25 research outputs found

    Electron crystallography: electron microscopy and electron diffraction

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    In the modern world of ever smaller devices and nanotechnology electron crystallography emerges as the most important method capable of determining the structure of minute objects down to the size of individual atoms. Crystals of only a few millionths of a millimetre are studied. This textbook explains how this is done

    A smectic dodecagonal quasicrystal

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    We report a solid smectic phase that exhibits dodecagonal global order. It is composed of axially stacked hexagonally ordered particle layers, and its 12-fold rotational symmetry induced by the 30° rotation of adjacent layers with respect to each other. A quasicrystal was produced in a molecular-dynamics simulation of a single-component system of particles interacting via a spherically-symmetric potential. It was formed as a result of a first-order phase transition from an isotropic liquid state that occurred under constant-density cooling. This finding implies that a similarly structured quasicrystal can possibly be produced by the same class of systems as those forming smectic-B crystals. This quasicrystal can also be expected to arise in a system of spherically-shaped colloidal particles with appropriately tuned potential

    Self-assembly of orthorhombic Fddd network in simple one-component liquids

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    Triply periodic continuous morphologies arising a result of the microphase separation in block copolymer melts have so far never been observed self-assembled in systems of particles with spherically symmetric interaction. We report a molecular dynamics simulation of two simple one-component liquids which self-assemble upon cooling into equilibrium orthorhombic continuous network morphologies with the Fddd space group symmetry reproducing the structure of those observed in block copolymers. The finding that the geometry of constituent molecules isn't relevant for the formation of triply periodic networks indicates the generic nature of this class of phase transition

    Self-assembly of orthorhombic Fddd network in simple one-component liquids

    No full text
    Triply periodic continuous morphologies arising a result of the microphase separation in block copolymer melts have so far never been observed self-assembled in systems of particles with spherically symmetric interaction. We report a molecular dynamics simulation of two simple one-component liquids which self-assemble upon cooling into equilibrium orthorhombic continuous network morphologies with the Fddd space group symmetry reproducing the structure of those observed in block copolymers. The finding that the geometry of constituent molecules isn't relevant for the formation of triply periodic networks indicates the generic nature of this class of phase transition

    Self-assembly of orthorhombic Fddd network in simple one-component liquids

    No full text
    Triply periodic continuous morphologies arising a result of the microphase separation in block copolymer melts have so far never been observed self-assembled in systems of particles with spherically symmetric interaction. We report a molecular dynamics simulation of two simple one-component liquids which self-assemble upon cooling into equilibrium orthorhombic continuous network morphologies with the Fddd space group symmetry reproducing the structure of those observed in block copolymers. The finding that the geometry of constituent molecules isn't relevant for the formation of triply periodic networks indicates the generic nature of this class of phase transition
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