Flow injection determination of readily assimilable nitrogen compounds during vinification

A flow injection method for the determination of readily assimilable nitrogen (r.a.n.), i.e. ammonium and aminated nitrogen, is reported. The difference in pH of the sample in the presence and absence of formaldehyde, which blocks the amino function, provides the value of r.a.n. by monitoring the changes in absorbance of bromothymol blue at 616 nm. The detection and quantification limits are 10 and 11.6 mg l-1, respectively; the reproducibility and repeatability are 3.94 mg l-1 and 1.35 mg l-1, respectively; and the sample throughput is 20 samples h-1. The method has been applied to the analysis of 120 samples of must and wine subjected to biological aging. The proposed method also provides good correlation with the reference method used in routine analysis, and it is faster and gives sufficient precision for wineries requirements

An unusual pi* shape resonance in the near-threshold photoionization of S(1) para-difluorobenzene

Previously reported dramatic changes in photoelectron angular distributions (PADs) as a function of photoelectron kinetic energy following the ionization of S1 p-difluorobenzene are shown to be explained by a shape resonance in the b(2g) symmetry continuum. The characteristics of this resonance are clearly demonstrated by a theoretical multiple-scattering treatment of the photoionization dynamics. New experimental data are presented which demonstrate an apparent insensitivity of the PADs to both vibrational motion and prepared molecular alignment, however, the calculations suggest that strong alignment effects may nevertheless be recognized in the detail of the comparison with experimental data. The apparent, but unexpected, indifference to vibrational excitation is rationalized by considering the nature of the resonance. The correlation of this shape resonance in the continuum with a virtual pi* antibonding orbital is considered. Because this orbital is characteristic of the benzene ring, the existence of similar resonances in related substituted benzenes is discussed.Bellm, SM: Davies, JA: Whiteside, PT; Guo, J: Powis, I; and Reid KL

Patterns of variability in voice onset time: a developmental study of motor speech skills in humans

This study investigated the developmental patterns of variability in the speech parameter voice onset time (VOT) in forty six children. Five groups of children participated in the study as follows: i) Group 1 - aged 5 years 8 months (n=6); ii) Group 2 - 7 years 10 months (n=10); iii) Group 3 - 9 years 10 months (n=10); iv) Group 4 - 11 years 10 months (n=10), and v) Group 5 - 13 years 2 months (n=10). Coefficient of variation (COV) values were examined for the VOT values of both "voiceless" (/p t k/) and "voiced" (/b d g/) plosives to determine patterns of variability. Significant effects of age were revealed for both the voiceless and voiced plosives, and levels of variability leveled off for Group 4. The data suggest that although variability in VOT decreases with age, the presence of residual variability may be a prerequisite for the further refinement of motor speech skills

Sex-specific fundamental and formant frequency patterns in a cross-sectional study

An extensive developmental acoustic study of the speech patterns of children and adults was reported by Lee and colleagues [Lee et al., J. Acoust. Soc. Am. 105, 1455-1468 (1999)]. This paper presents a reexamination of selected fundamental frequency and formant frequency data presented in their report for 10 monophthongs by investigating sex-specific and developmental patterns using two different approaches. The first of these includes the investigation of age- and sex-specific formant frequency patterns in the monophthongs. The second, the investigation of fundamental frequency and formant frequency data using the critical band rate (bark) scale and a number of acoustic-phonetic dimensions of the monophthongs from an age- and sex-specific perspective. These acoustic-phonetic dimensions include: vowel spaces and distances from speaker centroids; frequency differences between the formant frequencies of males and females; vowel openness/closeness and frontness/backness; the degree of vocal effort; and formant frequency ranges. Both approaches reveal both age- and sex-specific development patterns which also appear to be dependent on whether vowels are peripheral or non-peripheral. The developmental emergence of these sex-specific differences are discussed with reference to anatomical, physiological, sociophonetic and culturally determined factors. Some directions for further investigation into the age-linked sex differences in speech across the lifespan are also proposed

