123 research outputs found
Discovery of Li2(Pd,Pt)3B superconductors
Critical temperature Tc of the Li2(Pd1-xPtx)3B was reported to be 7-8K for
x=0 and 2.2-2.8K for x=1. In this article we present our preliminary results on
behavior of magnetization-temperature curves with starting composition of Pd-B
precursor, y-Li concentration in LiyPd3B and post-annealing of the Pd-end
compound. Results suggest that to maximize Tc ratio Pd:B should be close to
3:1, while y-Li has to be optimum. The lowest Tc for LiyPd3B was 4.4-4.6K,
while post-annealings at 560 deg. C allowed enhancement of Tc up to 8.2-8.4K.
Compositions Li2Z3B with Z=Ni, Ru, Rh, Re, Ag are not superconducting down to
1.8K. Exception is composition with Re showing superconductivity due to Re3B
compound. All samples were prepared by arc melting.Comment: 6 pages, 5 figs. presented at M2S, 200
Non-centro-symmetric superconductors Li2Pd3B and Li2(Pd0.8Pt0.2)3B: amplitude and phase fluctuations analysis of the experimental magnetization data
We report on magnetization data obtained as a function of temperature and
magnetic field in Li2 (Pd0.8Pt0.2)3B and Li2Pd3B non-centro-symmetric
superconductors. Reversible magnetization curves were plotted as M1/2 vs. T.
This allows study of the asymptotic behavior of the averaged order parameter
amplitude (gap) near the superconducting transition. Results of the analysis
show, as expected, a mean field superconducting transition for Li2Pd3B. On
contrary, a large deviation from the mean field behavior is revealed for
Li2(Pd0.8Pt0.2)3B. This is interpreted as due to the strength of the non s-wave
spin-triplet pairing in this Pt-containing compound which produces nodes in the
order parameter and consequently, phase fluctuations. The diamagnetic signal
above Tc(H) in Li2Pd3B is well explained by superconducting Gaussian
fluctuations, which agrees with the observed mean field transition. For
Li2(Pd0.8Pt0.2)3B the diamagnetic signal above Tc(H) is much higher than the
expected Gaussian values and appears to be well explained by three dimensional
critical fluctuations of the lowest-Landau-level type, which somehow agrees
with the scenario of a phase mediated transition.Comment: 7 pages (1 column) 3 figure
A Penetration Depth Study on Li2Pd3B and Li2Pt3B
In this paper we present a penetration depth study on the newly discovered
superconductors LiPdB and LiPtB. Surprisingly, the
low-temperature penetration depth demonstrates distinct behavior in
these two isostructural compounds. In LiPdB, follows an
exponential decay and can be nicely fitted by a two-gap BCS superconducting
model with a small gap K and a large gap K.
However, linear temperature dependence of is observed in LiPtB
below 0.3, giving evidence of line nodes in the energy gap.Comment: 2 pages, submitted to LT2
Superconductivity in metal rich Li-Pd-B ternary Boride
8K superconductivity was observed in the metal rich Li-Pd-B ternary system.
