High Throughput Petrochronology and Sedimentary Provenance Analysis by Automated Phase Mapping and LAICPMS

The first step in most geochronological studies is to extract dateable minerals from the host rock, which is time consuming, removes textural context, and increases the chance for sample cross contamination. We here present a new method to rapidly perform in situ analyses by coupling a fast scanning electron microscope (SEM) with Energy Dispersive X-ray Spectrometer (EDS) to a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LAICPMS) instrument. Given a polished hand specimen, a petrographic thin section, or a grain mount, Automated Phase Mapping (APM) by SEM/EDS produces chemical and mineralogical maps from which the X-Y coordinates of the datable minerals are extracted. These coordinates are subsequently passed on to the laser ablation system for isotopic analysis. We apply the APM1LAICPMS method to three igneous, metamorphic, and sedimentary case studies. In the first case study, a polished slab of granite from Guernsey was scanned for zircon, producing a 60968 Ma weighted mean age. The second case study investigates a paragneiss from an ultra high pressure terrane in the north Qaidam terrane (Qinghai, China). One hundred seven small (25 mm) metamorphic zircons were analyzed by LAICPMS to confirm a 41964 Ma age of peak metamorphism. The third and final case study uses APM1LAICPMS to generate a large provenance data set and trace the provenance of 25 modern sediments from Angola, documenting longshore drift of Orange River sediments over a distance of 1,500 km. These examples demonstrate that APM1LAICPMS is an efficient and cost effective way to improve the quantity and quality of geochronological data

Shortwave infrared hyperspectral imaging as a novel method to elucidate multi-phase dolomitization, recrystallization, and cementation in carbonate sedimentary rocks

From Springer Nature via Jisc Publications RouterHistory: received 2021-07-08, accepted 2021-10-18, registration 2021-10-25, pub-electronic 2021-11-05, online 2021-11-05, collection 2021-12Publication status: PublishedFunder: Society for Sedimentary Geology Foundation; Grant(s): Student research grantFunder: International Association of Sedimentologists; doi: http://dx.doi.org/10.13039/501100007463; Grant(s): Postgraduate research grantFunder: British Sedimentological Research Group; doi: http://dx.doi.org/10.13039/100011045; Grant(s): Trevor Elliot memorial grantFunder: American Association of Petroleum Geologists Foundation; doi: http://dx.doi.org/10.13039/100013604; Grant(s): Classen Family grantFunder: Canadian Foundation for Innovation; Grant(s): John R. Evans Leaders Fund - Funding for research infrastructure (project 22222)Funder: National Science and Engineering Research Council of Canada; Grant(s): Discovery grantAbstract: Carbonate rocks undergo low-temperature, post-depositional changes, including mineral precipitation, dissolution, or recrystallisation (diagenesis). Unravelling the sequence of these events is time-consuming, expensive, and relies on destructive analytical techniques, yet such characterization is essential to understand their post-depositional history for mineral and energy exploitation and carbon storage. Conversely, hyperspectral imaging offers a rapid, non-destructive method to determine mineralogy, while also providing compositional and textural information. It is commonly employed to differentiate lithology, but it has never been used to discern complex diagenetic phases in a largely monomineralic succession. Using spatial-spectral endmember extraction, we explore the efficacy and limitations of hyperspectral imaging to elucidate multi-phase dolomitization and cementation in the Cathedral Formation (Western Canadian Sedimentary Basin). Spectral endmembers include limestone, two replacement dolomite phases, and three saddle dolomite phases. Endmember distributions were mapped using Spectral Angle Mapper, then sampled and analyzed to investigate the controls on their spectral signatures. The absorption-band position of each phase reveals changes in %Ca (molar Ca/(Ca + Mg)) and trace element substitution, whereas the spectral contrast correlates with texture. The ensuing mineral distribution maps provide meter-scale spatial information on the diagenetic history of the succession that can be used independently and to design a rigorous sampling protocol

The Importance of Eurekan Mountains on Cenozoic Sediment Routing on the Western Barents Shelf

