X-ray powder diffraction of high-absorption materials at the XRD1 beamline off the best conditions: Application to (Gd,Nd)5Si4 compounds

Representative compounds of the new family of magnetic materials Gd5-xNdxSi4 were analyzed by X-ray diffraction at the XRD1 beamline at LNLS. To reduce X-ray absorption, thin layers of the powder samples were mounted outside the capillaries and measured in Debye-Scherrer geometry as usual. The X-ray diffraction analyses and the magnetometry results indicate that the behavior of the magnetic transition temperature as a function of Nd content may be directly related to the average of the four smallest interatomic distances between different rare earth sites of the majority phase of each compound. The quality and consistency of the results show that the XRD1 beamline is able to perform satisfactory X-ray diffraction experiments on high-absorption materials even off the best conditions.Comment: 12 pages, 3 figures, 3 table

Coupling and higher-order effects in the 12C(d,p)13C and 13C(p,d)12C reactions

Coupled channels calculations are performed for the 12C(d,p)13C and 13C(p,d)12C reactions between 7 and 60 MeV to study the effect of inelastic couplings in transfer reactions. The effect of treating transfer beyond Born approximation is also addressed. The coupling to the 12C 2+ state is found to change the peak cross-section by up to 15 %. Effects beyond Born approximation lead to a significant renormalization of the cross-sections, between 5 and 10 % for deuteron energies above 10 MeV, and larger than 10 % for lower energies. We also performed calculations including the remnant term in the transfer operator, which has a small impact on the 12C(d,p)13C(g.s.) and 13C(p,d)12C(g.s.) reactions. Above 30 MeV deuteron energy, the effect of the remnant term is larger than 10 % for the 12C(d,p)13C(3.09 MeV) reaction and is found to increase with decreasing neutron separation energy for the 3.09 MeV state of 13C. This is of importance for transfer reactions with weakly bound nuclei.Comment: 7 pages, 7 figures, submitted to Phys. Rev.

Stability of the Period-Doubled Core of the 90-degree Partial in Silicon

In a recent Letter [N. Lehto and S. Oberg, Phys. Rev. Lett. 80, 5568 (1998)], Lehto and Oberg investigated the effects of strain fields on the core structure of the 90-degree partial dislocation in silicon, especially the influence of the choice of supercell periodic boundary conditions in theoretical simulations. We show that their results for the relative stability between the two structures are in disagreement with cell-size converged tight-binding total energy (TBTE) calculations, which suggest the DP core to be more stable, regardless of the choice of boundary condition. Moreover, we argue that this disagreement is due to their use of a Keating potential.Comment: 1 page. Submitted to Comments section of PRL. Also available at http://www.physics.rutgers.edu/~dhv/preprints/rn_dcom/index.htm

Stochastic oscillations in models of epidemics on a network of cities

We carry out an analytic investigation of stochastic oscillations in a susceptible-infected-recovered model of disease spread on a network of $n$ cities. In the model a fraction $f_{jk}$ of individuals from city $k$ commute to city $j$, where they may infect, or be infected by, others. Starting from a continuous time Markov description of the model the deterministic equations, which are valid in the limit when the population of each city is infinite, are recovered. The stochastic fluctuations about the fixed point of these equations are derived by use of the van Kampen system-size expansion. The fixed point structure of the deterministic equations is remarkably simple: a unique non-trivial fixed point always exists and has the feature that the fraction of susceptible, infected and recovered individuals is the same for each city irrespective of its size. We find that the stochastic fluctuations have an analogously simple dynamics: all oscillations have a single frequency, equal to that found in the one city case. We interpret this phenomenon in terms of the properties of the spectrum of the matrix of the linear approximation of the deterministic equations at the fixed point.Comment: 13 pages, 7 figure

Modeling the long term dynamics of pre-vaccination pertussis

The dynamics of strongly immunizing childhood infections is still not well understood. Although reports of successful modeling of several incidence data records can be found in the literature, the key determinants of the observed temporal patterns have not been clearly identified. In particular, different models of immunity waning and degree of protection applied to disease and vaccine induced immunity have been debated in the literature on pertussis. Here we study the effect of disease acquired immunity on the long term patterns of pertussis prevalence. We compare five minimal models, all of which are stochastic, seasonally forced, well-mixed models of infection based on susceptible-infective-recovered dynamics in a closed population. These models reflect different assumptions about the immune response of naive hosts, namely total permanent immunity, immunity waning, immunity waning together with immunity boosting, reinfection of recovered, and repeat infection after partial immunity waning. The power spectra of the output prevalence time series characterize the long term dynamics of the models. For epidemiological parameters consistent with published data for pertussis, the power spectra show quantitative and even qualitative differences that can be used to test their assumptions by comparison with ensembles of several decades long pre-vaccination data records. We illustrate this strategy on two publicly available historical data sets.Comment: paper (31 pages, 11 figures, 1 table) and supplementary material (19 pages, 5 figures, 2 tables

Firm Performance and Modes of Innovation

It has been shown that firms tend to develop different modes of innovation, based on the relationship between the different types of underlying knowledge and learning processes. This paper seeks to identify different modes of business innovation, relating them to firms’ innovative and economic performance, and to analyze the relationship between the different innovation modes and the economic impact of the crisis on firms’ performance. These hypotheses are tested by regression and latent class models for the Portuguese population of firms, using a sample of 397 firms, classified according to technological intensity, firm size and region. Our results show three different modes of innovation in terms of the relationship between economic and innovative performance, with significant differences in terms of resilience in the face of the economic crisis. These findings lead to a reflection on innovation, competitiveness and regional policy.FC

Making sense of the sharing economy: a category formation approach

The sharing economy (SE) has drawn significant attention from several society stakeholders in the last five years. While business actors are interested in financial opportunities to meet consumer needs, new business models, academia and governmental organisations are concerned with potential unintended effects on society and the environment. Despite its notable global growth, there is still a lack of more solid ground in understanding its origins and respective mechanisms through which it has been evolving as a category. This research addresses the problematics of the origins and ascendency of the SE by examining the process by which it is arising as a new category, searching for conceptual clarification, and pinpointing the legitimacy granted by stakeholders. Our guiding research questions are: how the SE was formed and evolved as a category, and as a category, is the SE legitimate? Additionally, we attempt to identify the nature of the SE as a category. Making a historical analysis of the expression SE and its equivalents, this paper deepens the discussion about the SE’s nature by providing evidence that it has predominantly been formed by emergence processes, comprising social movement, similarity clustering, and truce components, which render the SE a particular case of category formation and allow communication, entrepreneurship, regulation, and research about what it is. Moreover, the findings reveal a generalised legitimacy granted to the SE by a vast number of stakeholders, although still lacking the consolidation of socio-political legitimation. The SE’s nature seems to fall into a metaphorical approach, notably, the notion of radial categories.info:eu-repo/semantics/publishedVersio

Temperature effects on dislocation core energies in silicon and germanium

Temperature effects on the energetics of the 90-degree partial dislocation in silicon and germanium are investigated, using non-equilibrium methods to estimate free energies, coupled with Monte Carlo simulations. Atomic interactions are described by Tersoff and EDIP interatomic potentials. Our results indicate that the vibrational entropy has the effect of increasing the difference in free energy between the two possible reconstructions of the 90-degree partial, namely, the single-period and the double-period geometries. This effect further increases the energetic stability of the double-period reconstruction at high temperatures. The results also indicate that anharmonic effects may play an important role in determining the structural properties of these defects in the high-temperature regime.Comment: 8 pages in two-column physical-review format with six figure