A spatially resolved fluid-solid interaction model for dense granular packs/Soft-Sand.

Fluid flow through dense granular packs or soft sands can be described as a Darcy’ s flow for low injection rates, as the friction between grain-grain and grain-walls dominate the solid system behaviour. For high injection rates, fluid forces can generate grain displacement forming flow channels or “fractures”, which in turn modify local properties within the system, such as permeability and stress distribution. Due to this kind of “self organized” behaviour, a spatially resolved model for these interactions is required to capture the dynamics of these systems. In this work, we present a resolved model based on the approach taken by the CFDEM open source project which uses LIGGGHTS – a discrete elements method (DEM)– to model the granular behaviour and OpenFoam finite volume library for computational fluid dynamics (CFD), to simulate the fluid behaviour. The capabilities provided by the DEM engine allows the properties of the solid phase, such as inter-grain cohesion and solid confinement stress to be controlled. In this work the original solver provided by the CFDEM project was modified so as to deal with dense granular packs more effectively. Advantages of the approach presented are that it does not require external “scaling parameters” to reproduce well known properties of porous materials and that it inherits the performance provided by the CFDEM project. The model is validated by reproducing the well-known properties of static porous materials, such as its permeability as a function of the system porosity, and by calculating the drag coefficient for a sphere resting inside a uniform flow. Finally, we present fracture patterns obtained when modelling water injection into a Hele-Shaw cell, filled with a dense granular pack

Ulcerative colitis: let's talk about extent

Ulcerative colitis (UC) is a chronic inflammatory disease in which clinical course varies substantially between patients. The extent of the disease is usually pointed out as one of the factors responsible for this variation. With this study, we pretended to evaluate the differences in natural history and pharmacological therapy prescription between left-sided and extended UC

Studies on the mouldability of structural foams in hybrid moulds

In the context of the research project Hybridmould 21, studies on the mouldability of structural foams using hybrid moulds have been carried out. Hybrid injection moulds are an increasingly considered alternative for prototype series or short production runs of large dimension parts. In this solution for injection moulds the moulding elements (blocks or other inserts) are manufactured in alternative metallic materials or in synthetic materials typically using rapid prototyping techniques. Structural foams, known since the 70s, are moulded by injection moulding without using the high pressures typically used in injection moulding. The formation of the structural foam results from the dispersed gaseous phase, which derives from the expansion of a chemical blowing agent usually compounded in a compatible masterbatch. In this project various thermoplastics and thermosets were used, namely, PP, ABS and PUR, us-ing a hybrid mould instrumented for the monitoring of temperature, pressure and expansion force. The mould-ing block was manufactured by vacuum casting of an epoxy composite. In this paper are mainly discussed the results obtained on liquid injection moulding polyurethane resins in the hybrid mould.QREN contract 2010/013307 – Project Hybridmould 2

Self-Organized Ordering of Nanostructures Produced by Ion-Beam Sputtering

We study the self-organized ordering of nanostructures produced by ion-beam sputtering (IBS) of targets amorphizing under irradiation. By introducing a model akin to models of pattern formation in aeolian sand dunes, we extend consistently the current continuum theory of erosion by IBS. We obtain new non-linear effects responsible for the in-plane ordering of the structures, whose strength correlates with the degree of ordering found in experiments. Our results highlight the importance of redeposition and surface viscous flow to this nanopattern formation process.Comment: 4 pages, 2 figure

PEAKTRAMS: An automated computational approach for the simultaneous detection of features in reverse phase and hilic hrms screening

Comparison of chromatograms obtained in reserved phase (RP) liquid chromatography and hydrophilic interaction liquid chromatography (HILIC) can provide valuable information for the identification and confirmation of suspect and non-target compounds. The plausibility of the obtained chromatographic retention times (RTs) in both modes as well as the ψomparison of the MS/MS spectra are strong points to be considered. This work presents the development of a novel automatic approach for the identification of common peaks between RP and HILIC chromatograms. The core of the program is written in R-project while a simple and user friendly graphical user interface (GUI) was built in JAVA. The first step consists of the introduction of the target chromatograms of the same sample (one obtained by RP and one by HILIC) plus the corresponding blank chromatograms. Blank subtraction was performed first using an algorithm to find in each scan the common m/z features (with a given mass accuracy). This algorithm also considers the RTs (a tolerance interval is applied), so the subtraction takes place even with slight drifts in the RTs between target and blank chromatograms. After blank subtraction, two different lists are obtained with the detected peaks in both RP and HILIC modes. Subsequently, m/z values are compared and matches are listed. The developed workflow was validated with solvent standards and with spiked wastewater samples with a mixture of compounds with a wide range of physicochemical properties. Successful results were obtained for 26 out of the 27 evaluated substances, allowing the recording of the corresponding RTs in both RP and HILIC mode

High intensity tapping regime in a frustrated lattice gas model of granular compaction

In the frame of a well established lattice gas model for granular compaction, we investigate the high intensity tapping regime where a pile expands significantly during external excitation. We find that this model shows the same general trends as more sophisticated models based on molecular dynamic type simulations. In particular, a minimum in packing fraction as a function of tapping strength is observed in the reversible branch of an annealed tapping protocol.Comment: 5 pages, 4 figure

Coulomb explosion sputtering of selectively oxidized Si

We have studied multiply charged Arq+ ion induced potential sputtering of a unique system comprising of coexisting Silicon and Silicon oxide surfaces. Such surfaces are produced by oblique angle oxygen ion bombardment on Si(100), where ripple structures are formed and one side of each ripple gets more oxidized. It is observed that higher the potential energy of Arq+ ion, higher the sputtering yield of the non conducting (oxide) side of the ripple as compared to the semiconducting side. The results are explained in terms of Coulomb explosion model where potential sputtering depends on the conductivity of the ion impact sites.Comment: 9 pages and 3 figure

Investigating participation in Advanced level mathematics: a study of student drop out

There has for some years been a growing concern about participation in university-entrance level mathematics in England and across the developed world. Extensive statistical analyses present the decline but offer little to help us understand the causes. In this paper we explore a concern which cannot be explored through national datasets, namely the retention of mathematics students on Advanced level mathematics courses. Drawing on survey data from fifteen secondary schools in the Midlands of England, we examine subject differences in decisions to study, withdraw from, and continue in a range of A level subjects. Not only is the rate of attrition from mathematics higher than most other subjects, but there are substantial differences between schools. In order to explore this high rate of attrition further we consider one school – Queensbury Park - in which a large proportion of students decided not to continue with their study of mathematics from year 12 to 13. Drawing on performance data and focus group interviews we explore some of the reasons for the students’ decisions