Spring molybdenum enrichment in scallop shells: a potential tracer of diatom productivity in temperate coastal environments (Brittany, NW France)

Skeletal molybdenum/calcium ([Mo]/[Ca])_shell ratios were examined in shells of the Great Scallop <i>Pecten maximus</i> collected in temperate coastal environments of Western Europe (42 to 49&deg; N). These ratios were determined by quantitative LA-ICP-MS analyses of daily striae taken every third day (i.e. a temporal resolution of 3 days) in 36 flat valves (2-years old; 3 shells/year). Variations of ([Mo]/[Ca])_shell ratios were significant and reproducible for scallops from the same population, from different years (1998–2004) and temperate coastal locations (NW France). The [Mo]/[Ca])_shell ratios exhibit typical profiles characterized by a background content, below the detection limit for this method (&lt;0.003 &mu;mol/mol) for most of the shell growth period, which is punctuated by a significant transient enrichment (0.031–2.1 &mu;mol/mol) mainly occurring from May to June. The Bay of Brest (France) was investigated in particular because of its long term observations on scallop communities, environmental variables, and high resolution analyses of dissolved Mo in bottom seawater in 2000. In 2000, dissolved Mo exhibited a significant increase in concentration just preceding the maximum ([Mo]/[Ca])_shell ratio. Both the intense monitoring survey in 2000 and over the 7-year period indicates that the ([Mo]/[Ca])_shell maximum is directly influenced by spring changes of environmental conditions at the sediment water interface (SWI), occurring subsequent to the intense and periodic spring bloom. Spring maxima of ([Mo]/[Ca])_shell ratios are closely correlated to the extent of silicic acid and nitrate depletion in seawater between winter and late spring (<i>r</i>²=0.878 and 0.780, <i>p</i><0.05, <i>n</i>=6) that reflects diatom uptake and productivity in the Bay of Brest. The Mo inputs in bottom waters and subsequent shell enrichment are thus suggested to be directly or indirectly influenced by such biogenic material input at the SWI. The [Mo]/[Ca])_shell records thus reveal unexpected biogeochemical cycles of Mo influenced by coastal spring productivity, faithfully recorded in scallop shells

Specificity and origin of the stability of the sr isotopic ratio in champagne wines

The 87Sr/86Sr ratio of 39 Champagnes from six different brands, originating from the whole “Appellation d’Origine Contrôlée” (AOC) Champagne was analyzed to establish a possible relation with the geographical origin. Musts (i.e., grape juice) and base wines were also analyzed to study the evolution of the Sr isotopic ratio during the elaboration process of sparkling wine. The results demonstrate that there is a very homogeneous Sr isotopic ratio (87 Sr/86 Sr = 0.70812, n = 37) and a narrow span of variability (2? = 0.00007, n = 37). Moreover, the Sr concentrations in Champagnes have also low variability, which can be in part explained by the homogeneity of the bedrock in the AOC Champagne. Measurements of the87 Sr/86 Sr ratio from musts and base wines show that blending during Champagne production plays a major role in the limited variability observed. Further, the87 Sr/86 Sr of the musts were closely linked to the87 Sr/86 Sr ratio of the vineyard soil. It appears that the87 Sr/86 Sr of the product does not change during the elaboration process, but its variability decreases throughout the process due to blending. Both the homogeneity of the soil composition in the Champagne AOC and the blending process during the wine making process with several blending steps at different stages account for the unique and stable Sr isotopic signature of the Champagne wines.Centre de Spectrometrie de Masse pour les Sciences de la Réactivité et de Spéciatio

