The future of global environmental assessments: Making a case for fundamental change

Since the late 1970s, over 140 global environmental assessments (GEAs) have been completed. But are they any longer fit for purpose? Some believe not. Compelling arguments have been advanced for a new assessment paradigm, one more focussed on problem-solving than problem-identification. If translated into new assessment practices, this envisaged paradigm could prevail for the next several decades, just as the current one has since the late 1970s. In this paper, it is contended that the arguments for GEAs 2.0 are, in fact, insufficiently bold. Solutions-orientated assessments, often associated with a ‘policy turn’ by their advocates, are undoubtedly necessary. But without a ‘politics turn’ they will be profoundly insufficient: policy options would be detached from the diverse socio-economic explanations and ‘deep hermeneutics’ of value that ultimately give them meaning, especially given the very high stakes now attached to managing human impacts on a fast-changing planet. Here we make the case for GEAs 3.0, where two paradigmatic steps forward are taken at once rather than just one. The second step involves the introduction of political reasoning and structured normative debate about existential alternatives, a pre-requisite to strategic decision-making and its operational expression. Possible objections to this second step are addressed and rebutted. Even so, the case for politically-overt GEAs faces formidable difficulties of implementation. However, we consider these challenges less a sign of our undue idealism and more an indication of the urgent need to mitigate, if not overcome them. In a world of ‘wicked problems’ we need ‘wicked assessments’ adequate to them, preparatory to so-called ‘clumsy solutions’. This paper is intended to inspire more far-reaching debate about the future of GEAs and, by implication, about the roles social science and the humanities might usefully play in addressing global environmental change. </jats:p

Free energy of the Fr\"ohlich polaron in two and three dimensions

We present a novel Path Integral Monte Carlo scheme to solve the Fr\"ohlich polaron model. At intermediate and strong electron-phonon coupling, the polaron self-trapping is properly taken into account at the level of an effective action obtained by a preaveraging procedure with a retarded trial action. We compute the free energy at several couplings and temperatures in three and two dimensions. Our results show that the accuracy of the Feynman variational upper bound for the free energy is always better than 5% although the thermodynamics derived from it is not correct. Our estimates of the ground state energies demonstrate that the second cumulant correction to the variational upper bound predicts the self energy to better than 1% at intermediate and strong coupling.Comment: RevTeX 7 pages 3 figures, revised versio

Non-thermal Leptogenesis and a Prediction of Inflaton Mass in a Supersymmetric SO(10) Model

The gravitino problem gives a severe constraint on the thermal leptogenesis scenario. This problem leads us to consider some alternatives to it if we try to keep the gravitino mass around the weak scale $m_{3/2} \sim 100$ GeV. We consider, in this paper, the non-thermal leptogenesis scenario in the framework of a minimal supersymmetric SO(10) model. Even if we start with the same minimal SO(10) model, we have different predictions for low-energy phenomenologies dependent on the types of seesaw mechanism. This is the case for leptogenesis: it is shown that the type-I see-saw model gives a consistent scenario for the non-thermal leptogenesis but not for type-II. The predicted inflaton mass needed to produce the observed baryon asymmetry of the universe is found to be $M_I \sim 5 \times 10^{11}$ GeV for the reheating temperature $T_R = 10^6$ GeV.Comment: 9 pages, 2 figures; the version to appear in JCA

Evidence for Bound Entangled States with Negative Partial Transpose

We exhibit a two-parameter family of bipartite mixed states $\rho_{bc}$, in a $d\otimes d$ Hilbert space, which are negative under partial transposition (NPT), but for which we conjecture that no maximally entangled pure states in $2\otimes 2$ can be distilled by local quantum operations and classical communication (LQ+CC). Evidence for this undistillability is provided by the result that, for certain states in this family, we cannot extract entanglement from any arbitrarily large number of copies of $\rho_{bc}$ using a projection on $2\otimes 2$. These states are canonical NPT states in the sense that any bipartite mixed state in any dimension with NPT can be reduced by LQ+CC operations to an NPT state of the $\rho_{bc}$ form. We show that the main question about the distillability of mixed states can be formulated as an open mathematical question about the properties of composed positive linear maps.Comment: Revtex, 19 pages, 2 eps figures. v2,3: very minor changes, submitted to Phys. Rev. A. v4: minor typos correcte

The dynamic balance of import and export of zinc in Escherichia coli suggests a heterogeneous population response to stress