Structural, microstructural, electrical and magnetic investigations for various
compositions proved that Li2Pd3B compound, which has a cubic structure composed
of distorted Pd6B octahedrons, is responsible for the superconductivity. This
is the first observation of superconductivity in metal rich ternary borides
containing alkaline metal and Pd as a late transition metal. The compound
prepared by arc melting has high density, is stable in the air and has an upper
critical field, Hc2(0), of 6T.Comment: 4 pages, 5 figur
Landau and Ott scaling for the kinetic energy density and the low conventional superconductors, and Nb
The scaling approach recently proposed by Landau and Ott for isothermal
magnetization curves is extended to the average kinetic energy density of the
condensate. Two low superconductors, Nb and are studied
and their isothermal reversible magnetization shown to display Landau and Ott
scaling. Good agreement is obtained for the upper critical field ,
determined from the Abrikosov approximation for the reversible region (standard
linear extrapolation of the magnetization curve), and from the maximum of the
kinetic energy curves. For the full range of data, which includes the
irreversible region, the isothermal curves for show an
impressive collapse into a single curve over the entire range of field
measurements. The Nb isothermal curves exhibit the interesting
feature of a constant and temperature independent minimum value
Evidence of large anisotropy in the magnetization of Na0.35CoO2.1.3H2O quasi-single-crystal superconductors
Quasi-single crystals (up to 2x2x1 mm3) of Na0.35CoO2.1.3H2O-superconductor
have been grown. Magnetization M(H, T) and M(T, H) curves with magnetic field
approximately parallel and perpendicular to c-axis indicates on large
anisotropy, comparable with Bi-based high-temperature superconducting (HTS)
phases.Comment: 14 pages, 4 figure
Full Bulk Spin Polarization and Intrinsic Tunnel Barriers at the Surface of Layered Manganites
Transmission of information using the spin of the electron as well as its
charge requires a high degree of spin polarization at surfaces. At surfaces
however this degree of polarization can be quenched by competing interactions.
Using a combination of surface sensitive x-ray and tunneling probes, we show
for the quasi-two-dimensional bilayer manganites that the outermost Mn-O
bilayer, alone, is affected: it is a 1-nm thick insulator that exhibits no
long-range ferromagnetic order while the next bilayer displays the full spin
polarization of the bulk. Such an abrupt localization of the surface effects is
due to the two-dimensional nature of the layered manganite while the loss of
ferromagnetism is attributed to weakened double exchange in the reconstructed
surface bilayer and a resultant antiferromagnetic phase. The creation of a
well-defined surface insulator demonstrates the ability to naturally
self-assemble two of the most demanding components of an ideal magnetic tunnel
junction.Comment: 19 pages, 5 figure
Temperature Dependent Polarized XANES Spectra for Zn-doped LSCO system
The cuprates seem to exhibit statistics, dimensionality and phase transitions
in novel ways. The nature of excitations [i.e. quasiparticle or collective],
spin-charge separation, stripes [static and dynamics], inhomogeneities,
psuedogap, effect of impurity dopings [e.g. Zn, Ni] and any other phenomenon in
these materials must be consistently understood. Zn-doped LSCO single crystal
were grown by TSFZ technique. Temperature dependent Polarized XANES [near edge
local structure] spectra were measured at the BL13-B1 [Photon Factory] in the
Flourescence mode from 10 K to 300 K. Since both stripes and nonmagnetic Zn
impurities substituted for Cu give rise to inhomogeneous charge and spin
distribution it is interesting to understand the interplay of Zn impurities and
stripes. To understand these points we have used Zn-doping and some of the
results obtained are as follows: The spectra show a strong dependence with
respect to the polarization angle, , as is evident at any temperature
by comparing the spectra where the electric field vector is parallel with
ab-plane to the one where it is parallel to the c-axis. By using the XANES
[temperature] difference spectra we have determined T* [experimentally we find,
T* 160-170 K] for this sample. The XANES difference spectra shows
that the changes in XANES features are larger in the ab-plane than the c-axis,
this trend is expected since zinc is doped in the ab-plane at the copper site.
Our study also complements the results in literature namely that zinc doping
does not affect the c-axis transport.Comment: To appear in Physica C [ISS2001 Special Issue], related talk
presented at ISS2001 as PC-16, 10 pages revtex and 7 pages of figures (pdf
Magnetization measurements on Li2Pd3B superconductor
Magnetization in DC magnetic fields and at different temperatures have been
measured on the Li2Pd3B compound. This material was recently found to show
superconductivity at 7-8K. Critical fields Hc1(0) and Hc2(0) have been
determined to be 135Oe and 4T, respectively. Critical current density, scaling
of the pinning force within the Kramer model and the irreversibility field data
are presented. Several superconductivity parameters were deduced: x(csi)=9.1
nm, l(lamda)=194nm and k=21. The material resembles other boride
superconductors from the investigated points of view.Comment: 10 pages, 5 figure
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