A standardised method for measuring in situ denitrification in shallow aquifers: numerical validation and measurements in riparian wetlands

A tracer test to examine in situ denitrification in shallow groundwater by a piezometer with a packer system used bromide as a tracer of dilution and acetylene (10%) to block the denitrification process at the nitrous oxide stage. During the test, dissolved oxygen, nitrate (NO3-), bromide (Br-), nitrous oxide (N2O) and dissolved organic carbon (DOC) were measured. To calibrate the experimental method, comparison with numerical simulations of the groundwater transfer were carried out, taking into account the environmental characteristics. The method was tested by measurements undertaken in different environmental conditions (geology, land use and hydrology) in two riparian wetlands. Denitrification rates measured by this method ranged from 5.7 10-6 g N-NO3-L-1 h-1 to 1.97 10-3 g N-NO3-L-1 h-1 The method is applicable in shallow aquifers with a permeability from 10-2 to 10-4m s-1

Ferrocenyl gold complexes as efficient catalysts

More than half a century after the discovery of the ferrocene structure in 1951, it remains as a suitable building block in many research areas, including catalysis with the development of key chiral catalysts. On the other hand, gold-mediated catalysis has been raised in recent years, allowing the creation of a great variety of C-C bonds and C-heteroatom bonds. In this context, this review covers the recent advances made with the combination of these two iconic figures in the organometallic chemistry field, since the first gold catalyzed reaction using a ferrocene ligand reported in 1986. The combination of the excellent properties and versatility of this metallocene, has allowed the obtainment of a plethora of ligands for metal catalysis, although their use joined to gold catalysis is still scarcely explored

Wetland restoration and nitrate reduction: the example of the periurban wetland of Vitoria-Gasteiz (Basque Country, North Spain)

Changes in land use and agricultural intensification caused wetlands on the quaternary aquifer of Vitoria-Gasteiz (Basque Country) to disappear some years ago and nitrate concentration in groundwaters increased very quickly. The Basque Government recently declared the East Sector of this aquifer a Vulnerable Zone according to the 91/676/CEE European Directive. Recently, the wetlands have been restored through the closure of the main drainage ditches, the consequent elevation of the water table and the abondonment of agricultural practices near the wetlands. This is the case of the Zurbano wetland. Restoration has allowed the recovery of its biogeochemical function, which has reduced nitrate concentrations in waters. Nitrate concentrations which exceed 50 mg l–1 in groundwaters entering into the wetland are less than 10 mg l–1 at the outlet. Conditions in the wetland are conducive to the loss of nitrates: organic matter rich wetted soils, clay presence allowing a local semiconfined flow and very low hydraulic gradient. Water quality monitoring at several points around the wetland showed the processes involved in nitrate loss, although some aspects still remain unresolved. However, during storm events, the wetland effectively reduces the nitrate concentration entering the Alegria River, the most important river on the quaternary aquifer

A new simple technique for improving the random properties of chaos-based cryptosystems

A new technique for improving the security of chaos-based stream ciphers has been proposed and tested experimentally. This technique manages to improve the randomness properties of the generated keystream by preventing the system to fall into short period cycles due to digitation. In order to test this technique, a stream cipher based on a Skew Tent Map algorithm has been implemented on a Virtex 7 FPGA. The randomness of the keystream generated by this system has been compared to the randomness of the keystream generated by the same system with the proposed randomness-enhancement technique. By subjecting both keystreams to the National Institute of Standards and Technology (NIST) tests, we have proved that our method can considerably improve the randomness of the generated keystreams. In order to incorporate our randomness-enhancement technique, only 41 extra slices have been needed, proving that, apart from effective, this method is also efficient in terms of area and hardware resources

Chaotic Encryption Applied to Optical Ethernet in Industrial Control Systems

In the past decades, Ethernet has become an alternative technology for the field buses traditionally used in industrial control systems and distributed measurement systems. Among different transmission media in Ethernet standards, optical fiber provides the best bandwidth, excellent immunity to electromagnetic interference, and less signal loses than other wired media. Due to the absence of a standard that provides security at the physical layer of optical Ethernet links, the main motivation of this paper is to propose and implement the necessary modifications to introduce encryption in Ethernet 1000Base-X standard. This has consisted of symmetric streaming encryption of the 8b10b symbols flow at physical coding sublayer level, thanks to a keystream generator based on chaotic algorithm. The overall system has been implemented and tested in an field programmable gate array and Ethernet traffic has been encrypted and transmitted over an optical link. The experimental results show that it is possible to cipher traffic at this level and hide the complete Ethernet traffic pattern from passive eavesdroppers. In addition, no space overhead is introduced in data frames during encryption, achieving the maximum throughput

Physical Layer Encryption for Industrial Ethernet in Gigabit Optical Links

Industrial Ethernet is a technology widely spread in factory floors and critical infrastructures where a high amount of data need to be collected and transported. Fiber optic networks at gigabit rates fit well with that type of environment, where speed, system performance, and reliability are critical. In this paper, a new encryption method for high-speed optical communications suitable for such kinds of networks is proposed. This new encryption method consists of a symmetric streaming encryption of the 8b/10b data flow at physical coding sublayer level. It is carried out thanks to a format preserving encryption block cipher working in CTR (counter) mode. The overall system has been simulated and implemented in a field programmable gate array. Thanks to experimental results, it can be concluded that it is possible to cipher traffic at this physical level in a secure way. In addition, no overhead is introduced during encryption, getting minimum latency and maximum throughput

