction by several pH units of IEP on rough nanostructured surfaces, with respect to flat crystalline rutile TiO2. In order to explain the observed behavior of IEP, we consider the roughness-induced self-overlap of the electrical double layers as a potential source of deviation from the trend expected for flat surfaces.Comment: 63 pages, including 7 figures and Supporting Informatio

Il Programma P.I.P.P.I.: un\u2019innovazione scientifica e sociale come risposta alla vulnerabilit\ue0 delle famiglie,

This article presents the aims and the structure of the Program P.I.P.P.I., a major social innovation, promoted by the Ministry of Labor and Social Policies with the Laboratory of Research and Intervention in Family Education (LabRIEF) of the University of Padua. Launched in 2011, it is today the most important experimentation ever made in Italy in the field of social policies. The aim is harmonizing practices and models of intervention addressed to neglecting families through training, documentation and systematic evaluation, shared throughout the entire country. It is based on the recognition of parental neglecting as a space of special opportunity to put forward prevention interventions, in particular compliance with Laws 285/1997, 328/2000 and 149/2001. It falls within the lines developed by the Agenda 2030 for Sustainable Development about innovation and social experimentation as a means to overcome social inequalities by experimenting actions capable of developing positive parenting (REC 2006/19 / EU), widespread in the living environment of children who live in vulnerable conditions, so as to "break the cycle of social disadvantage"

Light-time computations for the BepiColombo radioscience experiment

The radioscience experiment is one of the on board experiment of the Mercury ESA mission BepiColombo that will be launched in 2014. The goals of the experiment are to determine the gravity field of Mercury and its rotation state, to determine the orbit of Mercury, to constrain the possible theories of gravitation (for example by determining the post-Newtonian (PN) parameters), to provide the spacecraft position for geodesy experiments and to contribute to planetary ephemerides improvement. This is possible thanks to a new technology which allows to reach great accuracies in the observables range and range rate; it is well known that a similar level of accuracy requires studying a suitable model taking into account numerous relativistic effects. In this paper we deal with the modelling of the space-time coordinate transformations needed for the light-time computations and the numerical methods adopted to avoid rounding-off errors in such computations.Comment: 14 pages, 7 figures, corrected reference

Nanofriction behavior of cluster-assembled carbon films

We have characterized the frictional properties of nanostructured (ns) carbon films grown by Supersonic Cluster Beam Deposition (SCBD) via an Atomic Force-Friction Force Microscope (AFM-FFM). The experimental data are discussed on the basis of a modified Amonton's law for friction, stating a linear dependence of friction on load plus an adhesive offset accounting for a finite friction force in the limit of null total applied load. Molecular Dynamics simulations of the interaction of the AFM tip with the nanostructured carbon confirm the validity of the friction model used for this system. Experimental results show that the friction coefficient is not influenced by the nanostructure of the films nor by the relative humidity. On the other hand the adhesion coefficient depends on these parameters.Comment: 22 pages, 6 figures, RevTex

Low-frequency modes in the Raman spectrum of sp-sp2 nanostructured carbon

A novel form of amorphous carbon with sp-sp2 hybridization has been recently produced by supersonic cluster beam deposition showing the presence in the film of both polyynic and cumulenic species [L. Ravagnan et al. Phys. Rev. Lett. 98, 216103 (2007)]. Here we present a in situ Raman characterization of the low frequency vibrational region (400-800 cm-1) of sp-sp2 films at different temperatures. We report the presence of two peaks at 450 cm-1 and 720 cm-1. The lower frequency peak shows an evolution with the variation of the sp content and it can be attributed, with the support of density functional theory (DFT) simulations, to bending modes of sp linear structures. The peak at 720 cm-1 does not vary with the sp content and it can be attributed to a feature in the vibrational density of states activated by the disorder of the sp2 phase.Comment: 15 pages, 5 figures, 1 tabl

Optimal uniform strength design of frame and lattice structures

This paper provides a procedure to obtain the uniform strength of frame and lattice structures. Uniform strength condition is achieved by performing the shape optimization of all beam elements of the structure. The beam shape which guarantees uniform strength is analytically deduced from the one-dimensional Timoshenko model. The optimization problem presents itself as the search for the zeros of the objective-functions vector, which is a non-linear system of equations representing the kinematic-congruence and forces balance at every node of the structure. The analytical formulation of the optimization problem allows to construct the objective-functions vector without the use of external structural computation, i.e. not recurring to any Finite Element Analysis to accomplish iterations. This latter feature entails a great advantage in terms of computing time required to perform optimization. The proposed analytical formulation allows to directly insert the uniform strength condition into the objective-functions vector, transforming the optimization into an unconstrained problem. Some examples are shown in which the performance of the optimization procedure is discussed in terms of robustness and rate of computational complexity while increasing the degrees of freedom of the structure. The reliability and the quality of the optimization are verified through Finite Element Analysis

Joint Stiffness Influence on the First-Order Seismic Capacity of Dry-Joint Masonry Structures: Numerical DEM Investigations

Heritage masonry structures are often modelled as dry-jointed structures. On the one hand, it may correspond to the reality where the initial mortar was weak, missing, or has disappeared through time because of erosion and lixiviation. On the other hand, this modelling approach reduces complexity to the studied problem, both from an experimental and theoretical/numerical point of views, while being conservative. Still, for modelling purposes, in addition to the joint friction, numerical approaches require a specific elastic parameter, the dry-joint stiffness, which is often hard to estimate experimentally. This work numerically investigates the effect of the joint stiffness on the collapse of scaled-down tilting test experiments carried out on perforated dry-joint masonry shear walls. It is found that geometrical imperfections of bricks and the absence of vertical precompression load can lead to very low equivalent dry-joint stiffness, which strongly affects the results, both in terms of collapse and damage limit state (DLS) loads, with practical implications for the engineering practice

The large amplitude outburst of the young star HBC 722 in NGC 7000/IC 5070, a new FU Orionis candidate

We report the discovery of a large amplitude outburst from the young star HBC 722 (LkHA 188 G4) located in the region of NGC 7000/IC 5070. On the basis of photometric and spectroscopic observations, we argue that this outburst is of the FU Orionis type. We gathered photometric and spectroscopic observations of the object both in the pre-outburst state and during a phase of increase in its brightness. The photometric BVRI data (Johnson-Cousins system) that we present were collected from April 2009 to September 2010. To facilitate transformation from instrumental measurements to the standard system, fifteen comparison stars in the field of HBC 722 were calibrated in the BVRI bands. Optical spectra of HBC 722 were obtained with the 1.3-m telescope of Skinakas Observatory (Crete, Greece) and the 0.6-m telescope of Schiaparelli Observatory in Varese (Italy). The pre-outburst photometric and spectroscopic observations of HBC 722 show both low amplitude photometric variations and an emission-line spectrum typical of T Tau stars. The observed outburst started before May 2010 and reached its maximum brightness in September 2010, with a recorded Delta V~4.7 mag. amplitude. Simultaneously with the increase in brightness the color indices changed significantly and the star became appreciably bluer. The light curve of HBC 722 during the period of rise in brightness is similar to the light curves of the classical FUors - FU Ori and V1057 Cyg. The spectral observations during the time of increase in brightness showed significant changes in both the profiles and intensity of the spectral lines. Only H alpha remained in emission, while the H beta, Na I 5890/5896, Mg I triplet 5174, and Ba II 5854/6497 lines were in strong absorption.Comment: 4 pages, 6 figures, accepted for publication in A&