435 research outputs found
Quantitative treatment of the creep of metals by dislocation and rate-process theories
An equation for the steady-state rate of creep has been derived by applying the theory of dislocations to the creep of pure metals. The form of this equation is in agreement with empirical equations describing creep rates. The theory was also used to predict the dependence of steady-state rate of creep on physical constants of the material and good agreement was obtained with data in the literature for pure annealed metals. The rate of creep was found to decrease with increasing modulus of rigidity. This relation suggest that one of the requirements for a heat-resisting alloy is that its matrix be a metal that has a high modulus of rigidity and therefore a high modulus of elasticity
Phase transitions and phase diagram of the ferroelectric perovskite NBT-BT by anelastic and dielectric measurements
The complex elastic compliance and dielectric susceptibility of
(Na_{0.5}Bi_{0.5})_{1-x}Ba_{x}TiO_{3} (NBT-BT) have been measured in the
composition range between pure NBT and the morphotropic phase boundary
included, 0 <= x <= 0.08. The compliance of NBT presents sharp peaks at the
rhombohedral/tetragonal and tetragonal/cubic transitions, allowing the
determination of the tetragonal region of the phase diagram, up to now
impossible due to the strong lattice disorder and small distortions and
polarizations involved. In spite of ample evidence of disorder and structural
heterogeneity, the R-T transition remains sharp up to x = 0.06, whereas the T-C
transition merges into the diffuse and relaxor-like transition associated with
broad maxima of the dielectric and elastic susceptibilities. An attempt is made
at relating the different features in the anelastic and dielectric curves to
different modes of octahedral rotations and polar cation shifts. The
possibility is also considered that the cation displacements locally have
monoclinic symmetry, as for PZT near the morphotropic phase boundary.Comment: 11 pages, 9 figures, submitted to Phys. Rev.
Low-temperature phase transformations of PZT in the morphotropic phase-boundary region
We present anelastic and dielectric spectroscopy measurements of
PbZr(1-x)Ti(x)O(3) with 0.455 < x < 0.53, which provide new information on the
low temperature phase transitions. The tetragonal-to-monoclinic transformation
is first-order for x < 0.48 and causes a softening of the polycrystal Young's
modulus whose amplitude may exceed the one at the cubic-to-tetragonal
transformation; this is explainable in terms of linear coupling between shear
strain components and tilting angle of polarization in the monoclinic phase.
The transition involving rotations of the octahedra below 200 K is visible both
in the dielectric and anelastic losses, and it extends within the tetragonal
phase, as predicted by recent first-principle calculations.Comment: 4 pages, 4 figure
Effect of doping and oxygen vacancies on the octahedral tilt transitions in the BaCeO3 perovskite
We present a systematic study of the effect of Y doping and hydration level
on the structural transformations of BaCeO3 based on anelastic spectroscopy
experiments. The temperature of the intermediate transformation between
rhombohedral and orthorhombic Imma phases rises with increasing the molar
fraction x of Y roughly as (500 K)x in the hydrated state, and is depressed of
more than twice that amount after complete dehydration. This is explained in
terms of the effect of doping on the average (Ce/Y)-O and Ba-O bond lengths,
and of lattice relaxation from O vacancies. The different behavior of the
transition to the lower temperature Pnma orthorhombic phase is tentatively
explained in terms of progressive flattening of the effective shape of the OH
ion and ordering of the O vacancies during cooling.Comment: 8 pages, 5 figure
Hydrogen tunneling in the perovskite ionic conductor BaCe(1-x)Y(x)O(3-d)
We present low-temperature anelastic and dielectric spectroscopy measurements
on the perovskite ionic conductor BaCe(1-x)Y(x)O(3-x/2) in the protonated,
deuterated and outgassed states. Three main relaxation processes are ascribed
to proton migration, reorientation about an Y dopant and tunneling around a
same O atom. An additional relaxation maximum appears only in the dielectric
spectrum around 60 K, and does not involve H motion, but may be of electronic
origin, e.g. small polaron hopping. The peak at the lowest temperature,
assigned to H tunneling, has been fitted with a relaxation rate presenting
crossovers from one-phonon transitions, nearly independent of temperature, to
two-phonon processes, varying as T^7, to Arrhenius-like. Substituting H with D
lowers the overall rate by 8 times. The corresponding peak in the dielectric
loss has an intensity nearly 40 times smaller than expected from the classical
reorientation of the electric dipole associated with the OH complex. This fact
is discussed in terms of coherent tunneling states of H in a cubic and
orthorhombically distorted lattice, possibly indicating that only H in the
symmetric regions of twin boundaries exhibit tunneling, and in terms of
reduction of the effective dipole due to lattice polarization.Comment: submitted to Phys. Rev.
Double polarization hysteresis loop induced by the domain pinning by defect dipoles in HoMnO3 epitaxial thin films
We report on antiferroelectriclike double polarization hysteresis loops in
multiferroic HoMnO3 thin films below the ferroelectric Curie temperature. This
intriguing phenomenon is attributed to the domain pinning by defect dipoles
which were introduced unintentionally during film growth process. Electron
paramagnetic resonance suggests the existence of Fe1+ defects in thin films and
first principles calculations reveal that the defect dipoles would be composed
of oxygen vacancy and Fe1+ defect. We discuss migration of charged point
defects during film growth process and formation of defect dipoles along
ferroelectric polarization direction, based on the site preference of point
defects. Due to a high-temperature low-symmetry structure of HoMnO3, aging is
not required to form the defect dipoles in contrast to other ferroelectrics
(e.g., BaTiO3).Comment: 4 figure
Materials science experiments in space
The criteria for the selection of the experimental areas and individual experiments were that the experiment or area must make a meaningful contribution to the field of material science and that the space environment was either an absolute requirement for the successful execution of the experiment or that the experiment can be more economically or more conveniently performed in space. A number of experimental areas and individual experiments were recommended for further consideration as space experiments. Areas not considered to be fruitful and others needing additional analysis in order to determine their suitability for conduct in space are also listed. Recommendations were made concerning the manner in which these materials science experiments are carried out and the related studies that should be pursued
Octahedral tilting, monoclinic phase and the phase diagram of PZT
Anelastic and dielectric spectroscopy measurements on PZT close to the
morphotropic (MPB) and antiferroelectric boundaries provide new insight in some
controversial aspects of its phase diagram. No evidence is found of a border
separating monoclinic (M) from rhombohedral (R) phases, in agreement with
recent structural studies supporting a coexistence of the two phases over a
broad composition range x < 0.5, with the fraction of M increasing toward the
MPB. It is also discussed why the observed maximum of elastic compliance
appears to be due to a rotational instability of the polarisation and therefore
cannot be explained by extrinsic softening from finely twinned R phase alone,
but indicates the presence also of M phase, not necessarily homogeneous.
A new diffuse transition is found within the ferroelectric phase near x ~
0.1, at a temperature T_IT higher than the well established boundary T_T to the
phase with tilted octahedra. It is proposed that around T_IT the octahedra
start rotating in a disordered manner and finally become ordered below T_T. In
this interpretation, the onset temperature for octahedral tilting monotonically
increases up to the antiferroelectric transition of PbZrO3, and the depression
of T_T(x) below x = 0.18 would be a consequence of the partial relieve of the
mismatch between the cation radii with the initial stage of tilting below T_IT.Comment: submitted to J. Phys.: Condens. Matte
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