Relation between the High Density Phase and the Very-High Density Phase of Amorphous Solid Water

It has been suggested that high-density amorphous (HDA) ice is a structurally arrested form of high-density liquid (HDL) water, while low-density amorphous (LDA) ice is a structurally arrested form of low-density liquid (LDL) water. Recent experiments and simulations have been interpreted to support the possibility of a second "distinct" high-density structural state, named very high-density amorphous (VHDA) ice, questioning the LDL-HDL hypothesis. We test this interpretation using extensive computer simulations, and find that VHDA is a more stable form of HDA and that in fact VHDA should be considered as the amorphous ice of the quenched HDL.Comment: 5 pages, 4 fig

Gasification of oil palm empty fruit bunches (OPEFB) briquettes for bio-syngas production

Gasification of Oil Palm Empty Fruit Bunches (OPEFB) briquettes was investigated in an air blown 4.5 kW allothermal fluidized bed gasifier to examine the effects of bed temperature (600-800 °C) and equivalence ratio (λ = 0.25) on bio-syngas yield and composition. In addition, physicochemical and thermochemical characterization of the fuel properties of the OPEFB briquettes were also examined. The results demonstrate that pelletization improved the solid biomass fuel (SBF) properties of OPEFB including moisture content and higher heating value (HHV). The gasification of OPEFB briquettes produced bio-syngas comprising H2, CO, CO2, CH4 as well as solid biochar with a HHV higher than the original OPEFB briquettes. The highest yield of H2 was obtained at 600 °C while HHV of the bio-syngas was within the range 4-8 MJ/Nm3 for air gasification in fluidized bed gasifiers. In addition, agglomeration of bed materials did not occur during OPEFB briquettes gasification despite its high bed agglomeration potential (BAP). In conclusion, the gasification of OPEFB briquettes into bio-syngas and biochar is a practical route for bioenergy production in Malaysia

The relationship between fragility, configurational entropy and the potential energy landscape of glass forming liquids

Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled or compressed in such a fashion that it does not crystallise. Almost all types of materials are capable of glass formation -- polymers, metal alloys, and molten salts, to name a few. Given such diversity, organising principles which systematise data concerning glass formation are invaluable. One such principle is the classification of glass formers according to their fragility\cite{fragility}. Fragility measures the rapidity with which a liquid's properties such as viscosity change as the glassy state is approached. Although the relationship between features of the energy landscape of a glass former, its configurational entropy and fragility have been analysed previously (e. g.,\cite{speedyfr}), an understanding of the origins of fragility in these features is far from being well established. Results for a model liquid, whose fragility depends on its bulk density, are presented in this letter. Analysis of the relationship between fragility and quantitative measures of the energy landscape (the complicated dependence of energy on configuration) reveal that the fragility depends on changes in the vibrational properties of individual energy basins, in addition to the total number of such basins present, and their spread in energy. A thermodynamic expression for fragility is derived, which is in quantitative agreement with {\it kinetic} fragilities obtained from the liquid's diffusivity.Comment: 8 pages, 3 figure

Time-temperature superposition in viscous liquids

Dielectric relaxation measurements on supercooled triphenyl phosphite show that at low temperatures time-temperature superposition (TTS) is accurately obeyed for the primary (alpha) relaxation process. Measurements on 6 other molecular liquids close to the calorimetric glass transition indicate that TTS is linked to an $\omega^{-1/2}$ high-frequency decay of the alpha loss, while the loss peak width is nonuniversal.Comment: 4 page

Parameterized Supply Function Bidding: Equilibrium and Efficiency

We consider a model where a finite number of producers compete to meet an infinitely divisible but inelastic demand for a product. Each firm is characterized by a production cost that is convex in the output produced, and firms act as profit maximizers. We consider a uniform price market design that uses supply function bidding: firms declare the amount they would supply at any positive price, and a single price is chosen to clear the market. We are interested in evaluating the impact of price-anticipating behavior both on the allocative efficiency of the market and on the prices seen at equilibrium. We show that by restricting the strategy space of the firms to parameterized supply functions, we can provide upper bounds on both the inflation of aggregate cost at the Nash equilibrium relative to the socially optimal level, as well as the markup of the Nash equilibrium price above the competitive level: as long as N > 2 firms are competing, these quantities are both upper bounded by 1 + 1/(N − 2). This result holds even in the presence of asymmetric cost structure across firms. We also discuss several extensions, generalizations, and related issues.National Science Foundation (U.S.) (Graduate Research Fellowship)National Science Foundation (U.S.) (grant ECS-0312921

The Glass Transition Temperature of Water: A Simulation Study

We report a computer simulation study of the glass transition for water. To mimic the difference between standard and hyperquenched glass, we generate glassy configurations with different cooling rates and calculate the $T$ dependence of the specific heat on heating. The absence of crystallization phenomena allows us, for properly annealed samples, to detect in the specific heat the simultaneous presence of a weak pre-peak (``shadow transition''), and an intense glass transition peak at higher temperature. We discuss the implications for the currently debated value of the glass transition temperature of water. We also compare our simulation results with the Tool-Narayanaswamy-Moynihan phenomenological model.Comment: submitted to Phys. Re

Mechanical Relaxation in Glasses and at the Glass Transition

The Gilroy-Phillips model of relaxational jumps in asymmetric double-well potentials, developed for the Arrhenius-type secondary relaxations of the glass phase, is extended to a formal description of the breakdown of the shear modulus at the glass transition, the flow process.Comment: 13 pages, 11 figures, 49 ref