1,185 research outputs found
Compressing Random Microstructures via Stochastic Wang Tilings
This paper presents a stochastic Wang tiling based technique to compress or
reconstruct disordered microstructures on the basis of given spatial
statistics. Unlike the existing approaches based on a single unit cell, it
utilizes a finite set of tiles assembled by a stochastic tiling algorithm,
thereby allowing to accurately reproduce long-range orientation orders in a
computationally efficient manner. Although the basic features of the method are
demonstrated for a two-dimensional particulate suspension, the present
framework is fully extensible to generic multi-dimensional media.Comment: 4 pages, 6 figures, v2: minor changes as suggested by reviewers, v3:
corrected two typos in the revised versio
Mixing-induced anisotropic correlations in molecular crystalline systems
We investigate the structure of mixed thin films composed of pentacene (PEN)
and diindenoperylene (DIP) using X-ray reflectivity and grazing incidence X-ray
diffraction. For equimolar mixtures we observe vanishing in-plane order
coexisting with an excellent out-of-plane order, a yet unreported disordering
behavior in binary mixtures of organic semiconductors, which are crystalline in
their pure form. One approach to rationalize our findings is to introduce an
anisotropic interaction parameter in the framework of a mean field model. By
comparing the structural properties with those of other mixed systems, we
discuss the effects of sterical compatibility and chemical composition on the
mixing behavior, which adds to the general understanding of interactions in
molecular mixtures.Comment: 5 pages, 5 figures, accepted by Phys. Rev. Let
Mn incorporation in as-grown and annealed (Ga,Mn)As layers studied by x-ray diffraction and standing-wave uorescence
A combination of high-resolution x-ray diffraction and a new technique of
x-ray standing wave uorescence at grazing incidence is employed to study the
structure of (Ga,Mn)As diluted magnetic semiconductor and its changes during
post-growth annealing steps. We find that the film is formed by a uniform,
single crystallographic phase epilayer covered by a thin surface layer with
enhanced Mn concentration due to Mn atoms at random non-crystallographic
positions. In the epilayer, Mn incorporated at interstitial position has a
dominant effect on lattice expansion as compared to substitutional Mn. The
expansion coeffcient of interstitial Mn estimated from our data is consistent
with theory predictions. The concentration of interstitial Mn and the
corresponding lattice expansion of the epilayer are reduced by annealing,
accompanied by an increase of the density of randomly distributed Mn atoms in
the disordered surface layer. Substitutional Mn atoms remain stable during the
low-temperature annealing.Comment: 9 pages, 9 figure
The influence of lithium excess in the target on the properties andcompositions of Li1+ x Mn2O4− δ thin films prepared by PLD
Li-Mn-O thin films were deposited by pulsed laser deposition (PLD) onto stainless steel substrates using targets containing different concentrations of added Li2O. The influence of the target composition on the stoichiometry of the resulting thin films, the surface morphology and the electrochemical properties was studied. The application of the target with added 7.5 mol% Li2O results in an almost ideal lithium content, while all films were still oxygen deficient. The thin films were applied as electrodes in Li//Li1+x Mn2O4−δ cells (i.e. model cells for a rechargeable Li-ion battery) and characterized by cyclic voltammetry and galvanostatic charge/discharge experiments. The electrochemical measurements of the thin films confirmed that the thin films can serve as good model systems and that they show a sufficient cyclabilit
- …