A study of the dynamics of magnetic disaccommodation in amorphous ferromagnets. I. Experimental results

Systematic room‐temperature measurements of the aftereffect of the ac magnetic permeability have been performed on a Fe81B13.5 Si3.5C2 amorphous ribbon in order to get detailed information about the nature of the atomic ordering processes responsible for the magnetic relaxation. The magnetic aftereffect related to 180° domain‐wall motion has been measured by means of a specific technique allowing periodic domain‐wall displacements to be induced between two fixed, neighboring equilibrium positions by applying a square‐wave field of proper amplitude and frequency. In this way, the average direction of the magnetization vector is cyclically modified in all points where the studied directional ordering processes may occur. As a consequence, the kinetics of ordering is modified in a characteristic way, giving rise to relevant variations in the intensity of the magnetic aftereffect measured between fixed times (t1=2×10−3 s and t2=10−1 s), and in the value of the magnetic induction at the time t2. All measurements have been performed at constant applied field. The degree of reliability of this experimental technique has been analyzed in detail. The magnetic aftereffect, ΔB=B(t1)−B(t2), and the magnetic induction B(t2) have been measured as functions of the number of domain‐wall cycles, and after removing the square‐wave field for a variable time t∗. The results of many independent measurements are reported and discussed

A study of the dynamics of magnetic disaccommodation in amorphous ferromagnets. II. Theoretical considerations

The results obtained in part I are interpreted in terms of the viscosity field arising from independent processes of directional ordering for magnetic defects dispersed in the amorphous structure and interacting with the magnetization vector. A specific model is developed in order to take into account the changes in the ordering kinetics induced by the periodic magnetization rotations described in part I. This model, however, requires that the magnetic induction remain constant during the whole measurement; as a consequence, the model's predictions cannot be directly compared with the experimental results, obtained instead at constant applied field. This difficulty is overcome by deriving a general relationship between the magnetic‐induction decay and the viscosity field kinetics for an arbitrary number of half‐periods of the square‐wave field. The agreement of our theory with the experimental results turns out to be quite satisfactory. As consequence, the ordering processes responsible for the magnetic aftereffect in amorphous ferromagnets may be described as essentially uncorrelated

Short-time dynamics of correlated magnetic moments in superparamagnetic Cu-Co melt spun alloys exhibiting giant magnetoresistance

Evidence for correlation among superparamagnetic particles in melt-spun Cu100-xCox systems (x = 5-20) exhibiting a giant magnetoresistance is obtained by plotting this quantity as a function of reduced magnetization. Two ranges, R-theta(H-e) and R-theta(H-e), have been recently introduced to describe the extent of correlation among angles of tilt (theta) and of twist (phi) of superparamagnetic moments precessing around a local field axis. The angle of tilt appears to be spatially correlated over a distance larger by a factor of 3 than the angle of twist. This difference is explained by analyzing the short-time dynamics of magnetic moments in superparamagnetic granular systems with long-range interactions (of dipolar and the RKKY-like type). The typical time constants characterizing the process of scattering of conduction electrons by adjacent magnetic moments (electronic time of flight, relaxation times for theta and phi) are discussed in detail. An explicit expression for R-phi(H) is obtained by considering the competition between a magnetic interaction favoring parallel (or antiparallel) alignment or adjacent moments, and thermal disturbances resulting in a continuous loss of the phase coherence. (C) 1997 American Institute of Physics

Dipolar interactions among magnetite nanoparticles for magnetic hyperthermia: a rate-equation approach

Rate equations are used to study the dynamic magnetic properties of interacting magnetite nanoparticles viewed as double well systems (DWS) subjected to a driving field in the radio-frequency range. Dipole-dipole interaction among particles is modeled by inserting an ad-hoc term in the energy barrier to simulate the dependence of the interaction on both the interparticle distance and degree of dipole collinearity. The effective magnetic power released by an assembly of interacting nanoparticles dispersed in a diamagnetic host is shown to be a complex function of nanoparticle diameter, mean particle interdistance and frequency. Dipolar interaction markedly modifies the way a host material is heated by an assembly of embedded nanoparticles in magnetic hyperthermia treatments. Nanoparticle fraction and strength of the interaction can dramatically influence the amplitude and shape of the heating curves of the host material; the heating ability of interacting nanoparticles is shown to be either improved or reduced by their concentration in the host material. A frequency-dependent cut-off length of dipolar interactions is determined and explained. Particle polydispersity entailing a distribution of particle sizes brings about non-trivial effects on the heating curves depending on the strength of dipolar interaction

Magnetic Properties And Giant Magnetoresistance Of Melt-spun Granular Cu100-x-cox Alloys

Room-temperature measurements of magnetization and giant magnetoresistance were performed on rapidly solidified granular Cu100-xCox systems (x=5,10,15). The magnetoresistance of melt-spun Cu100-xCox ribbons was enhanced either by suitable furnace annealings or by exploiting the dc Joule-heating technique in the attempt of precipitating smaller magnetic particles. The particle-size distribution, the particle density, and mean distance are obtained for all compositions and heat treatments through a suitable analysis of the magnetic behavior of samples. The magnetoresistance is plotted as a function of the reduced magnetization, and a significant deviation from the quadratic behavior predicted by the independent-moment approach is observed at low fields. A simple theory taking explicitly into account the correlation existing among the magnetic particles is proposed. A general expression for the magnetoresistance in granular magnetic systems is obtained, and shown to accurately fit all the experimental curves, indicating that this effect is basically determined by the ratios between two distinct correlation ranges for the magnetic-moment fluctuations and the electronic mean free path. © 1995 The American Physical Society.5221153981541