Inorganic Mass Spectrometry

To establish a method for sensitive, accurate, and precise determination of Se in real samples, isotope dilution analysis using high-power nitrogen microwave-induced plasma mass spectrometry (N 2 MIP-IDMS) was conducted. In this study, freeze-dried human blood serum (Standard Reference Material, NIES No. 4) provided by NIES (National Institute for Environmental Studies) was used as a real sample. The measured isotopes of Se were 78 Se and 80 Se which are the major isotopes of Se. The appropriate amount of a Se spike solution was theoretically calculated by using an error multiplication factor (F) and was confirmed experimentally for the isotope dilution analysis. The mass discrimination effect was corrected for by using a standard Se solution for the measurement of Se isotope ratios in the spiked sample. However, the sensitivity for the detection of Se was not so good and the precision of the determination was not improved (2-3%) by N 2 MIP-IDMS with use of the conventional nebulizer. Therefore, a hydride generation system was connected to N 2 MIP-IDMS as a sample introduction system (HG-N 2 MIP-IDMS) in order to establish a more sensitive detection and a more precise determination of Se. A detection limit (3σ) of 10 pg mL -1 could be achieved, and the RSD was less than 1% at the concentration level of 5.0-10.0 ng mL -1 by HG-N 2 MIP-IDMS. The analytical results were found to be in a good agreement with those obtained by the standard addition method using conventional Ar ICPMS. It is well-known that Se is an essential element for all mammals. Se deficiency leads to deficiency syndromes, for example, Keshan disease, which is known for cardiac insufficiency that occurred in children and pregnant women in China. Problems also occur if the concentration of Se is too high; for example, gastroenteric disorders, dermatitis, and neurotic disorders are caused by excessive intake of Se. Moreover, it is well-known that the range of permissive intake amounts of Se is very narrow for human beings. Therefore, it is restricted as a toxic element in environmental standards. There are several sources of environmental Se pollution: the processes of Se refinement and the production processes of Se-containing products. For these reasons, the accurate and precise determination of trace levels of Se in environmental and biological samples is required, and studies of Se determination have been reported by several groups. [1][2][3][4][5][6][7][8][9][10][11] Because Ar ICPMS can measure multiple elements at a concentration range from ng mL -1 to fg mL -1 , it has widespread use in the determination of trace elements in various samples. 12-25 However

Rapport IV.3 Le rôle du cycle sédimentaire dans les flux de métaux traces en milieu estuarien macrotidal

The sedimentary cycle and trace metal fluxes in a macrotidal estuarine environment. A tentative biogeochemical model is proposed to explain the particulate — aqueous phase evolution of trace metal forms observed in the macrotidal Gironde Estuary, France. This qualitative model indicates the complementary nature of hydrodynamic, and of biological and chemical processes. Two main events can be distinguished : (1) sedimentation and development of slightly anaerobic conditions favoring the dissolution of iron coatings and of their associated trace metals, and (2) resuspension of deposited particles (precipitation of previously dissolved iron and scavenging of part of the previously liberated trace metals).Un modèle biogéochimique est proposé pour expliquer la transformation particulaire — dissous des métaux traces observée dans la Gironde, estuaire macrotidal. Ce modèle qualitatif met en évidence la complémentarité entre les processus hydrodynamiques conditionnant les périodes de sédimentation/remise en sus¬ pension du système bouchon vaseux/crème de vase et les processus biologiques et chimiques qui s’y déroulent. On distingue ainsi deux étapes (1) sédimentation-anaérobiose favorisant la solubilisation des métaux et (2) remise en suspension-aérobiose avec fixation sur le fer fraîchement précipité d’une partie des métaux traces libérés précédemment.Donard O., Bourg A. Rapport IV.3 Le rôle du cycle sédimentaire dans les flux de métaux traces en milieu estuarien macrotidal. In: L'hydraulique et la maitrise du littoral. Problèmes côtiers posés par le mouvement des sédiments et la pollution. Dix-huitièmes journées de l'hydraulique. Marseille, 11-13 septembre 1984. Tome 4, 1984

Grain-size partitioning of butyltins in estuarine and coastal sediments

Grain-size partitioning of tributyltin (TBT) and its degradation products di- and monobutyltin (DBT and MBT) in coastal sediments revealed a strong tendency on the part of these compounds to adsorb on to detrital fragments (algal and leaf debris mixed with light mineral particles). Butyltins have been weakly detected in sands washed from these debris, a finding which underlined the need to separate both fractions (sands and debris) for an accurate assessment of the grain size partitioning. In debris-free sediments, butyltins were mostly detected in the silt/clay fraction. It was found necessary to consider the total amount of butyltins in each fraction, and hence the relative proportion of each fraction, in order accurately to assess the grain-size partitioning of these compounds. At this stage however, it was difficult to determine whether butyltins were only adsorbed on the surface of particles (high adsorption capacities in organic debris and silt/clays) or strongly bound to organic matter