Controlling factors on clay mineral assemblages: insights from facies analysis of Pliocene to Pleistocene coastal margin deposits, Western Portugal

The clay fractions in the Pliocene to Pleistocene coastal margin record are usually dominated by kaolinite and illite, with lesser amounts of vermiculite, 10-14 mixed layer clays and smectite. The high clay mineral crystallinity, the mineralogical relations to facies and depositional setting and some horizontal variations along coeval deposits suggest that clay assemblages are mainly detrital. Illite is more important in inner shelf deposits and particularly in alluvial deposits from eastern locations. The high illite content in eastern alluvial deposits is explained by the input from the neighbouring Iberian Variscan Massif that is rich in mica. The high kaolinite content in prograding sand and gravel coastal plain is partially explained by the availability of this mineral in the drainage areas. Given the arkosic nature of some of these deposits, post-depositional feldspars weathering would also contribute to an increase in kaolinite content. Vermiculite is particularly important close to the surface and to unconformities, in horizons influenced by pedogenetic processes that have more aluminous illite with relatively low crystallinity. In organic rich mud sediments low pH conditions favour post-depositional transformation of illite to vermiculite and mixed layer clays

Late Quaternary warm marine mollusks from Santa Maria (Azores); paleoecologic and paleobiogeographic considerations

The sub-fossil fauna from the Late Quaternary marine deposits of Santa Maria is made of more than 50 species of gastropods and bivalves, 19 of them collected recently and for the first time in the northern coast of the island (Lagoinhas Bay). The sub-fossil shells are found in deposits of beach sands, situated 2-3 meters above the present low tide. The carbonated sands from the basal part of the succession yield an autochthonous association of borers dominated by the bivalve Myoforceps aristata (Dillwin, 1817). Upwards, the marine sands contain concentrations of beach drift shells, including well-preserved supratidal and intertidal gastropods, among them a large number of Rissoidae. The bivalve fauna is dominated by disarticulated valves of Ervilia castanea (Montagu, 1803), a small infaunal coloniser of mobile sandy substrates. The composition of the fauna is made essentially of West European species, many of them common to the West Coast of Portugal. However, a few "warm guests" with West African or Caribbean affinities were also found, suggesting a close relation with some of the "Tyrrhenian" warm associations found in the Western Mediterranean

Production of metallic nanoparticles, from industrial residues, by the use of different types of reduction gases

The need to enhance and reuse existing materials on secondary sources of metals has had quite an impact in recent times. Several processes and technologies had being studied for recovery of raw materials from industrial waste generated. This study focuses on the possibility of waste reducing, from the galvanic floor covering industry, with the aim of obtaining micro or nano-particles of nickel or a nickel based alloy. Sludges from one galvanic treatment plant were used as base material in two conditions: as produced and after a hydrometallurgical treatment for metal concentration. Several reducing agents were used in this study: a synthesis gas from a polymer pyrolysis and solid polymer agents (PVC, HDPE and PP residues). Obtained products were characterised in terms of metallic particles production during the reduction treatment and by SEM/EDS analysis on the final products. A simultaneous differential thermal and thermogravimetric equipment (DSC/TGA) was used for the study of the reduction process with a reduction gas obtained from the pyrolysis of chlorine free PVC derived char. The obtained results show that it is possible to obtain small metallic particles, in the range of 60 to 240 nm, at 800 ºC. Reduction tests, by the use of a solid residue, were made in a laboratorial furnace with two independent heating zones. Best results were obtained with de-chlorinated PVC as a reduction agent with the production of metallic particles, in the range of 150 to 600 nm, at 800 ºC. For all the tested conditions the metallic particles were constituted by Ni and Cu with variable chemical composition

Problemas atuais da juticultura amazônica.