Specific loss power of magnetic nanoparticles: A machine learning approach

A machine learning approach has been applied to the prediction of magnetic hysteresis properties (coercive field, magnetic remanence, and hysteresis loop area) of magnetic nanoparticles for hyperthermia applications. Trained on a dataset compiled from numerical simulations, a neural network and a random forest were used to predict power losses of nanoparticles as a function of their intrinsic properties (saturation, anisotropy, and size) and mutual magnetic interactions, as well as of application conditions (temperature, frequency, and applied field magnitude), for values of the parameters not represented in the database. The predictive ability of the studied machine learning approaches can provide a valuable tool toward the application of magnetic hyperthermia as a precision medicine therapy tailored to the patient's needs. (C) 2022 Author(s)

Magnetic properties and giant magnetoresistance of melt-spun granular Cu-100-x Co-x alloys

Room-temperature measurements of magnetization and giant magnetoresistance were performed on rapidly solidified granular Cu100-xCox systems (x=5,10,15). The magnetoresistance of melt-spun Cu100-xCox ribbons was enhanced either by suitable furnace annealings or by exploiting the de Joule-heating technique in the attempt of precipitating smaller magnetic particles. The particle-size distribution, the particle density, and mean distance are obtained for all compositions and heat treatments through a suitable analysis of the magnetic behavior of samples. The magnetoresistance is plotted as a function of the reduced magnetization, and a significant deviation from the quadratic behavior predicted by the independent-moment approach is observed at low fields. A simple theory taking explicitly into account the correlation existing among the magnetic particles is proposed. A general expression for the magnetoresistance in granular magnetic systems is obtained, and shown to accurately fit all the experimental curves, indicating that this effect is basically determined by the ratios between two distinct correlation ranges for the magnetic-moment fluctuations and the electronic mean free path

Observation of isotropic giant magnetoresistance in paramagnetic Au80 Fe20

Magnetization and magnetoresistance were measured at room temperature and above on Au80Fe20 platelets and ribbons obtained by solid-state quenching and melt spinning. The as-quenched samples contain a solid solution of Fe in Au and exhibit a paramagnetic (Curie-Weiss) behavior in the considered temperature range; magnetic data indicate very short-ranged magnetic correlation among adjacent spins, enhanced by local composition fluctuations. The solid solution is very stable. Only a very limited fraction (never exceeding 1%) of nanometer-sized, bcc Fe particles appears after long-time isothermal anneals at suitable temperatures. A negative magnetoresistance was observed at room temperature in all examined samples. The observed effect is anhysteretic, isotropic, and quadratically dependent on magnetic field H and magnetization M. The signal scales with M rather than with H, indicating that it depends on the field-induced magnetic order of the Fe moments, as it does for conventional giant magnetoresistance in granular magnetic systems. This effect derives from spin-dependent scattering of conduction electrons from single Fe spins or very small Fe clusters. The scattering centers are almost uncorrelated at a distance of the order of the electronic mean free path (of the order of 1.5 nm, or a few atomic spacings, at RT

Magnetic properties and giant magnetoresistance in melt-spun CoCu alloys

Magnetic, structural, and transport properties of as quenched and annealed Co10Cu90 samples have been investigated using x¿ray diffraction and a SQUID magnetometer. The largest value of MR change was observed for the as¿quenched sample annealed at 450°C for 30 min. The magnetic and transport properties closely correlate with the microstructure, mainly with Co magnetic particle size and its distribution. For thermal annealing the as quenched samples below 600°C, the Co particle diameters increase from 4.0 to 6.0 nm with a magnetoresistance (MR) drop from 33.0% to 5.0% at 10 K. Comparison with the theory indicates that the interfacial electron spin¿dependent scattering mechanism correlates with GMR for Co particle diameters up to about 6.0 nm

Magnetic hysteresis in granular CuCo alloys

Room-temperature hysteresis loops of granular Cu100-xCox alloys (5 less than or equal to x less than or equal to 15) obtained by planar flow casting in air and submitted to proper annealing treatments have been measured up to a field of 10 kOe by means of a vibrating sample magnetometer. In major loops (\H-vert\ = 10 kOe), the reduced remanence-to-saturation ratio m(r) = M-r/M-s and the coercivity H-c measured on all studied materials appear to be related by an almost linear law of the type m(r) approximate to 1/3 (mu H-c/kT), mu being the average magnetic moment on Co particles. A similar relation is also observed on minor symmetrical loops (100 Oe less than or equal to\H-vert\ less than or equal to 9 kOe). The observed results are accounted for by a model which considers the hysteresis as originating by magnetic interactions among nearly superparamagnetic Co particles. (C) 1999 American Institute of Physics. [S0021-8979(99)51408-4]