Use of ERTS data for a multidisciplinary analysis of Michigan resources

The author has identified the following significant results. The results of this investigation of ratioing simulated ERTS spectral bands and several non-ERTS bands (all collected by an airborne multispectral scanner) indicate that significant terrain information is available from band-ratio images. Ratio images, which are based on the relative spectral changes which occur from one band to another, are useful for enhancing differences and aiding the image interpreter in identifying and mapping the distribution of such terrain elements as seedling crops, all bare soil, organic soil, mineral soil, forest and woodlots, and marsh areas. In addition, the ratio technique may be useful for computer processing to obtain recognition images of large areas at lower costs than with statistical decision rules. The results of this study of ratio processing of aircraft MSS data will be useful for future processing and evaluation of ERTS-1 data for soil and landform studies. Additionally, the results of ratioing spectral bands other than those currently collected by ERTS-1 suggests that some other bands (particularly a thermal band) would be useful in future satellites

Hormones and temporal components of speech: sex differences and effects of menstrual cyclicity on speech

Voice onset time (VOT) is a salient acoustic parameter of speech which signals the “voiced” and “voiceless” status of plosives in English (e.g. the initial sound in ‘bat’ vs. the initial sound in ‘pat’). As a micro-temporal acoustic parameter, VOT may be sensitive to changes in hormones which may affect the neuromuscular systems involved in speech production. This study adopted a novel approach by investigating the effects of menstrual cycle phase and sex on VOT. VOT data representing the 6 plosives of English (/p b t d k g/) were examined for 7 women (age 20-23 years) at two phases of the menstrual cycle (day 18-25: High Estrogen and Progesterone; day 2-5: Low Estrogen and Progesterone). Results indicated that menstrual cycle phase had a significant interaction with the identity of the plosive (F (5,30) = 5.869, P .05), or the contrast between voiced and voiceless cognates (F (1,10) = .407, P > .05). In contrast, the high hormone phase VOT samples displayed significant plosive by sex interactions (F (5,50) = 4.442, P < .005). In addition, significant sex differences were found for the contrasts between cognate voiced and voiceless plosives (F (1,10) = 5.019, P < .05); the women displayed a more marked voiced/voiceless contrast. The findings suggest that ovarian hormones play some role in shaping some temporal components of speech

Bark and Hz scaled F2 Locus equations: Sex differences and individual differences

This study investigated speaker sex differences in F2 Locus equations (F2 LEs) based on linearly (Hz) and tonotopically (Bark) scaled formant measurements. F2 data based on English monosyllabic words produced by thirteen women and eleven men were tonotopically scaled and F2 LEs were derived for both the linear and tonotopically scaled formant values. Although the overall sex difference in the F2 LE slope values for women and men was significant for both sets of F2 measures, the magnitude of this difference decreased for the Bark (.047) compared to the Hz (.063) scale. The individual data revealed a significant correlation between the slope values of the Hz and Bark scale [r = .974; p<.0001] suggesting a lawful relationship between the two metrics. Further probing revealed that the F2 LE data from women were affected more by the Bark conversion than the data from men

Towards practical classical processing for the surface code: timing analysis

Topological quantum error correction codes have high thresholds and are well suited to physical implementation. The minimum weight perfect matching algorithm can be used to efficiently handle errors in such codes. We perform a timing analysis of our current implementation of the minimum weight perfect matching algorithm. Our implementation performs the classical processing associated with an nxn lattice of qubits realizing a square surface code storing a single logical qubit of information in a fault-tolerant manner. We empirically demonstrate that our implementation requires only O(n^2) average time per round of error correction for code distances ranging from 4 to 512 and a range of depolarizing error rates. We also describe tests we have performed to verify that it always obtains a true minimum weight perfect matching.Comment: 13 pages, 13 figures, version accepted for publicatio

Failure of a Dredged Slope in a Sensitive Clay

During construction of a new wharf facility in Portland, Maine, an underwater slope failed during dredging and subsequent driving of piles through the slope. The construction and failure of the slope are described. The major factors which contributed to the failure were: 1) high sensitivity of the silty clay, 2) placement of riprap on the crest of the slope to 4 to 6 ft above the design elevation, 3) method of dredging which caused high shear stresses and probable disturbed zones near the toe of the slope, 4) dredging slope steeper than design slope, 5) pile driving causing localized disturbed zones with low strength around the piles, and 6) sequence of dredging and pile driving