19,584 research outputs found
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Energy, climate and water in the 21st century – Texas and Florida share a strong connection with future challenges in the Earth sciences
Bureau of Economic Geolog
The DOE/NASA wind turbine data acquisition system. Part 3: Unattended power performance monitor
Software documentation, operational procedures, and diagnostic instructions for development version of an unattended wind turbine performance monitoring system is provided. Designed to be used for off line intelligent data acquisition in conjunction with the central host computer
REACTIVITY OF CHLOROPHYLL a/b-PROTEINS AND MICELLAR TRITON X-100 COMPLEXES OF CHLOROPHYLLS a OR b WITH BOROHYDRIDE
The reaction of several plant chlorophyll-protein complexes with NaBH4 has been studied by absorption spectroscopy. In all the complexes studied, chlorophyll b is more reactive than Chi a, due to preferential reaction of its formyl substituent at C-7. The complexes also show large variations in reactivity towards NaBH4 and the order of reactivity is: LHCI > PSII complex > LHCII > PSI > P700 (investigated as a component of PSI). Differential pools of the same type of chlorophyll have been observed in several complexes.
Parallel work was undertaken on the reactivity of micellar complexes of chlorophyll a and of chlorophyll b with NaBH4 to study the effect of aggregation state on this reactivity. In these complexes, both chlorophyll a and b show large variations in reactivity in the order monomer > oligomer > polymer with chlorophyll b generally being more reactive than chlorophyll a. It is concluded that aggregation decreases the reactivity of chlorophylls towards NaBH4 in vitro, and may similarly decrease reactivity in naturally-occurring chlorophyll-protein complexes
ARPES Study of X-Point Band Overlaps in LaB and SmB - Contrast to SrB and EuB
In contrast to our recent finding of an X-point band gap in divalent
hexaborides, we report here that angle resolved photoemission spectroscopy
(ARPES) data shows that the gap is absent for trivalent LaB and is absent
or nearly so for mixed valent SmB. This finding demonstrates a nontrivial
evolution of the band structure from divalent to trivalent hexaborides.Comment: submitted to SCES '0
Bulk Band Gaps in Divalent Hexaborides
Complementary angle-resolved photoemission and bulk-sensitive k-resolved
resonant inelastic x-ray scattering of divalent hexaborides reveal a >1 eV
X-point gap between the valence and conduction bands, in contradiction to the
band overlap assumed in several models of their novel ferromagnetism. This
semiconducting gap implies that carriers detected in transport measurements
arise from defects, and the measured location of the bulk Fermi level at the
bottom of the conduction band implicates boron vacancies as the origin of the
excess electrons. The measured band structure and X-point gap in CaB_6
additionally provide a stringent test case for proper inclusion of many-body
effects in quasi-particle band calculations.Comment: 4 pages, 3 figures; new RIXS analysis; accepted for publication in
PR
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Assessment of upper tropospheric HOx sources over the tropical Pacific based on NASA GTE/PEM data: Net effect on HOx and other photochemical parameters
Data for the tropical upper troposphere (8-12 km, 20° N-20° S) collected during NASA's Pacific Exploratory Missions have been used to carry out a detailed examination of the photochemical processes controlling HOx (OH+HO2). Of particular significance is the availability of measurements of nonmethane hydrocarbons, oxygenated hydrocarbons (i.e., acetone, methanol, and ethanol) and peroxides (i.e., H2O2 and CH3OOH). These observations have provided constraints on model calculations permitting an assessment of the potential impact of these species on the levels of HOx, CH3O2, CH2O, as well as ozone budget parameters. Sensitivity calculations using a time-dependent photochemical box model show that when constrained by measured values of the above oxygenated species, model estimated HOx levels are elevated relative to unconstrained calculations. The impact of constraining these species was found to increase with altitude, reflecting the systematic roll-off in water vapor mixing ratios with altitude. At 11-12 km, overall increases in HOx approached a factor of 2 with somewhat larger increases being found for gross and net photochemical production of ozone. While significant, the impact on HOx due to peroxides appears to be less than previously estimated. In particular, observations of elevated H2O2 levels may be more influenced by local photochemistry than by convective transport. Issues related to the uncertainty in high-altitude water vapor levels and the possibility of other contributing sources of HOx are discussed. Finally, it is noted that the uncertainties in gas kinetic rate coefficients at the low temperatures of the upper troposphere and as well as OH sensor calibrations should be areas of continued investigation. Copyright 1999 by the American Geophysical Union
Non-Fermi liquid angle resolved photoemission lineshapes of Li0.9Mo6O17
A recent letter by Xue et al. (PRL v.83, 1235 ('99)) reports a Fermi-Liquid
(FL) angle resolved photoemission (ARPES) lineshape for quasi one-dimensional
Li0.9Mo6O17, contradicting our report (PRL v.82, 2540 ('99)) of a non-FL
lineshape in this material. Xue et al. attributed the difference to the
improved angle resolution. In this comment, we point out that this reasoning is
flawed. Rather, we find that their data have fundamental differences from other
ARPES results and also band theory.Comment: To be published as a PRL Commen
Removal of Tetramethylammonium Cations from Zeolites
Zeolite α (high-silica LTA), a potential shape-selective catalyst, is synthesized in the presence of tetramethylammonium (TMA) ions. Since TMA+ ions are incapable of forming olefins at low temperature, temperatures in excess of 500ºC are required to thermally decompose them and burn off the carbonaceous deposits, frequently causing damage to the structure. In this paper, the thermal decomposition of zeolitic TMA+ ions is investigated. This work led to a less severe method for removing TMA+ ions by stepwise reaction with ammonia at low temperatures. TMA+ ions located in the supercage can easily be removed at a temperature as low as 250ºC, generating mono- and dimethylamine. Sodalite cage TMA+ ions require a temperature of not more than 400ºC to be degraded. Although this treatment raises the Si/Al ratio somewhat, damage to the structure is minimal. Since the size of the zeolitic pores defines the type of molecules capable of escaping from the zeolite cavities, decomposition of TMA+ ions in NaTMA-Y and NaTMA-high-silica sodalite have been included for comparison
A System for Accessible Artificial Intelligence
While artificial intelligence (AI) has become widespread, many commercial AI
systems are not yet accessible to individual researchers nor the general public
due to the deep knowledge of the systems required to use them. We believe that
AI has matured to the point where it should be an accessible technology for
everyone. We present an ongoing project whose ultimate goal is to deliver an
open source, user-friendly AI system that is specialized for machine learning
analysis of complex data in the biomedical and health care domains. We discuss
how genetic programming can aid in this endeavor, and highlight specific
examples where genetic programming has automated machine learning analyses in
previous projects.Comment: 14 pages, 5 figures, submitted to Genetic Programming Theory and
Practice 2017 worksho
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