19,600 research outputs found
Interplay between the magnetic anisotropy contributions of Cobalt nanowires
We report on the magnetic properties and the crystallographic structure of
the cobalt nanowire arrays as a function of their nanoscale dimensions. X-ray
diffraction measurements show the appearance of an in-plane HCP-Co phase for
nanowires with 50 nm diameter, suggesting a partial reorientation of the
magnetocrystalline anisotropy axis along the membrane plane with increasing
pore diameter. No significant changes in the magnetic behavior of the nanowire
system are observed with decreasing temperature, indicating that the effective
magnetoelastic anisotropy does not play a dominant role in the remagnetization
processes of individual nanowires. An enhancement of the total magnetic
anisotropy is found at room temperature with a decreasing nanowire
diameter-to-length ratio (d/L), a result that is quantitatively analyzed on the
basis of a simplified shape anisotropy model.Comment: 8 pages, 4 figure
Investigating the effect of belowground microbial volatiles on plant nutrient status: perspective and limitations
Volatile organic compounds displayed biological activities on a wide range of organisms, including plants and microbes. Investigating their role in the plant-microbe interaction processes occurring in the soil is challenging. By simulating belowground communication conditions between plant and microbes, in this study, we aimed to investigate the effects of the volatiles emitted by Serratia plymuthica and Fusarium culmorum on the nutrient status of maize plants. Plants were grown in potting soil and exposed to volatiles emitted by microbes inoculated in Petri dishes at the bottom of a jar. Nutrients content of plant tissues as well as soil volatiles were analyzed by ICP-MS and GC-MS, respectively. Our results showed that volatiles emitted belowground by Serratia plymuthica and Fusarium culmorum, in monoculture or interaction, differentially impacted on the content of some nutrient in plants, indicating that microbial volatiles-emitted belowground can affect the nutritional status of plants from a distance
Assessment of culture and environment in the Adolescent Brain and Cognitive Development Study: Rationale, description of measures, and early data.
Neurodevelopmental maturation takes place in a social environment in addition to a neurobiological one. Characterization of social environmental factors that influence this process is therefore an essential component in developing an accurate model of adolescent brain and neurocognitive development, as well as susceptibility to change with the use of marijuana and other drugs. The creation of the Culture and Environment (CE) measurement component of the ABCD protocol was guided by this understanding. Three areas were identified by the CE Work Group as central to this process: influences relating to CE Group membership, influences created by the proximal social environment, influences stemming from social interactions. Eleven measures assess these influences, and by time of publication, will have been administered to well over 7,000 9-10 year-old children and one of their parents. Our report presents baseline data on psychometric characteristics (mean, standard deviation, range, skewness, coefficient alpha) of all measures within the battery. Effectiveness of the battery in differentiating 9-10 year olds who were classified as at higher and lower risk for marijuana use in adolescence was also evaluated. Psychometric characteristics on all measures were good to excellent; higher vs. lower risk contrasts were significant in areas where risk differentiation would be anticipated
Macropore Formation and Pore Morphology Characterization of Heavily Doped p-Type Porous Silicon
Tuning the pore diameter of porous silicon films is essential for some applications such as biosensing, where the pore size can be used for filtering analytes or to control the biofunctionalization of its walls. However, macropore (>50nm) formation on p-type silicon is not yet fully controlled due to its strong dependence on resistivity. Electrochemical etching of heavily doped p-type silicon usually forms micropores (<5nm), but it has been found that bigger sizes can be achieved by adding an organic solvent to the electrolyte. In this work, we compare the results obtained when adding dimethylformamide (DMF) and dimethylsulfoxide (DMSO) to the electrolyte as well as the effect of a post-treatment of the sample with potasium hydroxide (KOH) and sodium hydroxide (NaOH) for macropore formation in p-type silicon with resistivities between 0.001 and 10Ω·cm, achieving pore sizes from 5 to 100nm
The obscured hyper-energetic GRB 120624B hosted by a luminous compact galaxy at z = 2.20
Gamma-ray bursts are the most luminous explosions that we can witness in the
Universe. Studying the most extreme cases of these phenomena allows us to
constrain the limits for the progenitor models. In this Letter, we study the
prompt emission, afterglow, and host galaxy of GRB 120624B, one of the
brightest GRBs detected by Fermi, to derive the energetics of the event and
characterise the host galaxy in which it was produced. Following the
high-energy detection we conducted a multi-wavelength follow-up campaign,
including near-infrared imaging from HAWKI/VLT, optical from OSIRIS/GTC, X-ray
observations from the Chandra X-ray Observatory and at
sub-millimetre/millimetre wavelengths from SMA. Optical/nIR spectroscopy was
performed with X-shooter/VLT. We detect the X-ray and nIR afterglow of the
burst and determine a redshift of z = 2.1974 +/- 0.0002 through the
identification of emission lines of [OII], [OIII] and H-alpha from the host
galaxy of the GRB. This implies an energy release of Eiso = (3.0+/-0.2)x10^54
erg, amongst the most luminous ever detected. The observations of the afterglow
indicate high obscuration with AV > 1.5. The host galaxy is compact, with R1/2
< 1.6 kpc, but luminous, at L ~ 1.5 L* and has a star formation rate of 91 +/-
6 Msol/yr as derived from H-alpha. As other highly obscured GRBs, GRB 120624B
is hosted by a luminous galaxy, which we also proof to be compact, with a very
intense star formation. It is one of the most luminous host galaxies associated
with a GRB, showing that the host galaxies of long GRBs are not always blue
dwarf galaxies, as previously thought.Comment: 6 pages, 4 figures, 4 tables; accepted for publication in A&
The origin of the Acheulean: the 1.7 million-year-old site of FLK West, Olduvai Gorge (Tanzania)
The appearance of the Acheulean is one of the hallmarks of human evolution. It represents the
emergence of a complex behavior, expressed in the recurrent manufacture of large-sized tools, with
standardized forms, implying more advance forethought and planning by hominins than those required
by the precedent Oldowan technology. The earliest known evidence of this technology dates back to
c. 1.7 Ma. and is limited to two sites (Kokiselei [Kenya] and Konso [Ethiopia]), both of which lack fauna.
The functionality of these earliest Acheulean assemblages remains unknown. Here we present the
discovery of another early Acheulean site also dating to c. 1.7 Ma from Olduvai Gorge. This site provides
evidence of the earliest steps in developing the Acheulean technology and is the oldest Acheulean site in
which stone tools occur spatially and functionally associated with the exploitation of fauna. Simple and
elaborate large-cutting tools (LCT) and handaxes co-exist at FLK West, showing that complex cognition
was present from the earliest stages of the Acheulean. Here we provide a detailed technological study
and evidence of the use of these tools on the butchery and consumption of fauna, probably by early
Homo erectus sensu lato
Easy to synthesize, robust organo-osmium asymmetric transfer hydrogenation catalysts
Asymmetric transfer hydrogenation (ATH) is an important process in organic synthesis for which the Noyori-type RuII catalysts [(arene)Ru(Tsdiamine)] are now well established and widely used. We now demonstrate for the first time the catalytic activity of the osmium analogues. X-ray crystal structures of the 16-electron OsII catalysts are almost identical to those of RuII. Intriguingly the precursor complex was isolated as a dichlorido complex with a monodentate amine ligand. The OsII catalysts are readily synthesised (within 1 h) and exhibit excellent enantioselectivity in ATH reactions of ketones
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