Analysis of breakdown in ferromagnetic tunnel junctions

Due to their very thin tunnel barrier layer, magnetic tunnel junctions show dielectric breakdown at voltages of the order of 1 V. At the moment of breakdown, a highly conductive short is formed in the barrier and is visible as a hot spot. The breakdown effect is investigated by means of voltage ramp experiments on a series of nominally identical Co/Al2O3/Co tunnel junctions. The results are described in terms of a voltage dependent breakdown probability, and are further analyzed within the framework of a general model for the breakdown probability in dielectric materials, within which it is assumed that at any time the breakdown probability is independent of the (possibly time-dependent) voltage that has been previously applied. The experimental data can be described by several specific forms of the voltage breakdown probability function. A comparison with the models commonly used for describing thin film SiO2 breakdown is given, as well as suggestions for future experiments

Asymmetric bias voltage dependence of the magnetoresistance of Co/Al2O3/Co magnetic tunnel junctions: Variation with the barrier oxidation time

Recently it has been observed that the magnetoresistance (MR) of plasma oxidized exchange biased Co/Al2O3/Co tunnel junctions can have a strongly asymmetric bias voltage (Vbias) dependence. In this article we report on the dependence of this phenomenon on barrier oxidation time tox. For junctions based on 1.5 nm Al, tox was varied from 20 to 120 s. For tox = 20 s, for which the MR is approximately 20% at Vbias = 0, and for tox = 90 s symmetric MR(Vbias) curves are found, with the MR decreasing monotonically with |Vbias|. A strong asymmetric bias voltage dependence was observed for intermediate oxidation times, which correspond to essentially full oxidation of the Al layer, but almost no formation of stoichiometric CoO at the bottom electrode. Samples with tox = 60 s show even an asymmetric double peak in MR(Vbias). Due to its strength, it has an important consequence for device applications: for a series of junctions with variable tox the maximum signal voltage (at a fixed current) is not necessarily obtained for junctions which have the largest MR ratio at Vbias = 0. ©2001 American Institute of Physics

Perpendicular-current Studies of Electron Transport Across Metal/Metal Interfaces

We review what we have learned about the scattering of electrons by the interfaces between two different metals (M1/M2) in the current-perpendicular-to-plane (CPP) geometry. In this geometry, the intrinsic quantity is the specific resistance, AR, the product of the area through which the CPP current flows times the CPP resistance. We describe results for both non-magnetic/non-magnetic (N1/N2) and ferromagnetic/non-magnetic (F/N) pairs. We focus especially upon cases where M1/M2 are lattice matched (i.e., have the same crystal structure and the same lattice parameters to within ~ 1%), because in these cases no-free-parameter calculations of 2AR agree surprisingly well with measured values. But we also list and briefly discuss cases where M1/M2 are not lattice matched, either having different crystal structures, or lattice parameters that differ by several percent. The published calculations of 2AR in these latter cases do not agree so well with measured values.Comment: 6 pages, 2 figures, 2 tables. In Press: Applied Surface Scienc

CO adsorption on neutral iridium clusters

The adsorption of carbon monoxide on neutral iridium clusters in the size range of n = 3 to 21 atoms is investigated with infrared multiple photon dissociation spectroscopy. For each cluster size only a single v(CO) band is present with frequencies in the range between 1962 cm-1 (n = 8) and 1985 cm-1 (n = 18) which can be attributed to an atop binding geometry. This behaviour is compared to the CO binding geometries on clusters of other group 9 and 10 transition metals as well as to that on extended surfaces. The preference of Ir for atop binding is rationalized by relativistic effects on the electronic structure of the later 5d metals

Observation of band structure and density of states effects in Co-based magnetic tunnel junctions

Utilizing Co/Al$_2$O$_3$/Co magnetic tunnel junctions (MTJs) with Co electrodes of different crystalline phases, a clear relationship between electrode structure and junction transport properties is presented. For junctions with one fcc(111) textured and one polycrystalline (poly-phase and poly-directional) Co electrode, a strong asymmetry is observed in the magnetotransport properties, while when both electrodes are polycrystalline the magnetotransport is essentially symmetric. These observations are successfully explained within a model based on ballistic tunneling between the calculated band structures (DOS) of fcc-Co and hcp-Co.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let

Secondary structure of Ac-Alan_n-LysH+^+ polyalanine peptides (nn=5,10,15) in vacuo: Helical or not?