No presente trabalho, os autores procuraram expor os problemas atuais que entravam o desenvolvimento da juticultura amazônica, ressaltando a importância marcante da produção das fibras desta tiliácea como fonte da manutenção do mercado interno brasileiro de matéria prima necessária ao abastecimento do parque nacional de aniagem. Os problemas considerados, no trabalho em questão, foram: 1) problemas de ordem agrícola, 2) problemas de ordem sócio-econômica. Procurou-se, também, de forma sintética, expor a situação do mercado nacional e as possibilidades de exportação. Como conclusão, os autores admitem a necessidade urgente e prioritária de se estimular econômicamente o juticultor a fim de que se possa posteriormente mostrar que a quantidade e qualidade do produto depende em grande parte dos problemas culturais e tecnológicos.Separata da Pesquisa Agropecuária Brasileira, v. 1, p. 1-6, 1966

Strong evidences for a nonextensive behavior of the rotation period in Open Clusters

Time-dependent nonextensivity in a stellar astrophysical scenario combines nonextensive entropic indices $q_{K}$ derived from the modified Kawaler's parametrization, and $q$, obtained from rotational velocity distribution. These $q$'s are related through a heuristic single relation given by $q\approx q_{0}(1-\Delta t/q_{K})$, where $t$ is the cluster age. In a nonextensive scenario, these indices are quantities that measure the degree of nonextensivity present in the system. Recent studies reveal that the index $q$ is correlated to the formation rate of high-energy tails present in the distribution of rotation velocity. On the other hand, the index $q_{K}$ is determined by the stellar rotation-age relationship. This depends on the magnetic field configuration through the expression $q_{K}=1+4aN/3$, where $a$ and $N$ denote the saturation level of the star magnetic field and its topology, respectively. In the present study, we show that the connection $q-q_{K}$ is also consistent with 548 rotation period data for single main-sequence stars in 11 Open Clusters aged less than 1 Gyr. The value of $q_{K}\sim$ 2.5 from our unsaturated model shows that the mean magnetic field topology of these stars is slightly more complex than a purely radial field. Our results also suggest that stellar rotational braking behavior affects the degree of anti-correlation between $q$ and cluster age $t$. Finally, we suggest that stellar magnetic braking can be scaled by the entropic index $q$.Comment: 6 pages and 2 figures, accepted to EPL on October 17, 201

Float-polishing process and analysis of float-polished quartz

A fluid-mechanical model is developed for the float-polishing process. In this model laminar flow between the sample and the lap results in pressure gradients at the grooves that support the sample on a fluid layer. The laminar fluid motion also produces supersmooth, damage-free surfaces. Quartz substrates for applications in high-stress environments were float polished, and their surfaces were analyzed by optical scatterometry, photoacoustic spectroscopy, and atomic force microscopy. The removal of 100 µm of material by a lapping-polishing process, with final float polishing, left low levels of subsurface damage, with a surface roughness of approximately 0.2-nm rms

The Farol Deposit (Depósito do Farol) – a Pleistocene beach deposit from Cape Mondego (Figueira da Foz, West Central Portugal)*

Among the Pleistocene and Holocene units recorded near the marine cliffs of Cape Mondego (Figueira da Foz, West Central Portugal) stands out the Farol Deposit (Depósito do Farol), at an altitude of ±95 m above present sea level. It is a marine terrace with three exposures of interstratified conglomerates and sands, overlapped by calclititic-fanglomerates. This sedimentary setting indicates that deposition took place in a seashore environment influenced by the proximity of a marine palaeocliff. The deposit has an interesting subfossil fauna with abraded and fragmented shells of Nucella lapillus (LINNÉ, 1758), Patella vulgata (LINNÉ, 1758) and Littorina littorea (LINNÉ, 1758), suggesting the existence of an environment with colder surface seawater, when compared with the present day Portuguese seashore. These specimens belonged to marine communities adapted to live in intertidal rocky platforms, which have been exposed to the cyclic action of waves and tidal flows, on the swash and surf zones. The Farol Deposit can be related to an Early/Middle Pleistocene “cold-water” episode, earlier to the Isotopic Stages 7 and 11. This episode occurred before the deposition of the units Quiaios Sands (Areias de Quiaios) and Cantanhede Sands (Areias de Cantanhede) (Sicilian?), but later than the Arazede Sands (Areias de Arazede) and Marinha das Ondas Sands (Areias de Marinha das Ondas) (Early Pleistocene)