The dependence of oxygen and nitrogen abundances on stellar mass from the CALIFA survey

We analysed the optical spectra of HII regions extracted from a sample of 350 galaxies of the CALIFA survey. We calculated total O/H abundances and, for the first time, N/O ratios using the semi-empirical routine HII-CHI-mistry, which, according to P\'erez-Montero (2014), is consistent with the direct method and reduces the uncertainty in the O/H derivation using [NII] lines owing to the dispersion in the O/H-N/O relation. Then we performed linear fittings to the abundances as a function of the de-projected galactocentric distances. The analysis of the radial distribution both for O/H and N/O in the non-interacting galaxies reveals that both average slopes are negative, but a non-negligible fraction of objects have a flat or even a positive gradient (at least 10\% for O/H and 4\% for N/O). The slopes normalised to the effective radius appear to have a slight dependence on the total stellar mass and the morphological type, as late low-mass objects tend to have flatter slopes. No clear relation is found, however, to explain the presence of inverted gradients in this sample, and there is no dependence between the average slopes and the presence of a bar. The relation between the resulting O/H and N/O linear fittings at the effective radius is much tighter (correlation coefficient $\rho_s$ = 0.80) than between O/H and N/O slopes ($\rho_s$ = 0.39) or for O/H and N/O in the individual \hii\ regions ($\rho_s$ = 0.37). These O/H and N/O values at the effective radius also correlate very tightly (less than 0.03 dex of dispersion) with total luminosity and stellar mass. The relation with other integrated properties, such as star formation rate, colour, or morphology, can be understood only in light of the found relation with mass.Comment: Accepted for publication in A&A. 20 pages, 19 figure

Molecular gas at supernova local environments unveiled by EDGE

CO observations allow estimations of the gas content of molecular clouds, which trace the reservoir of cold gas fuelling star formation, as well as to determine extinction via H$_2$ column density, N(H$_2$). Here, we studied millimetric and optical properties at 26 supernovae (SNe) locations of different types in a sample of 23 nearby galaxies by combining molecular $^{12}$C$^{16}$O (J = 1 $\rightarrow$ 0) resolved maps from the EDGE survey and optical Integral Field Spectroscopy from the CALIFA survey. We found an even clearer separation between type II and type Ibc SNe in terms of molecular gas than what we found in the optical using H$\alpha$ emission as a proxy for current SF rate, which reinforces the fact that SNe Ibc are more associated with SF-environments. While A$_V$ at SN locations is similar for SNe II and SNe Ibc, and higher compared to SNe Ia, N(H$_2$) is significantly higher for SNe Ibc than for SNe II and SNe Ia. When compared to alternative extinction estimations directly from SN photometry and spectroscopy, we find that our SNe Ibc have also redder color excess but showed standard Na I D absorption pseudo-equivalent widths ($\sim$1 \AA). In some cases we find no extinction when estimated from the environment, but high amounts of extinction when measured from SN observations, which suggests that circumstellar material or dust sublimation may be playing a role. This work serves as a benchmark for future studies combining last generation millimeter and optical IFS instruments to reveal the local environmental properties of extragalactic SNe.Comment: MNRAS accepted, 17 pages, 8 Figures, 4 Table

The cosmic evolution of the spatially-resolved star formation rate and stellar mass of the CALIFA survey

We investigate the cosmic evolution of the absolute and specific star formation rate (SFR, sSFR) of galaxies as derived from a spatially-resolved study of the stellar populations in a set of 366 nearby galaxies from the CALIFA survey. The analysis combines GALEX and SDSS images with the 4000 break, H_beta, and [MgFe] indices measured from the datacubes, to constrain parametric models for the SFH, which are then used to study the cosmic evolution of the star formation rate density (SFRD), the sSFR, the main sequence of star formation (MSSF), and the stellar mass density (SMD). A delayed-tau model, provides the best results, in good agreement with those obtained from cosmological surveys. Our main results from this model are: a) The time since the onset of the star formation is larger in the inner regions than in the outer ones, while tau is similar or smaller in the inner than in the outer regions. b) The sSFR declines rapidly as the Universe evolves, and faster for early than for late type galaxies, and for the inner than for the outer regions of galaxies. c) SFRD and SMD agree well with results from cosmological surveys. At z< 0.5, most star formation takes place in the outer regions of late spiral galaxies, while at z>2 the inner regions of the progenitors of the current E and S0 are the major contributors to SFRD. d) The inner regions of galaxies are the major contributor to SMD at z> 0.5, growing their mass faster than the outer regions, with a lookback time at 50% SMD of 9 and 6 Gyr for the inner and outer regions. e) The MSSF follows a power-law at high redshift, with the slope evolving with time, but always being sub-linear. f) In agreement with galaxy surveys at different redshifts, the average SFH of CALIFA galaxies indicates that galaxies grow their mass mainly in a mode that is well represented by a delayed-tau model, with the peak at z~2 and an e-folding time of 3.9 Gyr.Comment: 23 pages, 16 figures, 6 tables, accepted for publication in Astronomy & Astrophysics. *Abridged abstract