ARXPS-studies ofcˆ-axis textured YBa2Cu3Ox-films

YBa2Cu3Ox sputter deposited cold on MgO grows in O2 annealing epitaxially to a transparent, superconducting film with Tc 80K. The unscraped surfaces of these films are smooth showing XPS lines changing with photoelectron take-off angle. This enhanced data base allows to separate the different chemical compounds (hydroxide, peroxide, carbonate, carboxyle, cuprate, graphite ...) and to obtain their spatial distribution. This yields the compounds, their amount and distribution making up the cinder growing with O2-anneal at internal and external surfaces. The cinder stoichiometry gives insights in the chemistry going on in O2 annealing. Below the cinder the signature ofcˆ-axis oriented YBa2Cu3Ox is identified, showing that a Ba-oxide layer forms the stable surface. This coats insulating CuO2 and Y-oxide layers yielding so an intrinsic dead layer

A Large Systematic Search for Close Supermassive Binary and Rapidly Recoiling Black Holes - II. Continued Spectroscopic Monitoring and Optical Flux Variability

We present new spectroscopic observations that are part of our continuing monitoring campaign of 88 quasars at z<0.7 whose broad H$\beta$ lines are offset from their systemic redshifts by a few thousand km/s. These quasars have been considered candidates for hosting supermassive black hole binaries (SBHBs) by analogy with single-lined spectroscopic binary stars. We present the data and describe our improved analysis techniques, which include an extensive evaluation of uncertainties. We also present a variety of measurements from the spectra that are of general interest and will be useful in later stages of our analysis. Additionally, we take this opportunity to study the variability of the optical continuum and integrated flux of the broad H$\beta$ line. We compare the variability properties of the SBHB candidates to those of a sample of typical quasars with similar redshifts and luminosities observed multiple times during the Sloan Digital Sky Survey. We find that the variability properties of the two samples are similar (variability amplitudes of 10-30% on time scales of approximately 1-7 years) and that their structure functions can be described by a common model with parameters characteristic of typical quasars. These results suggest that the broad-line regions of SBHB candidates have a similar extent as those of typical quasars. We discuss the implications of this result for the SBHB scenario and ensuing constraints on the orbital parameters.Comment: 19 pages in ApJ format. Accepted for publication in the Astrophysical Journal Supplement

BLUF Domain Function Does Not Require a Metastable Radical Intermediate State

BLUF (blue light using flavin) domain proteins are an important family of blue light-sensing proteins which control a wide variety of functions in cells. The primary light-activated step in the BLUF domain is not yet established. A number of experimental and theoretical studies points to a role for photoinduced electron transfer (PET) between a highly conserved tyrosine and the flavin chromophore to form a radical intermediate state. Here we investigate the role of PET in three different BLUF proteins, using ultrafast broadband transient infrared spectroscopy. We characterize and identify infrared active marker modes for excited and ground state species and use them to record photochemical dynamics in the proteins. We also generate mutants which unambiguously show PET and, through isotope labeling of the protein and the chromophore, are able to assign modes characteristic of both flavin and protein radical states. We find that these radical intermediates are not observed in two of the three BLUF domains studied, casting doubt on the importance of the formation of a population of radical intermediates in the BLUF photocycle. Further, unnatural amino acid mutagenesis is used to replace the conserved tyrosine with fluorotyrosines, thus modifying the driving force for the proposed electron transfer reaction; the rate changes observed are also not consistent with a PET mechanism. Thus, while intermediates of PET reactions can be observed in BLUF proteins they are not correlated with photoactivity, suggesting that radical intermediates are not central to their operation. Alternative nonradical pathways including a keto–enol tautomerization induced by electronic excitation of the flavin ring are considered

The wavefront of the radio signal emitted by cosmic ray air showers

Analyzing measurements of the LOPES antenna array together with corresponding CoREAS simulations for more than 300 measured events with energy above $10^{17}\,$eV and zenith angles smaller than $45^\circ$, we find that the radio wavefront of cosmic-ray air showers is of approximately hyperbolic shape. The simulations predict a slightly steeper wavefront towards East than towards West, but this asymmetry is negligible against the measurement uncertainties of LOPES. At axis distances $\gtrsim 50\,$m, the wavefront can be approximated by a simple cone. According to the simulations, the cone angle is clearly correlated with the shower maximum. Thus, we confirm earlier predictions that arrival time measurements can be used to study the longitudinal shower development, but now using a realistic wavefront. Moreover, we show that the hyperbolic wavefront is compatible with our measurement, and we present several experimental indications that the cone angle is indeed sensitive to the shower development. Consequently, the wavefront can be used to statistically study the primary composition of ultra-high energy cosmic rays. At LOPES, the experimentally achieved precision for the shower maximum is limited by measurement uncertainties to approximately $140\,$g/cm$^2$. But the simulations indicate that under better conditions this method might yield an accuracy for the atmospheric depth of the shower maximum, $X_\mathrm{max}$, better than $30\,$g/cm$^2$. This would be competitive with the established air-fluorescence and air-Cherenkov techniques, where the radio technique offers the advantage of a significantly higher duty-cycle. Finally, the hyperbolic wavefront can be used to reconstruct the shower geometry more accurately, which potentially allows a better reconstruction of all other shower parameters, too.Comment: accepted by JCA