The importance of topography generated by Eocene Eurekan deformation as a sediment source for sandstones deposited on the western Barents Shelf margin is evaluated through a sediment provenance study conducted on wellbore materials retrieved from Spitsbergen and from the Vestbakken Volcanic Province and the Sørvestsnaget Basin in the southwest Barents Sea. A variety of complementary techniques record a provenance change across the Paleocene-Eocene boundary in wellbore BH 10-2008, which samples Paleogene strata of the Central Tertiary Basin in Spitsbergen. Sandstones containing K-feldspar with radiogenic Pb isotopic compositions, chrome spinel in the heavy mineral assemblage, and detrital zircons and rutiles with prominent Palaeoproterozoic and Late Palaeozoic—Early Mesozoic U-Pb age populations are up-section replaced by sandstone containing albitic plagioclase feldspar, metasedimentary schist rock fragments, a heavy mineral assemblage with abundant chloritoid, metamorphic apatite with low REE contents, metapelitic rutile with Silurian U-Pb ages and zircons with predominantly Archaean and Palaeoproterozoic U-Pb age populations. Our results clearly demonstrate the well-known regional change in source area from an exposed Barents Shelf terrain east of the Central Tertiary Basin during the Paleocene to the emerging Eurekan mountains west and north of the Central Tertiary Basin during the Eocene. Eocene sandstones deposited in the marginal basins of the southwestern Barents Shelf, which were sampled in wellbores 7316/5-1 and 7216/11-1S, contain elements of both the Eurekan and the eastern Barents Shelf provenance signatures. The mixing of the two sand types and delivery to the southwest margin of the Barents Shelf is consistent with a fill and spill model for the Central Teritary Basin, with transport of Eurekan-derived sediment east then south hundreds of kilometres across the Shelf

Provenance of Late Paleozoic-Mesozoic sandstones, Taimyr Peninsula, Arctic

The sedimentary and provenance characteristics of seven Permo-Carboniferous and two early Cretaceous samples from the Taimyr Peninsula provide information about the latest evolution of Uralian Orogeny. The Permo-Carboniferous samples have a mixed provenance of recycled and first cycle sediment, sourced from metamorphic and igneous terranes. U-Pb detrital zircon ages represent a mixture of Precambrian-Paleozoic grains with euhedral, penecontemporaneous late Carboniferous and Permian grains consistent with derivation from the Uralian and Timanian orogens, plus additional Caledonian material presumably derived from Baltica. There are distinct differences between the late Permian sample and the other Carboniferous and early Permian samples, interpreted to reflect the final collisional stage of Uralian Orogeny. Early Cretaceous sediments deposited when the Amerasian Basin opened preserve a mixed provenance of metamorphic and igneous source material of mainly first cycle detritus, as well as an unstable heavy mineral assemblage dominated by staurolite, suggesting local derivation. Detrital zircon ages fall almost exclusively into one late Permian-early Triassic cluster, indicating no relationship with the Cretaceous Verkhoyansk fold belt

Provenance of Late Paleozoic-Mesozoic sandstones, Taimyr Peninsula, Arctic

The sedimentary and provenance characteristics of seven Permo-Carboniferous and two early Cretaceous samples from the Taimyr Peninsula provide information about the latest evolution of Uralian Orogeny. The Permo-Carboniferous samples have a mixed provenance of recycled and first cycle sediment, sourced from metamorphic and igneous terranes. U-Pb detrital zircon ages represent a mixture of Precambrian-Paleozoic grains with euhedral, penecontemporaneous late Carboniferous and Permian grains consistent with derivation from the Uralian and Timanian orogens, plus additional Caledonian material presumably derived from Baltica. There are distinct differences between the late Permian sample and the other Carboniferous and early Permian samples, interpreted to reflect the final collisional stage of Uralian Orogeny. Early Cretaceous sediments deposited when the Amerasian Basin opened preserve a mixed provenance of metamorphic and igneous source material of mainly first cycle detritus, as well as an unstable heavy mineral assemblage dominated by staurolite, suggesting local derivation. Detrital zircon ages fall almost exclusively into one late Permian-early Triassic cluster, indicating no relationship with the Cretaceous Verkhoyansk fold belt

