516 research outputs found
One-Center Charge Transfer Transitions in Manganites
In frames of a rather conventional cluster approach, which combines the
crystal field and the ligand field models we have considered different charge
transfer (CT) states and O 2p-Mn 3d CT transitions in MnO octahedra.
The many-electron dipole transition matrix elements were calculated using the
Racah algebra for the cubic point group. Simple "local" approximation allowed
to calculate the relative intensity for all dipole-allowed and
CT transitions. We present a self-consistent description of
the CT bands in insulating stoichiometric LaMnO compound with the
only Mn valent state and idealized octahedral MnO centers
which allows to substantially correct the current interpretation of the optical
spectra. Our analysis shows the multi-band structure of the CT optical response
with the weak low-energy edge at 1.7 eV, associated with forbidden
transition and a series of the weak and strong
dipole-allowed high-energy transitions starting from 2.5 and 4.5 eV,
respectively, and extending up to nearly 11 eV. The most intensive features are
associated with two strong composite bands near eV and
eV, respectively, resulting from the superposition of the dipole-allowed
and CT transitions. These predictions are in good
agreement with experimental spectra. The experimental data point to a strong
overscreening of the crystal field parameter in the CT states of
MnO centers.Comment: 10 pages, 3 figure
Oxygen isotope effect and phase separation in the optical conductivity of (LaPr)CaMnO thin films
The optical conductivities of films of
(LaPr)CaMnO with different oxygen isotopes
(O and O) have been determined in the spectral range from 0.3 to
4.3 eV using a combination of transmission in the mid-infrared and ellipsometry
from the near-infrared to ultra-violet regions. We have found that the isotope
exchange strongly affects the optical response in the ferromagnetic phase in a
broad frequency range, in contrast to the almost isotope-independent optical
conductivity above . The substitution by O strongly suppresses the
Drude response and a mid-infrared peak while enhancing the conductivity peak at
1.5 eV. A qualitative explanation can be given in terms of the phase separation
present in these materials. Moreover, the optical response is similar to the
one extracted from measurements in polished samples and other thin films, which
signals to the importance of internal strain.Comment: 11 pages, 11 figures, to appear in PR
Microwave properties of Nd_0.5Sr_0.5MnO_3: a key role of the (x^2-y^2)-orbital effects
Transmittance of the colossal magnetoresistive compound Nd_0.5Sr_0.5MnO_3
showing metal-insulator phase transition has been studied by means of the
submm- and mm-wavelength band spectroscopy. An unusually high transparency of
the material provided direct evidence for the significant suppression of the
coherent Drude weight in the ferromagnetic metallic state. Melting of the
A-type antiferromagnetic states has been found to be responsible for a
considerable increase in the microwave transmission, which was observed at the
transition from the insulating to the metallic phase induced by magnetic field
or temperature. This investigation confirmed a dominant role of the
(x^2-y^2)-orbital degree of freedom in the low-energy optical properties of
Nd_0.5Sr_0.5MnO_3 and other doped manganites with planar (x^2-y^2)-orbital
order, as predicted theoretically. The results are discussed in terms of the
orbital-liquid concept.Comment: 8 pages, 3 figure
Orbital dynamics: The origin of the anomalous optical spectra in ferromagnetic manganites
We discuss the role of orbital degeneracy in the transport properties of
perovskite manganites, focusing in particular on the optical conductivity in
the metallic ferromagnetic phase at low temperatures. Orbital degeneracy and
strong correlations are described by an orbital t-J model which we treat in a
slave-boson approach. Employing the memory-function formalism we calculate the
optical conductivity, which is found to exhibit a broad incoherent component
extending up to bare bandwidth accompanied by a strong suppression of the Drude
weight. Further, we calculate the constant of T-linear specific heat. Our
results are in overall agreement with experiment and suggest low-energy orbital
fluctuations as the origin of the strongly correlated nature of the metallic
phase of manganites.Comment: To appear in: Phys. Rev. B 58 (Rapid Communications), 1 November 199
Gesture Detection Towards Real-Time Ergonomic Analysis for Intelligent Automation Assistance
Manual handling involves transporting of load by hand through lifting or lowering and operators on the manufacturing shop floor are daily faced with constant lifting and lowering operations which leads to Work-Related Musculoskeletal Disorders. The trend in data collection on the Shop floor for ergonomic evaluation during manual handling activities has revealed a gap in gesture detection as gesture triggered data collection could facilitate more accurate ergonomic data capture and analysis. This paper presents an application developed to detect gestures towards triggering real-time human motion data capture on the shop floor for ergonomic evaluations and risk assessment using the Microsoft Kinect. The machine learning technology known as the discrete indicator—precisely the AdaBoost Trigger indicator was employed to train the gestures. Our results show that the Kinect can be trained to detect gestures towards real-time ergonomic analysis and possibly offering intelligent automation assistance during human posture detrimental tasks
Spin/Orbital Pattern-Dependent Polaron Absorption in Nd(1-x)Sr(x)MnO3
We investigated optical properties of Nd(1-x)Sr(x)MnO3 (x= 0.40, 0.50, 0.55,
and 0.65) single crystals. In the spin/orbital disordered state, their
conductivity spectra look quite similar, and the strength of the mid-infrared
absorption peak is proportional to x(1-x) consistent with the polaron picture.
