Fuel quality/processing study. Volume 2: Appendix. Task 1 literature survey

The results of a literature survey of fuel processing and fuel quality are given. Liquid synfuels produced from coal and oil shale are discussed. Gas turbine fuel property specifications are discussed. On-site fuel pretreatment and emissions from stationary gas turbines are discussed. Numerous data tables and abstracts are given

Viking and Mars Rover exobiology

Other than Earth, Mars is the planet generating the greatest interest among those researching and contemplating the origin and distribution of life throughout the universe. The similarity of the early environments of Earth and Mars, and the biological evolution on early Earth provides the motivation to seriously consider the possibility of a primordial Martian biosphere. In 1975 the Viking project launched two unmanned spacecraft to Mars with the intent of finding evidence of the existence of present or past life on this planet. Three Viking Biology experiments were employed: the Labeled Release experiment, the Gas Exchange Experiment, and the Pyrolytic Release experiment. Each of these three experiments tested for microbial existence and utilization of a substrate by examining the gases evolved from specific chemical reactions. Although the results of these experiments were inconclusive, they inferred that there are no traces of extant life on Mars. However, the experiments did not specifically look for indication of extinct life. Therefore, most of the exobiologic strategies and experiments suggested for the Mars Rover Sample Return Mission involve searching for signature of extinct life. The most significant biological signatures and chemical traces to detect include: isotopic and chemical signatures of metabolic activity, anomalous concentrations of certain metals, trace and microfossils, organically preserved materials, carbonates, nitrates, and evaporites

Fuel quality processing study, volume 1

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants

Families of Quintic Calabi-Yau 3-Folds with Discrete Symmetries

At special loci in their moduli spaces, Calabi-Yau manifolds are endowed with discrete symmetries. Over the years, such spaces have been intensely studied and have found a variety of important applications. As string compactifications they are phenomenologically favored, and considerably simplify many important calculations. Mathematically, they provided the framework for the first construction of mirror manifolds, and the resulting rational curve counts. Thus, it is of significant interest to investigate such manifolds further. In this paper, we consider several unexplored loci within familiar families of Calabi-Yau hypersurfaces that have large but unexpected discrete symmetry groups. By deriving, correcting, and generalizing a technique similar to that of Candelas, de la Ossa and Rodriguez-Villegas, we find a calculationally tractable means of finding the Picard-Fuchs equations satisfied by the periods of all 3-forms in these families. To provide a modest point of comparison, we then briefly investigate the relation between the size of the symmetry group along these loci and the number of nonzero Yukawa couplings. We include an introductory exposition of the mathematics involved, intended to be accessible to physicists, in order to make the discussion self-contained.Comment: 54 pages, 3 figure

Two Kerr black holes with axisymmetric spins: An improved Newtonian model for the head-on collision and gravitational radiation

We present a semi-analytical approach to the interaction of two (originally) Kerr black holes through a head-on collision process. An expression for the rate of emission of gravitational radiation is derived from an exact solution to the Einstein's field equations. The total amount of gravitational radiation emitted in the process is calculated and compared to current numerical investigations. We find that the spin-spin interaction increases the emission of gravitational wave energy up to 0.2% of the total rest mass. We discuss also the possibility of spin-exchange between the holes.Comment: 8 pages, RevTeX, 2 figures, psbox macro include

Nonadditive entropy and nonextensive statistical mechanics - Some central concepts and recent applications

We briefly review central concepts concerning nonextensive statistical mechanics, based on the nonadditive entropy $S_q=k\frac{1-\sum_{i}p_i^q}{q-1} (q \in {\cal R}; S_1=-k\sum_{i}p_i \ln p_i)$. Among others, we focus on possible realizations of the $q$-generalized Central Limit Theorem, including at the edge of chaos of the logistic map, and for quasi-stationary states of many-body long-range-interacting Hamiltonian systems.Comment: 15 pages, 9 figs., to appear in Journal of Physics: Conf.Series (IOP, 2010

Liquid-like thermal conduction in a crystalline solid

A solid conducts heat through both transverse and longitudinal acoustic phonons, but a liquid employs only longitudinal vibrations. Here, we report that the crystalline solid AgCrSe2 has liquid-like thermal conduction. In this compound, Ag atoms exhibit a dynamic duality that they are exclusively involved in intense low-lying transverse acoustic phonons while they also undergo local fluctuations inherent in an order-to-disorder transition occurring at 450 K. As a consequence of this extreme disorder-phonon coupling, transverse acoustic phonons become damped as approaching the transition temperature, above which they are not defined anymore because their lifetime is shorter than the relaxation time of local fluctuations. Nevertheless, the damped longitudinal acoustic phonon survives for thermal transport. This microscopic insight might reshape the fundamental idea on thermal transport properties of matter and facilitates the optimization of thermoelectrics.Comment: four figures, supplemental informatio

Impact of the East Asian summer monsoon on long-term variations in the acidity of summer precipitation in Central China

The acidity of precipitation has been observed at stations of the Acid Rain Monitoring Network run by the China Meteorological Administration (CMA-ARMN) since 1992. Previous studies have shown that different long-term trends exist in different regions but detailed analysis of the causes of these is lacking. In this paper, we analyze summertime precipitation acidity data from the CMA-ARMN during 1992–2006 using EOFs and show that the summertime pH in China had different trends before and after 2000. The most significant decrease of pH is found in Central China. To investigate the causes of this decrease of pH in summer, we explore the relationship between changes in the pH value, the East Asian summer monsoon index, rainfall data, and pollutants emissions. We find that the East Asian summer monsoon can significantly affect the acidity of summer precipitation in Central China. In strong monsoon years, the pH in Central China is about 0.33 lower than that in weak monsoon years. Chemical transport model simulations using fixed emissions indicate that about 65% of the pH value difference (i.e., 0.22) is related to the summer monsoon, and constitutes 18–36% of the observed pH change (0.6∼1.2) in Central China during 1992–2006. Further studies reveal a relationship between the pH in Central China and the rainfall in the middle and lower reaches of the Yangtze River (MLYR), which can explain about 24% of the variance of pH in Central China. Simulations using an annually varying emission inventory show that at least 60% of the variation in precipitation acidity in Central China can be attributed to changes in pollutant emissions. Therefore, the increase in emissions of acidic species is the most important cause for the observed decrease of pH in Central China, and changes in meteorological factors, such as rainfall and other parameters related to the East Asian summer monsoon, play a less important but still significant role

Joint diffraction and modeling approach to the structure of liquid alumina

The structure of liquid alumina at a temperature ∼2400 K near its melting point was measured using neutron and high-energy x-ray diffraction by employing containerless aerodynamic–levitation and laser-heating techniques. The measured diffraction patterns were compared to those calculated from molecular dynamics simulations using a variety of pair potentials, and the model found to be in best agreement with experiments was refined using the reverse Monte Carlo method. The resultant model shows that the melt is composed predominantly of AlO4 and AlO5 units, in the approximate ratio of 2:1, with only minor fractions of AlO3 and AlO6 units. The majority of Al-O-Al connections involve corner-sharing polyhedra (83%), although a significant minority involve edge-sharing polyhedra (16%), predominantly between AlO5 and either AlO5 or AlO4 units. Most of the oxygen atoms (81%) are shared among three or more polyhedra, and the majority of these oxygen atoms are triply shared among one or two AlO4 units and two or one AlO5 units, consistent with the abundance of these polyhedra in the melt and their fairly uniform spatial distribution