Dynamics of immersed molecules in superfluids

The dynamics of a molecule immersed in a superfluid medium are considered. Results are derived using a classical hydrodynamic approach followed by canonical quantization. The classical model, a rigid body immersed in incompressible fluid, permits a thorough analysis; its effective Hamiltonian generalizes the usual rigid-rotor Hamiltonian. In contrast to the free rigid rotor, the immersed body is shown to have chaotic dynamics. Quantization of the classical model leads to new and experimentally verifiable features. It is shown, for instance, that chiral molecules can behave as "quantum propellers": the rotational-translational coupling induced by the superfluid leads to a nonzero linear momentum in the ground state. Hydrogen peroxide is a strong candidate for experimental detection of this effect. The signature is a characteristic splitting of rotational absorption lines. The 1_{01} --> 1_{10} line in hydrogen peroxide, for example, is predicted to split into three lines separated by as much as 0.01 cm^{-1}, which is about the experimental linewidth.Comment: 10 pages, 3 figure

A Fast Scan Submillimeter Spectroscopic Technique

A new fast scan submillimeter spectroscopic technique (FASSST) has been developed which uses a voltage tunable backward wave oscillator (BWO) as a primary source of radiation, but which uses fast scan (~105 Doppler limited resolution elements/s) and optical calibration methods rather than the more traditional phase or frequency lock techniques. Among its attributes are (1) absolute frequency calibration to ~1/10 of a Doppler limited gaseous absorption linewidth (\u3c0.1 MHz, 0.000 003 cm-1), (2) high sensitivity, and (3) the ability to measure many thousands of lines/s. Key elements which make this system possible include the excellent short term spectral purity of the broadly (~100 GHz) tunable BWO; a very low noise, rapidly scannable high voltage power supply; fast data acquisition; and software capable of automated calibration and spectral line measurement. In addition to the unique spectroscopic power of the FASSST system, its implementation is simple enough that it has the prospect of impacting a wide range of scientific problems

Detection of interstellar hydrogen peroxide

The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph A. By observing several transitions of HOOH in the (sub)millimeter regime we seek to identify the molecule and also to determine the excitation conditions through a multilevel excitation analysis. We have detected three spectral lines toward the SM1 position of {\rho} Oph A at velocity-corrected frequencies that coincide very closely with those measured from laboratory spectroscopy of HOOH. A fourth line was detected at the 4{\sigma} level. We also found through mapping observations that the HOOH emission extends (about 0.05 pc) over the densest part of the {\rho} Oph A cloud core. We derive an abundance of HOOH relative to that of H_2 in the SM1 core of about 1\times10^(-10). To our knowledge, this is the first reported detection of HOOH in the interstellar medium.Comment: 5 pages, 4 figures, accepted for publication in Astronomy & Astrophysics, new version corrects a typo in Table 1 (and consequently in Fig 4

Channel sounding and indoor radio channel characteristics in the W-band

This work presents directional radio channel measurements in the W-band using a commercial versatile channel sounder based on a vector network analyzer (VNA), capable of measuring scattering parameters from 75 to 500 GHz with frequency converters. The commercial setup has been modified by increasing the distance for one of the converters using precision coaxial cables and avoiding the use of amplifiers. Firstly, initial distance-dependent single-input single-output (SISO) measurements of indoor radio channels are presented to assess the validity of the setup in the 75 110 GHz frequency band with highly directive horn antennas. Then, single-input multiple-output (SIMO) radio channels were measured at 94 GHz using one directional and one omnidirectional antenna mounted on two positioners. Initial channel characterization is presented comprising root mean square (rms) delay spread, rms angular spread, K-factor, and path loss in an indoor environment at 94 GHz.This work was supported by MINECO, Spain (TEC2013-47360-C3-2-P TEC2013-47360-C3-3-P) and by European FEDER funds.Martínez Inglés, M.; Gaillot, D.; Pascual-García, J.; Molina-García-Pardo, JM.; Rodriguez Rodriguez, JV.; Rubio Arjona, L.; Juan Llacer, L. (2016). Channel sounding and indoor radio channel characteristics in the W-band. EURASIP Journal on Wireless Communications and Networking. 30:1-8. doi:10.1186/s13638-016-0530-7S1830D Zico, Ultra-wideband and 60 GHz communications for biomedical applications. Springer. http://link.springer.com/book/10.1007%2F978-1-4614-8896-5 .L Jofre, J Romeu, S Capdevila, J Abril, E Nova, M Alonso, The “challenging” world of Terahertz radiation and imaging. Proceedings of the 5th European Conference on Antennas and Propagation (EUCAP), 2011, pp. 3470–3475M Kawase, “Non-destructive evaluation method of pharmaceutical tablet by terahertz-time-domain spectroscopy: application to sound-alike medicines”, J. Infrared Millimeter Terahertz Waves, 34(9), 566–571KD Anderson, 94 GHz propagation in the evaporation duct. IEEE Trans. Antennas Propag. 38(5), 746–753 (1990)K Aydin, Y-M Lure, Millimeter wave scattering and propagation in rain: a computational study at 94 and 140 GHz for oblate spheroidal and spherical raindrops. IEEE Trans. Geosci. Remote Sens. 29(1), 593–601 (1991)C Gloaguen, An experiment for propagation studies at 94 GHz. Eighth Int. Conf. Antennas Propagation 1, 406–409 (1993)A Kajiwara, “Indoor propagation measurements at 94 GHz,” personal, indoor and mobile radio communications, 1995. Sixth IEEE Int. Symp PIMRC’95. Wireless Merging Inf. Superhighway 3, 1026 (1995)J Helminger, J Detlefsen, H Groll, Propagation properties of an indoor-channel at 94 GHz. Int. Conf. Microw Millimeter Wave Technol.Proc 98, 9–14 (1998)R Piesiewicz, R Geise, M Jacob, J Jemai, T Kurner, “Indoor channel measurements of point-to-point ultra broadband short range links between 75 GHz and 110 GHz”, in International Symposium Antennas and Propagation Society, 2008, pp. 1–4A Brizzi, A Pellegrini, Y Hao, “Experimental characterization of the propagation on the human torso at W band”, in Radio Science Meeting (Joint with AP-S Symposium), USNC-URSI, 2013, p. 39K Haneda, J Järveläinen, A Karttunen, M Kyro, J Putkonen, Indoor short-range radio propagation measurements At 60 and 70 GHz, in EuCAP 2014, The Hague, The Netherlands, 2014, pp. 1–4S Promwong, J Takada, Free space link budget estimation scheme for ultra wideband impulse radio with imperfect antennas. IEICE Electronics Express 1(7), 188–192 (2004)NL Johnson, S Kotz, N Balakrishnan, Continuous univariate distributions, vol. 1 (Wiley-Interscience, Hoboken, 1993)A Richter, Estimation of radio channel parameters: models and algorithms (Dr.-Ing. dissertation, TU Ilmenau, Ilmenau, Germany, 2005

