448 research outputs found
Extrusion de l'Eudragit E100 assistée par du CO 2 supercritique : détermination de la distribution des temps de séjour
National audienceL'extrusion est un procédé largement utilisé industriellement pour la mise en forme de matériaux. Dans ce travail, nous nous intéressons plus particulièrement à l'utilisation du dioxyde de carbone supercritique (CO 2 Sc) comme agent porogène pour la fabrication de mousses polymères par extrusion. Pour cela, une extrudeuse monovis a été modifiée afin de pouvoir injecter du CO 2 Sc dissous au sein de la matière extrudée et ainsi fabriquer des mousses. La présence de CO 2 Sc au sein de la matière modifie entre autres les propriétés rhéologiques du matériau et a donc une influence sur l'écoulement dans l'extrudeuse. Afin de caractériser l'écoulement de la matière au sein de l'extrudeuse, des expériences de traçage ont été réalisées en présence et en absence de CO 2. Cela nous a permis de mettre en évidence l'écart de l'écoulement réel à un écoulement piston ainsi que l'influence de la présence de CO 2 dans l'extrudeuse. Mots-clés : extrusion, Eudragit E100, distribution des temps de séjour, dioxyde de carbone, supercritiqu
Biexciton oscillator strength
Our goal is to provide a physical understanding of the elementary coupling
between photon and biexciton and to derive the physical characteristics of the
biexciton oscillator strength, following the procedure we used for trion.
Instead of the more standard two-photon absorption, this work concentrates on
molecular biexciton created by photon absorption in an exciton gas. We first
determine the appropriate set of coordinates in real and momentum spaces to
describe one biexciton as two interacting excitons. We then turn to second
quantization and introduce the "Fourier transform in the exciton sense" of the
biexciton wave function which is the relevant quantity for oscillator strength.
We find that, like for trion, the oscillator strength for the formation of one
biexciton out of one photon plus a \emph{single} exciton is extremely small: it
is one biexciton volume divided by one sample volume smaller than the exciton
oscillator strength. However, due to their quantum nature, trion and biexciton
have absorption lines which behave quite differently. Electrons and trions are
fermionic particles impossible to pile up all at the same energy. This would
make the weak trion line spread with electron density, the peak structure only
coming from singular many-body effects. By contrast, the bosonic nature of
exciton and biexciton makes the biexciton peak mainly rise with exciton
density, this rise being simply linear if we forget many-body effects between
the photocreated exciton and the excitons present in the sample
Auger decay of degenerate and Bose-condensed excitons in CuO
We study the non-radiative Auger decay of excitons in CuO, in which two
excitons scatter to an excited electron and hole. The exciton decay rate for
the direct and the phonon-assisted processes is calculated from first
principles; incorporating the band structure of the material leads to a
relatively shorter lifetime of the triplet state ortho excitons. We compare our
results with the Auger decay rate extracted from data on highly degenerate
triplet excitons and Bose-condensed singlet excitons in CuO.Comment: 15 pages, revtex, figures available from G. Kavoulaki
On a biphononic origin of the 1125 cm^(-1) absorption band in cuprous oxide
We report on the IR spectroscopic studies in both reflection (50-900 cm^{-1})
and transmission (900-3000 cm^{-1}) mode of the vibration spectrum of the
cuprous oxide. A detailed analysis based on a comparison of the temperature
dependences of the absorption band at 1125 cm^{-1} and of IR and Raman active
fundamental vibrations results in assignment of the former to a biphonon.Comment: 5 pages, 5 figures (to appear in Phys.Lett. A
Mesenchymal Stromal Cells Fail to Prevent Acute Graft-versus-Host Disease and Graft Rejection after Dog Leukocyte Antigen-Haploidentical Bone Marrow Transplantation
Mesenchymal stromal cells (MSCs) have been shown to have immunosuppressive effects in vitro. To test the hypothesis that these effects can be harnessed to prevent graft-versus-host disease (GVHD) and graft rejection after hematopoietic cell transplantation (HCT), we administered a combination of 3 different immortalized marrow-derived MSC lines (15-30 × 106 MSCs/kg/day, 2-5 times/week) or third-party primary MSC (1.0 × 106 MSCs/kg/day, 3 times/week) to canine recipients (n = 15) of dog leukocyte antigen–haploidentical marrow grafts prepared with 9.2 Gy of total body irradiation. Additional pharmacological immunosuppression was not given after HCT. Before their in vivo use, the MSC products were shown to suppress alloantigen-induced T cell proliferation in a dose-dependent, major histocompatibility complex–unrestricted, and cell contact–independent fashion in vitro. Among 14 evaluable dogs, 7 (50%) rejected their grafts and 7 engrafted, with ensuing rapidly fatal acute GVHD (50%). These observations were not statistically different from outcomes obtained with historical controls (n = 11) not given MSC infusions (P = .69). Thus, survival curves for MSC-treated dogs and controls were virtually superimposable (median survival, 18 vs 15 days, respectively). Finally, outcomes of dogs given primary MSCs (n = 3) did not appear to be different from those given clonal MSCs (n = 12). In conclusion, our data fail to demonstrate MSC-mediated protection against GVHD and allograft rejection in this model