As temperature lowers, the Nd(1-x)Sr(x)MnO3 samples enter into various
spin/orbital ordered states, whose optical responses are quite different. These
optical responses can be explained by the spin/orbital ordering
pattern-dependent polaron hopping.Comment: 3 figures (gzipped
Metallic ferromagnetism without exchange splitting
In the band theory of ferromagnetism there is a relative shift in the
position of majority and minority spin bands due to the self-consistent field
due to opposite spin electrons. In the simplest realization, the Stoner model,
the majority and minority spin bands are rigidly shifted with respect to each
other. Here we consider models at the opposite extreme, where there is no
overall shift of the energy bands. Instead, upon spin polarization one of the
bands broadens relative to the other. Ferromagnetism is driven by the resulting
gain in kinetic energy. A signature of this class of mechanisms is that a
transfer of spectral weight in optical absorption from high to low frequencies
occurs upon spin polarization. We show that such models arise from generalized
tight binding models that include off-diagonal matrix elements of the Coulomb
interaction. For certain parameter ranges it is also found that reentrant
ferromagnetism occurs. We examine properties of these models at zero and finite
temperatures, and discuss their possible relevance to real materials
Interplay of charge and orbital ordering in manganese perovskites
A model of localized classical electrons coupled to lattice degrees of
freedom and, via the Coulomb interaction, to each other, has been studied to
gain insight into the charge and orbital ordering observed in lightly doped
manganese perovskites. Expressions are obtained for the minimum energy and
ionic displacements caused by given hole and electron orbital configurations.
The expressions are analyzed for several hole configurations, including that
experimentally observed by Yamada et al. in La_{7/8}Sr_{1/8}MnO_3. We find
that, although the preferred charge and orbital ordering depend sensitively on
parameters, there are ranges of the parameters in which the experimentally
observed hole configuration has the lowest energy. For these parameter values
we also find that the energy differences between different hole configurations
are on the order of the observed charge ordering transition temperature. The
effects of additional strains are also studied. Some results for
La_{1/2}Ca_{1/2}MnO_3 are presented, although our model may not adequately
describe this material because the high temperature phase is metallic.Comment: 12 pages in RevTex, 5 figures in PS files, to appear in Phys. Rev. B
(New paragraphs and references added, typos corrected
Polaron Absorption in a Perovskite Manganite La0.7Ca0.3MnO3
Temperature dependent optical conductivity spectra of a La0.7Ca0.3MnO3 (LCMO)
sample were measured. In the metallic regime at very low temperatures, they
clearly showed two types of absorption features, i.e., a sharp Drude peak and a
broad mid-infrared absorption band, which could be explained as coherent and
incoherent bands of a large lattice polaron. This elementary excitation in LCMO
was found to be in a strong coupling regime and to have interactions with the
spin degree of freedom.Comment: 4 pages and separate 4 figure
Optical Studies of a Layered Manganite La_{1.2}Sr_{1.8}Mn_2O_7 : Polaron Correlation Effect
Optical conductivity spectra of a cleaved ab-plane of a
La_{1.2}Sr_{1.8}Mn_2O_7 single crystal exhibit a small polaron absorption band
in the mid-infrared region at overall temperatures. With decreasing temperature
(T) to Curie temperature (T_C), the center frequency of the small polaron band
moves to a higher frequency, resulting in a gap-like feature, and that it
collapses to a lower frequency below T_C. Interestingly, with decreasing T, the
stretching phonon mode hardens above T_C and softens below T_C. These
concurring changes of lattice and electronic structure indicate that short
range polaron correlation exist above T_C but disappear with a magnetic
ordering.Comment: 4 pages including 5 figures. submitted to Phys. Rev.
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