The polyalanine-based peptide series Ac-Ala_n-LysH+ (n=5-20) is a prime example that a secondary structure motif which is well-known from the solution phase (here: helices) can be formed in vacuo. We here revisit this conclusion for n=5,10,15, using density-functional theory (van der Waals corrected generalized gradient approximation), and gas-phase infrared vibrational spectroscopy. For the longer molecules (n=10,15) \alpha-helical models provide good qualitative agreement (theory vs. experiment) already in the harmonic approximation. For n=5, the lowest energy conformer is not a simple helix, but competes closely with \alpha-helical motifs at 300K. Close agreement between infrared spectra from experiment and ab initio molecular dynamics (including anharmonic effects) supports our findings.Comment: 4 pages, 4 figures, Submitted to JPC Letter

Optical creation of vibrational intrinsic localized modes in anharmonic lattices with realistic interatomic potentials

Using an efficient optimal control scheme to determine the exciting fields, we theoretically demonstrate the optical creation of vibrational intrinsic localized modes (ILMs) in anharmonic perfect lattices with realistic interatomic potentials. For systems with finite size, we show that ILMs can be excited directly by applying a sequence of femtosecond visible laser pulses at THz repetition rates. For periodic lattices, ILMs can be created indirectly via decay of an unstable extended lattice mode which is excited optically either by a sequence of pulses as described above or by a single picosecond far-infrared laser pulse with linearly chirped frequency. In light of recent advances in experimental laser pulse shaping capabilities, the approach is experimentally promising.Comment: 20 pages, 7 eps figures. Accepted, Phys. Rev.

Infrared Multiple Photon Dissociation Action Spectroscopy and Theoretical Studies of Diethyl Phosphate Complexes: Effects of Protonation and Sodium Cationization on Structure

The gas-phase structures of deprotonated, protonated, and sodium-cationized complexes of diethyl phosphate (DEP) including [DEP − H]−, [DEP + H]+, [DEP + Na]+, and [DEP − H + 2Na]+ are examined via infrared multiple photon dissociation (IRMPD) action spectroscopy using tunable IR radiation generated by a free electron laser, a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) with an electrospray ionization (ESI) source, and theoretical electronic structure calculations. Measured IRMPD spectra are compared to linear IR spectra calculated at the B3LYP/6-31G(d,p) level of theory to identify the structures accessed in the experimental studies. For comparison, theoretical studies of neutral complexes are also performed. These experiments and calculations suggest that specific geometric changes occur upon the binding of protons and/or sodium cations, including changes correlating to nucleic acid backbone geometry, specifically P–O bond lengths and ∠OPO bond angles. Information from these observations may be used to gain insight into the structures of more complex systems, such as nucleotides and solvated nucleic acids

Development of a pump-probe facility combining a far-infrared source with laser-like characteristics and a VUV free electron laser

The TESLA Test Facility (TTF) at DESY is a facility producing sub-picosecond electron pulses for the generation of VUV or soft X-ray radiation in a free electron laser (FEL). The same electron pulses would also allow the direct production of high-power coherent radiation by passing the electron beam through an undulator. Intense, coherent far-infrared (FIR) undulator radiation can be produced from electron bunches at wavelengths longer than or equal to the bunch length. The source described in this paper provides, in the wavelength range 50– 300 μm , a train of about 1– 10 ps long radiation pulses, with about 1 mJ of optical energy per pulse radiated into the central cone. The average output power can exceed 50 W . In this conceptual design, we intend to use a conventional electromagnetic undulator with a 60 cm period length and a maximum field of 1.5 T . The FIR source will use the spent electron beam coming from the VUV FEL which allows one to significantly extend the scientific potential of the TTF without interfering with the main option of the TTF FEL operation. The pulses of the coherent FIR radiation are naturally synchronized with the VUV pulses from the main TTF FEL, enabling pump-probe techniques using either the FEL pulse as a pump or the FIR pulse as a probe, or vice versa