Optical binding in nanoparticle assembly: Potential energy landscapes

Optical binding is an optomechanical effect exhibited by systems of micro- and nanoparticles, suitably irradiated with off-resonance laser light. Physically distinct from standing-wave and other forms of holographic optical traps, the phenomenon arises as a result of an interparticle coupling with individual radiation modes, leading to optically induced modifications to Casmir-Polder interactions. To better understand how this mechanism leads to the observed assemblies and formation of patterns in nanoparticles, we develop a theory in terms of optically induced energy landscapes exhibiting the three-dimensional form of the potential energy field. It is shown in detail that the positioning and magnitude of local energy maxima and minima depend on the configuration of each particle pair, with regards to the polarization and wave vector of the laser light. The analysis reveals how the positioning of local minima determines the energetically most favorable locations for the addition of a third particle to each equilibrium pair. It is also demonstrated how the result of such an addition subtly modifies the energy landscape that will, in turn, determine the optimum location for further particle additions. As such, this development represents a rigorous and general formulation of the theory, paving the way toward full comprehension of nanoparticle assembly based on optical binding

Cyclic homogeneous Riemannian manifolds

In spin geometry, traceless cyclic homogeneous Riemannian manifolds equipped with a homogeneous spin structure can be viewed as the simplest manifolds after Riemannian symmetric spin spaces. In this paper, we give some characterizations and properties of cyclic and traceless cyclic homogeneous Riemannian manifolds and we obtain the classification of simply-connected cyclic homogeneous Riemannian manifolds of dimension less than or equal to four. We also present a wide list of examples of non-compact irreducible Riemannian $3$-symmetric spaces admitting cyclic metrics and give the expression of these metrics

Homogeneous spin Riemannian manifolds with the simplest Dirac operator

We show the existence of nonsymmetric homogeneous spin Riemannian manifolds whose Dirac operator is like that on a Riemannian symmetric spin space. Such manifolds are exactly the homogeneous spin Riemannian manifolds $(M,g)$ which are traceless cyclic with respect to some quotient expression $M=G/K$ and reductive decomposition $\mathfrak{g} = \mathfrak{k} \oplus \mathfrak{m}$. Using transversally symmetric fibrations of noncompact type, we give a list of them

Quasi-chemical approximation for polyatomic mixtures

The statistical thermodynamics of binary mixtures of polyatomic species was developed on a generalization in the spirit of the lattice-gas model and the quasi-chemical approximation (QCA). The new theoretical framework is obtained by combining: (i) the exact analytical expression for the partition function of non-interacting mixtures of linear $k$-mers and $l$-mers (species occupying $k$ sites and $l$ sites, respectively) adsorbed in one dimension, and its extension to higher dimensions; and (ii) a generalization of the classical QCA for multicomponent adsorbates and multisite-occupancy adsorption. The process is analyzed through the partial adsorption isotherms corresponding to both species of the mixture. Comparisons with analytical data from Bragg-Williams approximation (BWA) and Monte Carlo simulations are performed in order to test the validity of the theoretical model. Even though a good fitting is obtained from BWA, it is found that QCA provides a more accurate description of the phenomenon of adsorption of interacting polyatomic mixtures.Comment: 27 pages, 8 figure

Circular dichroism of cholesteric polymers and the orbital angular momentum of light

We explore experimentally if the light's orbital angular momentum (OAM) interacts with chiral nematic polymer films. Specifically, we measure the circular dichroism of such a material using light beams with different OAM. We investigate the case of strongly focussed, non-paraxial light beams, where the spatial and polarization degrees of freedom are coupled. Within the experimental accuracy, we cannot find any influence of the OAM on the circular dichroism of the cholesteric polymer.Comment: 3 pages, 4 figure

