1,532 research outputs found
Thermoacoustic effects in supercritical fluids near the critical point: Resonance, piston effect, and acoustic emission and reflection
We present a general theory of thermoacoustic phenomena in supercritical
fluids near the critical point in a one-dimensional cell. We take into account
the effects of the heat conduction in the boundary walls and the bulk viscosity
near the critical point. We introduce a coefficient characterizing
reflection of sound with frequency at the boundary. As applications,
we examine the acoustic eigenmodes in the cell, the response to time-dependent
perturbations, sound emission and reflection at the boundary. Resonance and
rapid adiabatic changes are noteworthy. In these processes, the role of the
thermal diffusion layers is enhanced near the critical point because of the
strong critical divergence of the thermal expansion.Comment: 15 pages, 7 figure
Dynamics of Binary Mixtures with Ions: Dynamic Structure Factor and Mesophase Formation
Dynamic equations are presented for polar binary mixtures containing ions in
the presence of the preferential solvation. In one-phase states, we calculate
the dynamic structure factor of the composition accounting for the ion motions.
Microphase separation can take place for sufficiently large solvation asymmetry
of the cations and the anions. We show two-dimensional simulation results of
the mesophase formation with an antagonistic salt, where the cations are
hydrophilic and the anions are hydrophobic. The structure factor S(q) in the
resultant mesophase has a sharp peak at an intermediate wave number on the
order of the Debye-Huckel wave number. As the quench depth is increased, the
surface tension nearly vanishes in mesophases due to an electric double layer.Comment: 24 pages, 10 figures, to appear in Journal of Physics: Condensed
Matte
Magnetic properties of PrCu at high pressure
We report a study of the low-temperature high-pressure phase diagram of the
intermetallic compound PrCu, by means of molecular-field calculations and
Cu nuclear-quadrupole-resonance (NQR) measurements under pressure.
The pressure-induced magnetically-ordered phase can be accounted for by
considering the influence of the crystal electric field on the electron
orbitals of the Pr ions and by introducing a pressure-dependent exchange
interaction between the corresponding local magnetic moments. Our experimental
data suggest that the order in the induced antiferromagnetic phase is
incommensurate. The role of magnetic fluctuations both at high and low
pressures is also discussed.Comment: 7 pages, 6 figures, submitted to Eur. Phys. J.
Intermediate states at structural phase transition: Model with a one-component order parameter coupled to strains
We study a Ginzburg-Landau model of structural phase transition in two
dimensions, in which a single order parameter is coupled to the tetragonal and
dilational strains. Such elastic coupling terms in the free energy much affect
the phase transition behavior particularly near the tricriticality. A
characteristic feature is appearance of intermediate states, where the ordered
and disordered regions coexist on mesoscopic scales in nearly steady states in
a temperature window. The window width increases with increasing the strength
of the dilational coupling. It arises from freezing of phase ordering in
inhomogeneous strains. No impurity mechanism is involved. We present a simple
theory of the intermediate states to produce phase diagrams consistent with
simulation results.Comment: 16 pages, 14 figure
Viscoelastic Effect on Hydrodynamic Relaxation in Polymer Solutions
The viscoelastic effect on the hydrodynamic relaxation in semidilute polymer
solutions is investigated. From the linearized two-fluid model equations, we
predict that the dynamical asymmetry coupling between the velocity fluctuations
and the viscoelastic stress influences on the hydrodynamic relaxation process,
resulting in a wave-number-dependent shear viscosity.Comment: 7pages; To be published in Journal of the Physical Society of
Japan,Vol 72,No2,(2003
Shear flow effects on phase separation of entangled polymer blends
We introduce an entanglement model mixing rule for stress relaxation in a polymer blend to a modified Cahn-Hilliard equation of motion for concentration fluctuations in the presence of shear flow. Such an approach predicts both shear-induced mixing and demixing, depending on the relative relaxation times and plateau moduli of the two components
Binary fluids under steady shear in three dimensions
We simulate by lattice Boltzmann the steady shearing of a binary fluid
mixture with full hydrodynamics in three dimensions. Contrary to some
theoretical scenarios, a dynamical steady state is attained with finite
correlation lengths in all three spatial directions. Using large simulations we
obtain at moderately high Reynolds numbers apparent scaling expon ents
comparable to those found by us previously in 2D. However, in 3D there may be a
crossover to different behavior at low Reynolds number: accessing this regime
requires even larger computational resource than used here.Comment: 4 pages, 3 figure
Phase separation transition in liquids and polymers induced by electric field gradients
Spatially uniform electric fields have been used to induce instabilities in
liquids and polymers, and to orient and deform ordered phases of
block-copolymers. Here we discuss the demixing phase transition occurring in
liquid mixtures when they are subject to spatially nonuniform fields. Above the
critical value of potential, a phase-separation transition occurs, and two
coexisting phases appear separated by a sharp interface. Analytical and
numerical composition profiles are given, and the interface location as a
function of charge or voltage is found. The possible influence of demixing on
the stability of suspensions and on inter-colloid interaction is discussed.Comment: 7 pages, 3 figures. Special issue of the J. Phys. Soc. Ja
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