6,631 research outputs found
Fundamental electrode kinetics
Report presents the fundamentals of electrode kinetics and the methods used in evaluating the characteristic parameters of rapid-charge transfer processes at electrode-electrolyte interfaces. The concept of electrode kinetics is outlined, followed by the principles underlying the experimental techniques for the investigation of electrode kinetics
Phase field crystal dynamics for binary systems: Derivation from dynamical density functional theory, amplitude equation formalism, and applications to alloy heterostructures
The dynamics of phase field crystal (PFC) modeling is derived from dynamical
density functional theory (DDFT), for both single-component and binary systems.
The derivation is based on a truncation up to the three-point direct
correlation functions in DDFT, and the lowest order approximation using scale
analysis. The complete amplitude equation formalism for binary PFC is developed
to describe the coupled dynamics of slowly varying complex amplitudes of
structural profile, zeroth-mode average atomic density, and system
concentration field. Effects of noise (corresponding to stochastic amplitude
equations) and species-dependent atomic mobilities are also incorporated in
this formalism. Results of a sample application to the study of surface
segregation and interface intermixing in alloy heterostructures and strained
layer growth are presented, showing the effects of different atomic sizes and
mobilities of alloy components. A phenomenon of composition overshooting at the
interface is found, which can be connected to the surface segregation and
enrichment of one of the atomic components observed in recent experiments of
alloying heterostructures.Comment: 26 pages, 5 figures; submitted to Phys. Rev.
Scaffolds and Generalized Integral Galois Module Structure
Let be a finite, totally ramified -extension of complete local
fields with residue fields of characteristic , and let be a
-algebra acting on . We define the concept of an -scaffold on ,
thereby extending and refining the notion of a Galois scaffold considered in
several previous papers, where was Galois and for
. When a suitable -scaffold exists, we show how to
answer questions generalizing those of classical integral Galois module theory.
We give a necessary and sufficient condition, involving only numerical
parameters, for a given fractional ideal to be free over its associated order
in . We also show how to determine the number of generators required when it
is not free, along with the embedding dimension of the associated order. In the
Galois case, the numerical parameters are the ramification breaks associated
with . We apply these results to biquadratic Galois extensions in
characteristic 2, and to totally and weakly ramified Galois -extensions in
characteristic . We also apply our results to the non-classical situation
where is a finite primitive purely inseparable extension of arbitrary
exponent that is acted on, via a higher derivation (but in many different
ways), by the divided power -Hopf algebra.Comment: Further minor corrections and improvements to exposition. Reference
[BE] updated. To appear in Ann. Inst. Fourier, Grenobl
Snowex 2017 Community Snow Depth Measurements: A Quality-Controlled, Georeferenced Product
Snow depth was one of the core ground measurements required to validate remotely-sensed data collected during SnowEx Year 1, which occurred in Colorado. The use of a single, common protocol was fundamental to produce a community reference dataset of high quality. Most of the nearly 100 Grand Mesa and Senator Beck Basin SnowEx ground crew participants contributed to this crucial dataset during 6-25 February 2017. Snow depths were measured along ~300 m transects, whose locations were determined according to a random-stratified approach using snowfall and tree-density gradients. Two-person teams used snowmobiles, skis, or snowshoes to travel to staked transect locations and to conduct measurements. Depths were measured with a 1-cm incremented probe every 3 meters along transects. In shallow areas of Grand Mesa, depth measurements were also collected with GPS snow-depth probes (a.k.a. MagnaProbes) at ~1-m intervals. During summer 2017, all reference stake positions were surveyed with <10 cm accuracy to improve overall snow depth location accuracy. During the campaign, 193 transects were measured over three weeks at Grand Mesa and 40 were collected over two weeks in Senator Beck Basin, representing more than 27,000 depth values. Each day of the campaign depth measurements were written in waterproof field books and photographed by National Snow and Ice Data Center (NSIDC) participants. The data were later transcribed and prepared for extensive quality assessment and control. Common issues such as protocol errors (e.g., survey in reverse direction), notebook image issues (e.g., halo in the center of digitized picture), and data-entry errors (sloppy writing and transcription errors) were identified and fixed on a point-by-point basis. In addition, we strove to produce a georeferenced product of fine quality, so we calculated and interpolated coordinates for every depth measurement based on surveyed stakes and the number of measurements made per transect. The product has been submitted to NSIDC in csv format. To educate data users, we present the study design and processing steps that have improved the quality and usability of this product. Also, we will address measurement and design uncertainties, which are different in open vs. forest areas
NASA Cold Land Processes Experiment (CLPX 2002/03): ground-based and near-surface meteorological observations
A short-term meteorological database has been developed for the Cold Land Processes Experiment (CLPX). This database includes meteorological observations from stations designed and deployed exclusively for CLPXas well as observations available from other sources located in the small regional study area (SRSA) in north-central Colorado. The measured weather parameters include air temperature, relative humidity, wind speed and direction, barometric pressure, short- and long-wave radiation, leaf wetness, snow depth, snow water content, snow and surface temperatures, volumetric soil-moisture content, soil temperature, precipitation, water vapor flux, carbon dioxide flux, and soil heat flux. The CLPX weather stations include 10 main meteorological towers, 1 tower within each of the nine intensive study areas (ISA) and one near the local scale observation site (LSOS); and 36 simplified towers, with one tower at each of the four corners of each of the nine ISAs, which measured a reduced set of parameters. An eddy covariance system within the North Park mesocell study area (MSA) collected a variety of additional parameters beyond the 10 standard CLPX tower components. Additional meteorological observations come from a variety of existing networks maintained by the U.S. Forest Service, U.S. Geological Survey, Natural Resource Conservation Service, and the Institute of Arctic and Alpine Research. Temporal coverage varies from station to station, but it is most concentrated during the 2002/ 03 winter season. These data are useful in local meteorological energy balance research and for model development and testing. These data can be accessed through the National Snow and Ice Data Center Web site
Diffusive Atomistic Dynamics of Edge Dislocations in Two Dimensions
The fundamental dislocation processes of glide, climb, and annihilation are
studied on diffusive time scales within the framework of a continuum field
theory, the Phase Field Crystals (PFC) model. Glide and climb are examined for
single edge dislocations subjected to shear and compressive strain,
respectively, in a two dimensional hexagonal lattice. It is shown that the
natural features of these processes are reproduced without any explicit
consideration of elasticity theory or ad hoc construction of microscopic
Peierls potentials. Particular attention is paid to the Peierls barrier for
dislocation glide/climb and the ensuing dynamic behavior as functions of strain
rate, temperature, and dislocation density. It is shown that the dynamics are
accurately described by simple viscous motion equations for an overdamped point
mass, where the dislocation mobility is the only adjustable parameter. The
critical distance for the annihilation of two edge dislocations as a function
of separation angle is also presented.Comment: 13 pages with 17 figures, submitted to Physical Review
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