A retarded coupling approach to intermolecular interactions

A wide range of physical phenomena such as optical binding and resonance energy transfer involve electronic coupling between adjacent molecules. A quantum electrodynamical description of these intermolecular interactions reveals the presence of retardation effects. The clarity of the procedure associated with the construction of the quantum amplitudes and the precision of the ensuing results for observable energies and rates are widely acknowledged. However, the length and complexity of the derivations involved in such quantum electrodynamical descriptions increase rapidly with the order of the process under study. Whether through the use of time-ordering approaches, or the more expedient state-sequence method, time-consuming calculations cannot usually be bypassed. A simple and succinct method is now presented, which provides for a direct and still entirely rigorous determination of the quantum electrodynamical amplitudes for processes of arbitrarily high order. Using the approach, new results for optical binding in two- and three-particle systems are secured and discussed

Raman scattering mediated by neighboring molecules

Raman scattering is most commonly associated with a change in vibrational state within individual molecules, the corresponding frequency shift in the scattered light affording a key way of identifying material structures. In theories where both matter and light are treated quantum mechanically, the fundamental scattering process is represented as the concurrent annihilation of a photon from one radiation mode and creation of another in a different mode. Developing this quantum electrodynamical formulation, the focus of the present work is on the spectroscopic consequences of electrodynamic coupling between neighboring molecules or other kinds of optical center. To encompass these nanoscale interactions, through which the molecular states evolve under the dual influence of the input light and local fields, this work identifies and determines two major mechanisms for each of which different selection rules apply. The constituent optical centers are considered to be chemically different and held in a fixed orientation with respect to each other, either as two components of a larger molecule or a molecular assembly that can undergo free rotation in a fluid medium or as parts of a larger, solid material. The two centers are considered to be separated beyond wavefunction overlap but close enough together to fall within an optical near-field limit, which leads to high inverse power dependences on their local separation. In this investigation, individual centers undergo a Stokes transition, whilst each neighbor of a different species remains in its original electronic and vibrational state. Analogous principles are applicable for the anti-Stokes case. The analysis concludes by considering the experimental consequences of applying this spectroscopic interpretation to fluid media; explicitly, the selection rules and the impact of pressure on the radiant intensity of this process

Factores de variabilidad del lanzamiento en salto en balonmano por efecto de la oposición

Se han analizado las variables biomecánicas que determinan la eficacia de un gesto técnico como es el lanzamiento en salto a distancia en balonmano realizado sin y con oposición defensiva. El propósito del trabajo es estudiar los factores de variabilidad por efecto de la oposición. Para el desarrollo de este trabajo se han utilizado las técnicas fotogramétricas tridimensionales (3D). El aspecto más relevante que se desprende de los resultados expuestos es la falta de significación estadística entre todos los factores causales cuando se comparan las dos situaciones experimentales propuestas (sin y con oposición)

Bending behavior analysis of geogrid reinforced adobe walls

La tierra cruda constituye el material de construcción más importante en muchas regiones del planeta. Dado el riesgo sísmico existente en la mayor parte de estas regiones, es necesario el desarrollo de técnicas de refuerzo eficaces y adecuadas desde un punto de vista tecnológico y socioeconómico. Este artículo analiza desde un punto experimental y analítico el comportamiento a flexión de muros de adobe reforzados con geomallas. Las leyes momento-curvatura de los muros ensayados son aproximadas mediante una serie de modelos analíticos que permiten analizar el comportamiento del material compuesto adobe-geomalla. Los resultados obtenidos muestran como la geomalla mejora el comportamiento de la mampostería de adobe en términos de resistencia y ductilidad, mejorando así su comportamiento en caso de movimiento sísmico.Rammed earth is a widely used building material in many regions of the world. Due to the high seismic risk in those areas, earthen constructions require suitable and efficient reinforcement techniques from a technological and socioeconomic point of view. This paper analyzes the bending behavior of geogrid reinforced adobe walls from an experimental and analytical point of view. The experimental bending moment-curvature relationships are analytically approached. The results show how geogrid reinforcement improves the performance of adobe masonry in terms of strength and ductility. Thus, a better seismic performance is achieve