Zinc is essential for life, but toxic in excess. Thus all cells must control their internal zinc concentration. We used a systems approach, alternating rounds of experiments and models, to further elucidate the zinc control systems in Escherichia coli. We measured the response to zinc of the main specific zinc import and export systems in the wild-type, and a series of deletion mutant strains. We interpreted these data with a detailed mathematical model and Bayesian model fitting routines. There are three key findings: first, that alternate, non-inducible importers and exporters are important. Second, that an internal zinc reservoir is essential for maintaining the internal zinc concentration. Third, our data fitting led us to propose that the cells mount a heterogeneous response to zinc: some respond effectively, while others die or stop growing. In a further round of experiments, we demonstrated lower viable cell counts in the mutant strain tested exposed to excess zinc, consistent with this hypothesis. A stochastic model simulation demonstrated considerable fluctuations in the cellular levels of the ZntA exporter protein, reinforcing this proposal. We hypothesize that maintaining population heterogeneity could be a bet-hedging response allowing a population of cells to survive in varied and fluctuating environments

Optical Absorption Spectra of Bipolarons

The absorption of large bipolarons is investigated using the path-integral method. The response of a bipolaron to an external electromagnetic field is derived in the framework of the memory-function approach. The bipolaron optical absorption spectrum consists of a series of relatively narrow peaks. The peculiarities of the bipolaron optical absorption as a function of the frequency of the electromagnetic field may be attributed to the transitions involving relaxed excited states and scattering states of a bipolaron.Comment: 14 pages, 3 figures, E-mail addresses: [email protected], [email protected]; to be published in Phys. Rev.

Photochemistry of Furyl- and Thienyldiazomethanes: Spectroscopic Characterization of Triplet 3-Thienylcarbene

Photolysis (λ \u3e 543 nm) of 3-thienyldiazomethane (1), matrix isolated in Ar or N2 at 10 K, yields triplet 3-thienylcarbene (13) and α-thial-methylenecyclopropene (9). Carbene 13 was characterized by IR, UV/vis, and EPR spectroscopy. The conformational isomers of 3-thienylcarbene (s-E and s-Z) exhibit an unusually large difference in zero-field splitting parameters in the triplet EPR spectrum (|D/hc| = 0.508 cm–1, |E/hc| = 0.0554 cm–1; |D/hc| = 0.579 cm–1, |E/hc| = 0.0315 cm–1). Natural Bond Orbital (NBO) calculations reveal substantially differing spin densities in the 3-thienyl ring at the positions adjacent to the carbene center, which is one factor contributing to the large difference in D values. NBO calculations also reveal a stabilizing interaction between the sp orbital of the carbene carbon in the s-Z rotamer of 13 and the antibonding σ orbital between sulfur and the neighboring carbon—an interaction that is not observed in the s-E rotamer of 13. In contrast to the EPR spectra, the electronic absorption spectra of the rotamers of triplet 3-thienylcarbene (13) are indistinguishable under our experimental conditions. The carbene exhibits a weak electronic absorption in the visible spectrum (λmax = 467 nm) that is characteristic of triplet arylcarbenes. Although studies of 2-thienyldiazomethane (2), 3-furyldiazomethane (3), or 2-furyldiazomethane (4) provided further insight into the photochemical interconversions among C5H4S or C5H4O isomers, these studies did not lead to the spectroscopic detection of the corresponding triplet carbenes (2-thienylcarbene (11), 3-furylcarbene (23), or 2-furylcarbene (22), respectively)

The role of the chemical composition of monetite on the synthesis and properties of α-tricalcium phosphate

Peer reviewedPublisher PD

Polaron effects in electron channels on a helium film

Using the Feynman path-integral formalism we study the polaron effects in quantum wires above a liquid helium film. The electron interacts with two-dimensional (2D) surface phonons, i.e. ripplons, and is confined in one dimension (1D) by an harmonic potential. The obtained results are valid for arbitrary temperature ($T$), electron-phonon coupling strength ($\alpha$), and lateral confinement ($\omega_{0}$). Analytical and numerical results are obtained for limiting cases of $T$, $\alpha$, and $\omega_{0}$. We found the surprising result that reducing the electron motion from 2D to quasi-1D makes the self-trapping transition more continuous.Comment: 6 pages, 7 figures, submitted to Phys. Rev.