Model tests on single batter piles subjected to lateral soil movement

A series of laboratory tests have been carried out to investigate the lateral response of battered piles under lateral soil movement. Model tests were carried out using instrumented rigid aluminium piles. The piles were embedded in homogeneous sand soil at batter angles &beta = 0°, ±10° and ±20° were subjected to two types of lateral soil movement profile. The results obtained from the study are presented in terms of the bending moment, shear force, soil reaction, pile rotation and lateral deflections along the length of the batter pile. The results of model tests on single vertical and batter piles under horizontal loads showed that the batter angle (&beta) significantly influenced the response of the batter piles. Regardless of the value of sand density, bending moment and deflection with batter angles &beta = +10° or positive batter piles were higher compared then vertical piles and negative batter piles

Photochromism and Solid State Photoluminescence of Bi and Pb Complexes and Coordination Polymers based on N-R-4,4’-bipyridinium entities (R= O-, CH3, CH2CN,…)

Date du colloque : 06/2013</p

Sensor systems for a changing ocean

The papers in this special section focus on sensor system deployment in the field of oceanography. Oceans regulate the Earth's climate and are integral to all known sources of life. Ocean processes are of biological, geological, chemical, or physical nature, occurring at micro- to kilometer scales, from less than seconds to centuries, turning the understanding and the sustainable management of the ocean into a multiscale and multidisciplinary effort. Collection of in situ observation of a volume that covers over 70% of the planet is also inherently challenging and remains generally difficult and costly in time and resources, with so far a rather unsatisfactory result, in particular with respect to space-time resolution. Over the past decade, there has been a steady crescendo of interest to support the development of a truly integrated and sustainably funded Ocean Observing System. This will be achieved with more long-term measurements of key parameters but is impaired by the costs and lack of reliability of ocean sensors in general.Postprint (author's final draft

Porous Coordination Polymers based on (bi)pyridinium Ligands

International audienc

Photochromic and Photluminescence Properties of N-substituted-4,4’-Bipyridinium based Complexes

Date du colloque : 10/2012International audienc

N-Methyl-4,4-bipyridinium and N-Methyl-N -oxide-4,4 -bipyridinium Bismuth Complexes - Photochromism and Photoluminescence in the Solid State

Three bismuth complexes based on N-methyl-4,4-bipyridinium (hMV(+)), (hMV)[Bi(hMV)Cl-5] (1), and N-methyl-N-oxide-4,4-bipyridinium (MVO+), [Bi(MVO)X-4(dmso)]center dot dmso [X = Cl (2), Br (3)], are reported. All three compounds show luminescence in the solid state with maxima at 545 nm (yellow for 1) and 560 nm (orange for 2 and 3) with quantum yields up to 10 %. Upon UV irradiation, 1 undergoes a color change from white to blue accompanied by a reduction of the photoluminescence intensity. The analysis of the crystal structure of the three complexes points to a photoinduced charge-transfer (PICT) process at the origin of the photochromism in 1

Rayleigh–Taylor instability in two-component relativistic jets

Relativistic jets associated with active galactic nuclei and gamma-ray bursts propagate over huge distances without significant loss of momentum. At the same time they are bright emitters, which is indicative of strong energy dissipation. This points towards a mechanism of internal dissipation which does not result in a global disruption of the flow. One possibility is internal shocks and another one is turbulence driven by local instabilities. Such instabilities can be triggered when a freely expanding jet is reconfined by either the cocoon or external gas pressure. In this paper, we study the dynamics of two-component spine-sheath hydrodynamic jets coming into pressure equilibrium with external gas using 2D computer simulations. We find that the jet oscillations lead to a rapid onset of Rayleigh–Taylor-type instabilities, which results in additional internal dissipation and mixing of the jet components. Although slightly different in details, this outcome holds both for the heavy-spine-light-sheath and light-spine-heavy-sheath configurations. The results may provide an explanation to the spatial flaring observed in some AGN jets on kpc-scales

Photochromism and Solid State Photoluminescence of Bi and Pb Complexes and Coordination Polymers based on N-R-4,4’-bipyridinium entities (R= O-, CH3, CH2CN)

Date du colloque : 05/2013</p

Bipyridinium Ligands: Highly Luminescent Bismuth Complexes

International audienc

Optical and morphological properties of thermally vacuum evaporated cdte thin films for photovoltaic apllications

International audienc