MILLIMETER AND SUBMILLIMETER SPECTROSCOPY OF CHLORINE NITRATE: THE Cl QUADRUPOLE TENSOR AND THE HARMONIC FORCE FIELD

Author Institution: Jet Propulsion Laboratory, California Institute of Technology; Department of Physics, University of South Alabama; Department of Chemistry, University of South AlabamaThe rotational spectrum of $CIONO_{2}$ has been (re-) investigated in the millimeter and submillimeter regions in the ground vibrational and first excited torsional states for both $^{35}$Cl and $^{37}$Cl isotopomers. A large number of $a$- and $b$-type $R$- and $Q$-branch as well as $b$-type $P$-branch transitions have been observed. This has enabled the improvement of the spectroscopic constants and the prediction of lines in the submillimeter region. Accidental near-degeneracies of rotational levels allowed the observation of a $\Delta J = 2$ transition and the precise determination of the off-diagonal quadrupole coupling constant $\chi_{ab}$. The quartic distortion constants along with the vibrational wavenumbers and inertial defects have been used to calculate a harmonic force field. The results will be related to the molecular structure determined from an electron diffraction study and to data from related molecules such as $Cl_{2}O$

Infrared Simulations Derived from Submillimeter Wave Analyses

Author Institution: Department of Physics, Wright State University, Dayton OH 45435; Department of Physics, Pittsburg State University, Pittsburg, KS 66726; Department of Physics, University of South Alabama, Mobile, AL 36688; Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warszawa, Poland; Earth Science Division, NASA Headquarters, Washington, DC 20546; Department of Physics, The Ohio State University, Columbus, OH 43210The analysis of infrared spectra of heavy molecules is challenging due to partially resolved transitions and overlapping hot bands. Quite often it is necessary to analyze jet-cooled spectra, perform a band contour analysis, or empirically measure the cross sections to provide analyses for inclusion into spectral databases for atmospheric remote sensing applications. The specificity of the pure rotational spectra in the submillimeter wave region enables the determination of the rotational manifolds of many thermally populated vibrational states. The resulting analyses provide spectral constants to directly simulate the infrared spectrum and model the Q/P/R branch transitions, account for the temperature dependence of the spectrum, and aid in the assignment and determination of band centers and transitions moments of both the fundamental and the associated hot bands. We will demonstrate the utility of this approach by discussing recent advances in the simulation of the infrared spectrum of nitric acid and chlorine nitrate

MICROWAVE ROTATION-INVERSION SPECTRUM OF NT3 NT_{3}

Author Institution: Department of Physics, Duke University Durham; Staats Oak Ridge National Laboratory, Duke University DurhamBecause of the relative difficulty of preparation and handling of molecules containing tritium, few spectroscopic investigations of such molecules have been reported. One molecule containing tritium which is of particular interest to microwave spectroscopists in $NT_{3}$ because of the possibility of observing splitting in the rotational spectrum de to inversion. We report the measurement by microwave techniques of several rotational transitions of $NT_{3}$ in the millimeter and submillimeter wave length region, and the detection of the inversion splitting. Tentative rotation, distortion, and inversion parameters calculated from these measurements are being refined by further measurements. Work at Duke University is supported by the National Science Foundation, Grant GP-34590