Resonant inelastic x-ray scattering study of the electronic structure of CuO
A resonant inelastic x-ray scattering study of the electronic structure of
the semiconductor cuprous oxide, , is reported. When the incident
x-ray energy is tuned to the Cu K-absorption edge, large enhancements of the
spectral features corresponding to the electronic transitions between the
valence band and the conduction band are observed. A feature at 6.5 eV can be
well described by an interband transition from occupied states of mostly Cu 3d
charactor to unoccupied states with mixed 3d, 4s and 2p character. In addition,
an insulating band gap is observed, and the momentum dependence of the lower
bound is measured along the direction. This is found to be in good
agreement with the valence band dispersion measured with angle-resolved
photoemission spectroscopy.Comment: 7 pages, 6 figure
The Yellow Excitonic Series of Cu2O Revisited by Lyman Spectroscopy
We report on the observation of the yellow exciton Lyman series up to the
fourth term in Cu2O by time-resolved mid-infrared spectroscopy. The dependence
of the oscillator strength on the principal quantum number n can be well
reproduced using the hydrogenic model including an AC dielectric constant, and
precise information on the electronic structure of the 1s exciton state can be
obtained. A Bohr radius a_{1s}=7.9 A and a 1s-2p transition dipole moment
\mu_{1s-2p}= 4.2 eA were found
Fine structure of excitons in CuO
Three experimental observations on 1s-excitons in CuO are not consistent
with the picture of the exciton as a simple hydrogenic bound state: the
energies of the 1s-excitons deviate from the Rydberg formula, the total exciton
mass exceeds the sum of the electron and hole effective masses, and the
triplet-state excitons lie above the singlet. Incorporating the band structure
of the material, we calculate the corrections to this simple picture arising
from the fact that the exciton Bohr radius is comparable to the lattice
constant. By means of a self-consistent variational calculation of the total
exciton mass as well as the ground-state energy of the singlet and the
triplet-state excitons, we find excellent agreement with experiment.Comment: Revised abstract; 10 pages, revtex, 3 figures available from G.
Kavoulakis, Physics Department, University of Illinois, Urban
Particle density fluctuations
Event-by-event fluctuations in the multiplicities of charged particles and
photons at SPS energies are discussed. Fluctuations are studied by controlling
the centrality of the reaction and rapidity acceptance of the detectors.
Results are also presented on the event-by-event study of correlations between
the multiplicity of charged particles and photons to search for DCC-like
signals.Comment: Talk presented at Quark Matter 2002, Nantes, Franc
Azimuthal Anisotropy of Photon and Charged Particle Emission in Pb+Pb Collisions at 158 A GeV/c
The azimuthal distributions of photons and charged particles with respect to
the event plane are investigated as a function of centrality in Pb + Pb
collisions at 158 A GeV/c in the WA98 experiment at the CERN SPS. The
anisotropy of the azimuthal distributions is characterized using a Fourier
analysis. For both the photon and charged particle distributions the first two
Fourier coefficients are observed to decrease with increasing centrality. The
observed anisotropies of the photon distributions compare well with the
expectations from the charged particle measurements for all centralities.Comment: 8 pages and 6 figures. The manuscript has undergone a major revision.
The unwanted correlations were enhanced in the random subdivision method used
in the earlier version. The present version uses the more established method
of division into subevents separated in rapidity to minimise short range
correlations. The observed results for charged particles are in agreement
with results from the other experiments. The observed anisotropy in photons
is explained using flow results of pions and the correlations arising due to
the decay of the neutral pion
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