Mossbauer and magnetization studies of amorphous NdFeB compositionally modulated thin films

Several NdFeB compositionally modulated thin films are studied by using both conversion electron Mossbauer spectra and SQUID (superconducting quantum-interference-device) magnetometry. Both the hyperfine fields and the easy magnetization magnitude are not correlated with the modulation characteristic length (lambda) while the magnetization perpendicular to the thin-film plane decreases as lambda increases. The spectra were recorded at room temperature being the gamma rays perpendicular to the substrate plane. The magnetization measurements were recorded by using a SHE SQUID magnetometer in applied magnetic fields up to 5.5 T and in the temperature range between 1.8 and 30 K

Ultra-high critical current densities of superconducting YBa2_2Cu3_3O7−δ_{7-\delta} thin films in the overdoped state

Doping is one of the most relevant paths to tune the functionality of cuprates, it determines carrier density and the overall physical properties of these impressive superconducting materials. We present an oxygen doping study of YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) thin films from underdoped to overdoped state, correlating the measured charge carrier density, $n_\textrm{H}$, the hole doping, $p$, and the critical current density, $J_\textrm{c}$. Our results show a continuous increase of $J_\textrm{c}$ with charge carrier density, reaching 90 MA/cm$^2$ at 5 K for $p$-doping at the Quantum Critical Point (QCP), linked to an increase of the superconducting condensation energy. The ultra-high $J_\textrm{c}$ achived corresponds to a third of the depairing current, i.e. a value 60 % higher than ever reported in YBCO films. The overdoped regime is characterized by a sudden increase of $n_\textrm{H}$, associated to the reconstruction of the Fermi-surface at the QCP. Overdoping YBCO opens a promising route to extend the current carrying capabilities of REBCO coated conductors for applications

Observation of insulator-metal transition in EuNiO3_{3} under high pressure

The charge transfer antiferromagnetic (T$_{N}$ =220 K) insulator EuNiO$_{3}$ undergoes, at ambient pressure, a temperature-induced metal insulator MI transition at T$_{MI}$=463 K. We have investigated the effect of pressure (up to p~20 GPa) on the electronic, magnetic and structural properties of EuNiO$_{3}$ using electrical resistance measurements, {151}^Eu nuclear resonance scattering of synchrotron radiation and x-ray diffraction, respectively. With increasing pressure we find at p$_{c}$ =5.8 GPa a transition from the insulating state to a metallic state, while the orthorhombic structure remains unchanged up to 20 GPa. The results are explained in terms of a gradual increase of the electronic bandwidth with increasing pressure, which results in a closing of the charge transfer gap. It is further shown that the pressure-induced metallic state exhibits magnetic order with a lowervalue of T$_{N}$ (T$_{N}$ ~120 K at 9.4 GPa) which disappears between 9.4 and 14.4 GPa.Comment: 10 pages, 3 figure

A hidden Goldstone mechanism in the Kagom\'e lattice antiferromagnet

In this paper, we study the phases of the Heisenberg model on the \kagome lattice with antiferromagnetic nearest neighbour coupling $J_1$ and ferromagnetic next neighbour coupling $J_2$. Analysing the long wavelength, low energy effective action that describes this model, we arrive at the phase diagram as a function of $\chi = \frac{J_2}{J_1}$. The interesting part of this phase diagram is that for small $\chi$, which includes $\chi =0$, there is a phase with no long range spin order and with gapless and spin zero low lying excitations. We discuss our results in the context of earlier, numerical and experimental work.Comment: 21 pages, latex file with 5 figure

Complejos de cefalexina con cationes de elementos del cuarto periodo. I.-Estudio en disolución acuosa

The formation of the complexes, in aqueous solution, between the cephalexin and sorne ious of the fourth period elements has been investigated by potentiometric and spectrophotometric methods. The stability constants has been determinated.Se ha investigado la formación de complejos, en disolución acuosa, de cefalexina [ácido 7-(D-2-amino-2-fenil-acetamido )-3-metil-8-oxo-S-tia-1-azabiciclo [4.2.O] oct-2-eno-2-carboxilico] con cationes de elementos del cuarto período, por métodos potenciométricos y espectrofotométricos. Se han determinado asímismo las constantes de formación de complejos

Complejos de cefalexina con cationes de elementos del cuarto periodo. I.-Estudio en disolución acuosa

Se ha investigado la formación de complejos, en disolución acuosa, de cefalexina [ácido 7-(D-2-amino-2-fenil-acetamido )-3-metil-8-oxo-S-tia-1-azabiciclo [4.2.O] oct-2-eno-2-carboxilico] con cationes de elementos del cuarto período, por métodos potenciométricos y espectrofotométricos. Se han determinado asímismo las constantes de formación de complejos.The formation of the complexes, in aqueous solution, between the cephaIexin and sorne ious of the fourth period elements has been investigated by potentiometric and spectrophotometric methods. The stability constants has been determinated

Cross-over between channeling and pinning at twin boundaries in YBa2Cu3O7 thin films

The critical current (Jc) of highly twinned YBa2Cu3O7 films has been measured as a function of temperature, magnetic field and angle. For much of the parameter space we observe a strong suppression of Jc for fields in the twin boundary (TB) directions; this is quantitatively modeled as flux-cutting-mediated vortex channeling. For certain temperatures and fields a cross-over occurs to a regime in which channeling is blocked and the TBs act as planar pinning centers so that TB pinning enhances the overall Jc. In this regime, intrinsic pinning along the TBs is comparable to that between the twins.Comment: Submitted to PR