Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure-Property Relationships.

Rapid improvements in polymer-electrolyte fuel-cell (PEFC) performance have been driven by the development of commercially available ion-conducting polymers (ionomers) that are employed as membranes and catalyst binders in membrane-electrode assemblies. Commercially available ionomers are based on a perfluorinated chemistry comprised of a polytetrafluoroethylene (PTFE) matrix that imparts low gas permeability and high mechanical strength but introduces significant mass-transport losses in the electrodes. These transport losses currently limit PEFC performance, especially for low Pt loadings. In this study, we present a novel ionomer incorporating a glassy amorphous matrix based on a perfluoro(2-methylene-4-methyl-1,3-dioxolane) (PFMMD) backbone. The novel backbone chemistry induces structural changes in the ionomer, restricting ionomer domain swelling under hydration while disrupting matrix crystallinity. These structural changes slightly reduce proton conductivity while significantly improving gas permeability. The performance implications of this trade-off are assessed, which reveal the potential for substantial performance improvement by incorporation of highly permeable ionomers as the functional catalyst binder. These results underscore the significance of tailoring material chemistry to specific device requirements, where ionomer chemistry should be rationally designed to match the local transport requirements of the device architecture

Micro-Welding Of High Thermal Conductive Material Aluminum-Graphite Composite By Pulsed ND:YAG Laser.

The development of advanced materials with superior high thermal properties and high specific strength has led to new metal matrix composites (MMCs) as a great attractive material in electrical and electronic industries. In order to manufacture more practical component from MMCs, a tech-nique for joining MMCs to other similar composites or monolithic materials is strongly required. Therefore, the reliable and economic joining technique is investigated to increase the applications of MMCs. In this study, the overlap welding of pure aluminum and super thermal conductive (STC) aluminum-graphite composite was experimentally and numerically investigated by using a pulsed Nd:YAG laser. In order to discuss the welding of dissimilar materials with different thermophysical properties, the temporal change of heat input was controlled by arranging the laser pulse waveform. The porosities and bumps were observed as the remarkable weld defects in the welding process without a pulse control. On the other hand, the weld bead was largely free of defects, and a size of bump was relatively small with the appropriate controlled pulse waveform. It was clarified that the laser welded joint of an aluminum and a STC aluminum-graphite composite could be successfully achieved with the better weld penetration stability by the appropriate controlled pulse waveform

重症慢性肝疾患における高γク口ブリン血症の意義 : とくに血清グ口プリン/IgG とICG除去能との相聞に関連して

BACKGROUND/AIMS:Although hyperglobulinemia is frequently detected in severe chronic liver diseases (CLD) such as liver cirrhosis (LC), the mechanism for this is still uncertain. Hyperglobulinemia may represent a functional aspect of the liver.METHODOLOGY: The correlation between serum globulin (GLB) level and each of various liver function tests including the indocyanine green (ICG) retention rate at 15 min (ICGR15) was studied using 146 patients with liver dysfunction. The correlations among GLB, IgG and ICGR15 were also studied in other 32 patients with LC, in whom the glycosylation pattern of IgG was determined by enzyme-linked immunosorbent assay to detect terminal galactose (Gal) and neuraminic acid (NA) using biotinylated lectins.RESULTS:GLB level was predominantly correlated with ICGR15 (r = 0.449) among various liver function tests in 146 patients with liver dysfunction. In the 32 patients with LC, strong positive correlations between GLB and IgG (r = 0.875), between GLB and ICGR15 (r = 0.435), and between IgG and ICGR15 (r = 0.557) were evident. The glycosylation pattern of IgG showed that the proportions of both Gal and NA were inversely correlated with serum IgG levels (r = -0.516 and -0.390, respectively) in these patients. Significant decreases of the proportions were found in patients with IgG elevation (> 20 g/L, n = 13).CONCLUSIONS:The correlation between GLB and ICGR15 suggested that hyperglobulinemia is related to a common dysfunction estimated by ICG clearance, which represents mainly the liver's blood flow and removal capacity. The removal of immunoglobulins by the liver may be impaired in patients with severe liver dysfunction because the liver is a major catabolic site for immunoglobulins. The glycation pattern suggested that the proportions of asialo IgG and agalactosyl IgG were increased in the LC patients with IgG elevation possibly by deficient receptor-mediated removal in the liver. Although further investigations will be needed, hyperglobulinemia could be predictive for a certain impaired hepatic function estimated by ICG clearance in severe CLD such as LC.博士（医学）・乙第1301号・平成24年7月26日Hepato Gastroenterology © 200

Notes on the Fauna of the Pterostichus Ground beetle in and around the Hiruzen Experimental Forest

鳥取大学蒜山演習林の生物多様性調査の一環として、同演習林および周辺地域でナガゴミムシ類Pterostichus (s.str) (Coleoptera, Carabidae)のチョウサを実施した。2001年～2002年にかけて、演習林内および周辺地域でピットフォールトラップを用いた採集を実施し、7種のナガゴミムシ類を採集した