Ehrenfest relations at the glass transition: solution to an old paradox

In order to find out whether there exists a thermodynamic description of the glass phase, the Ehrenfest relations along the glass transition line are reconsidered. It is explained that the one involving the compressibility is always satisfied, and that the one involving the specific heat is principally incorrect. Thermodynamical relations are presented for non-ergodic systems with a one-level tree in phase space. They are derived for a spin glass model, checked for other models, and expected to apply, e.g., to glass forming liquids. The second Ehrenfest relation gets a contribution from the configurational entropy.Comment: 4 pages revtex, to appear in Phys. Rev. Let

Thermodynamics of the glassy state: effective temperature as an additional system parameter

A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasi-equilibrium at an effective temperature. It enters thermodynamic relations with the configurational entropy as conjugate variable. Slow fluctuations contribute to susceptibilities via quasi-equilibrium relations, while there is also a configurational term. Fluctuation-dissipation relations also involve the effective temperature. Fluctuations in the energy are non-universal, however. The picture is supported by analytically solving the dynamics of a toy model.Comment: 5 pages, REVTEX. Phys. Rev. Lett, to appea

Third Cumulant of the total Transmission of diffuse Waves

The probability distribution of the total transmission is studied for waves multiple scattered from a random, static configuration of scatterers. A theoretical study of the second and third cumulant of this distribution is presented. Within a diagrammatic approach a theory is developed which relates the third cumulant normalized to the average, $\langle \langle T_a^3 \rangle \rangle$, to the normalized second cumulant $\langle \langle T_a^2 \rangle \rangle$. For a broad Gaussian beam profile it is found that $\langle \langle T_a^3 \rangle \rangle= \frac{16}{5} \langle \langle T_a^2 \rangle \rangle^2$. This is in good agreement with data of optical experiments.Comment: 16 pages revtex, 8 separate postscript figure

Thermodynamic picture of the glassy state

A picture for thermodynamics of the glassy state is introduced. It assumes that one extra parameter, the effective temperature, is needed to describe the glassy state. This explains the classical paradoxes concerning the Ehrenfest relations and the Prigogine-Defay ratio. As a second part, the approach connects the response of macroscopic observables to a field change with their temporal fluctuations, and with the fluctuation-dissipation relation, in a generalized non-equilibrium way.Comment: Proceedings of the Conference "Unifying Concepts in Glass Physics", ICTP, Trieste, 15 - 18 September 199

Do the Herschel cold clouds in the Galactic halo embody its dark matter?

Recent Herschel/SPIRE maps of the Small and Large Magellanic Clouds (SMC, LMC) exhibit in each thousands of clouds. Observed at 250 microns, they must be cold, T ~ 15 K, hence the name "Herschel cold clouds" (HCCs). From the observed rotational velocity profile and the assumption of spherical symmetry, the Galactic mass density is modeled in a form close to that of an isothermal sphere. If the HCCs constitute a certain fraction of it, their angular size distribution has a specified shape. A fit to the data deduced from the SMC/LMC maps supports this and yields for their radius 2.5 pc, with a small change when allowing for a spread in HCC radii. There are so many HCCs that they will make up all the missing Halo mass density if there is spherical symmetry and their average mass is of order 15,000 Mo. This compares well with the Jeans mass of circa 40,000 Mo and puts forward that the HCCs are in fact Jeans clusters, constituting all the Galactic dark matter and much of its missing baryons, a conclusion deduced before from a different field of the sky (Nieuwenhuizen, Schild and Gibson 2011). A preliminary analysis of the intensities yields that the Jeans clusters themselves may consist of some billion MACHOs of a few dozen Earth masses. With a size of dozens of solar radii, they would mostly obscure stars in the LMC, SMC and towards the Galactic center, and may thus have been overlooked in microlensing.Comment: Revised and corrected version, matches published version. Conclusions unchange

Changes in Pilot Control Behaviour across Stewart Platform Motion Systems

Low-cost motion systems have been proposed for certain training tasks that would otherwise be performed on high-performance full flight simulators. These systems have shorter stroke actuators, lower bandwidth, and higher noise. The influence of these characteristics on pilot perception and control behaviour is unknown, and can be investigated by simulating a model of a simulator with limited capabilities on a high-end simulator. The platform limitations, such as a platform filter, time delay, and simulator noise characteristics, can then be removed one by one and their effect on control behaviour studied in isolation. By applying a cybernetic approach, human behaviour can be measured objectively in target-following disturbance-rejection control tasks. Experimental results show that small changes in time delay and simulator noise characteristics do not negatively affect human behaviour in these tasks. However, the motion system bandwidth has a significant effect on performance and control behaviour. Participants barely use motion cues when these have a low bandwidth, and instead rely on visual cues to generate lead to perform the control task. Therefore, simulator motion cues must be considered carefully in piloted control tasks in simulators and measured results depend on simulator characteristics as pilots adapt their control behaviour to the available cues

Does the Third Law of Thermodynamics hold in the Quantum Regime?

The first in a long series of papers by John T. Lewis, G. W. Ford and the present author, considered the problem of the most general coupling of a quantum particle to a linear passive heat bath, in the course of which they derived an exact formula for the free energy of an oscillator coupled to a heat bath in thermal equilibrium at temperature T. This formula, and its later extension to three dimensions to incorporate a magnetic field, has proved to be invaluable in analyzing problems in quantum thermodynamics. Here, we address the question raised in our title viz. Nernst's third law of thermodynamics

Competition between glassiness and order in a multi-spin glass

A mean-field multi-spin interaction spin glass model is analyzed in the presence of a ferromagnetic coupling. The static and dynamical phase diagrams contain four phases (paramagnet, spin glass, ordinary ferromagnet and glassy ferromagnet) and exhibit reentrant behavior. The glassy ferromagnet phase has anomalous dynamical properties. The results are consistent with a nonequilibrium thermodynamics that has been proposed for glasses.Comment: revised version, 4 pages Revtex, 2 eps-figures. Phys. Rev. E, Rapid Communication, to appea

Exactly solvable model of a quantum spin glass

A mean field spherical model with random couplings between pairs, quartets, and possibly higher multiplets of spins is considered. It has the same critical behavior as the Sherrington-Kirkpatrick model. It thus exhibits replica symmetry breaking. The order parameter function is solved exactly in the whole low temperature phase. The zero field cooled susceptibility remains finite at low $T$. Next a quantum version of the system is considered. Whereas the magnetic properties are not altered qualitatively, the thermodynamics is now regular at small temperatures.Comment: 4 pages postscript. Revised version, to appear in Phys. Rev. Let

"Optical conductance fluctuations: diagrammatic analysis in Landauer approach and non-universal effects"

The optical conductance of a multiple scattering medium is the total transmitted light of a diffuse incoming beam. This quantity, very analogous to the electronic conductance, exhibits universal conductance fluctuations. We perform a detailed diagrammatic analysis of these fluctuations. With a Kadanoff-Baym technique all the leading diagrams are systematically generated. A cancellation of the short distance divergencies occurs, that yields a well behaved theory. The analytical form of the fluctuations is calculated and applied to optical systems. Absorption and internal reflections reduce the fluctuations significantly.Comment: 25 pages Revtex 3.0, 18 seperate postscript figure