Provenance of Late Paleozoic-Mesozoic sandstones, Taimyr Peninsula, Arctic

The sedimentary and provenance characteristics of seven Permo-Carboniferous and two early Cretaceous samples from the Taimyr Peninsula provide information about the latest evolution of Uralian Orogeny. The Permo-Carboniferous samples have a mixed provenance of recycled and first cycle sediment, sourced from metamorphic and igneous terranes. U-Pb detrital zircon ages represent a mixture of Precambrian-Paleozoic grains with euhedral, penecontemporaneous late Carboniferous and Permian grains consistent with derivation from the Uralian and Timanian orogens, plus additional Caledonian material presumably derived from Baltica. There are distinct differences between the late Permian sample and the other Carboniferous and early Permian samples, interpreted to reflect the final collisional stage of Uralian Orogeny. Early Cretaceous sediments deposited when the Amerasian Basin opened preserve a mixed provenance of metamorphic and igneous source material of mainly first cycle detritus, as well as an unstable heavy mineral assemblage dominated by staurolite, suggesting local derivation. Detrital zircon ages fall almost exclusively into one late Permian-early Triassic cluster, indicating no relationship with the Cretaceous Verkhoyansk fold belt

Diagenetic products, settings and evolution of the pre-salt succession in the Northern Campos Basin, Brazil

Despite all the effort made towards an understanding of the sedimentary, tectonic and diagenetic evolution of the pre-salt sequence and the Pre-Salt reservoirs of the Northern Campos Basin (East Brazil), two knowledge gaps have yet to be filled: (1) a detailed study of diagenesis in the crystalline basement and rift phases; and (2) the timing of diagenetic events that affected the pre-salt succession. In this study, samples from these geologic units were analysed for mineral composition and paragenetic evolution, fluid temperature and salinity, stable isotope compositions and laser ablation inductively coupled plasma mass spectrometer derived U–Pb ages of carbonate phases. The U–Pb ages of replacive and vein-filling cements reveal three tectono-diagenetic events, named the Barremian–Aptian (BADE, 125–117 Ma), the Albo–Cenomanian (ACDE, 103–98 Ma) and the Campanian–Maastrichtian (CMDE, 83–70 Ma). Each phase is characterized by distinct minerals, precipitation temperatures and burial conditions. The hydrothermal qualifier, identified by the temperature contrast between fluid and host rock, was initially high during BADE, then diminished over time (through ACDE) until it achieved equilibrium with the host rocks during CMDE. Diagenetic events are not coeval with magmatism but do coincide with known regional tectonic events described in the literature and are interpreted to be the result of increasing intraplate stresses. Multidisciplinary studies that include diagenetic events constrained by geochronological data will certainly lead to more robust conceptual geologic models, and, therefore, to a more reliable management of resources and strategies such as enhanced oil recovery, carbon capture, utilization and storage, and drinking water

Shortwave infrared hyperspectral imaging as a novel method to elucidate multi‑phase dolomitization, recrystallization, and cementation in carbonate sedimentary rocks

Abstract Carbonate rocks undergo low-temperature, post-depositional changes, including mineral precipitation, dissolution, or recrystallisation (diagenesis). Unravelling the sequence of these events is time-consuming, expensive, and relies on destructive analytical techniques, yet such characterization is essential to understand their post-depositional history for mineral and energy exploitation and carbon storage. Conversely, hyperspectral imaging offers a rapid, non-destructive method to determine mineralogy, while also providing compositional and textural information. It is commonly employed to differentiate lithology, but it has never been used to discern complex diagenetic phases in a largely monomineralic succession. Using spatial-spectral endmember extraction, we explore the efficacy and limitations of hyperspectral imaging to elucidate multi-phase dolomitization and cementation in the Cathedral Formation (Western Canadian Sedimentary Basin). Spectral endmembers include limestone, two replacement dolomite phases, and three saddle dolomite phases. Endmember distributions were mapped using Spectral Angle Mapper, then sampled and analyzed to investigate the controls on their spectral signatures. The absorption-band position of each phase reveals changes in %Ca (molar Ca/(Ca + Mg)) and trace element substitution, whereas the spectral contrast correlates with texture. The ensuing mineral distribution maps provide meter-scale spatial information on the diagenetic history of the succession that can be used independently and to design a rigorous sampling protocol