1,293 research outputs found
Mode Coupling relaxation scenario in a confined glass former
Molecular dynamics simulations of a Lennard-Jones binary mixture confined in
a disordered array of soft spheres are presented. The single particle dynamical
behavior of the glass former is examined upon supercooling. Predictions of mode
coupling theory are satisfied by the confined liquid. Estimates of the
crossover temperature are obtained by power law fit to the diffusion
coefficients and relaxation times of the late region. The exponent
of the von Schweidler law is also evaluated. Similarly to the bulk, different
values of the exponent are extracted from the power law fit to the
diffusion coefficients and relaxation times.Comment: 5 pages, 4 figures, changes in the text, accepted for publication on
Europhysics Letter
Structural Relaxation and Mode Coupling in a Simple Liquid: Depolarized Light Scattering in Benzene
We have measured depolarized light scattering in liquid benzene over the
whole accessible temperature range and over four decades in frequency. Between
40 and 180 GHz we find a susceptibility peak due to structural relaxation. This
peak shows stretching and time-temperature scaling as known from
relaxation in glass-forming materials. A simple mode-coupling model provides
consistent fits of the entire data set. We conclude that structural relaxation
in simple liquids and relaxation in glass-forming materials are
physically the same. A deeper understanding of simple liquids is reached by
applying concepts that were originally developed in the context of
glass-transition research.Comment: submitted to New J. Phy
Convergence to Stable Laws in Relative Entropy
Convergence to stable laws in relative entropy is established for sums of
i.i.d. random variables
Rate of convergence and Edgeworth-type expansion in the entropic central limit theorem
An Edgeworth-type expansion is established for the entropy distance to the
class of normal distributions of sums of i.i.d. random variables or vectors,
satisfying minimal moment conditions.Comment: Published in at http://dx.doi.org/10.1214/12-AOP780 the Annals of
Probability (http://www.imstat.org/aop/) by the Institute of Mathematical
Statistics (http://www.imstat.org
Mode-Coupling Theory as a Mean-Field Description of the Glass Transition
Mode-coupling theory (MCT) is conjectured to be a mean-field description of
dynamics of the structural glass transition and the replica theory to be its
thermodynamic counterpart. However, the relationship between the two theories
remains controversial and quantitative comparison is lacking. In this Letter,
we investigate MCT for monatomic hard sphere fluids at arbitrary dimensions
above three and compare the results with replica theory. We find grave
discrepancies between the predictions of two theories. While MCT describes the
nonergodic parameter quantitatively better than the replica theory in three
dimension, it predicts a completely different dimension dependence of the
dynamical transition point. We find it to be due to the pathological behavior
of the nonergodic parameters derived from MCT, which exhibit negative tails in
real space at high dimensions.Comment: 5 pages, to appear in Phys. Rev. Lett.: Typos have been correcte
- …