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Interaction of Void Spacing and Material Size Effect on Inter-Void Flow Localization
The ductile fracture process in porous metals due to growth and coalescence of micron scale voids is not only affected by the imposed stress state but also by the distribution of the voids and the material size effect. The objective of this work is to understand the interaction of the inter-void spacing (or ligaments) and the resultant gradient induced material size effect on void coalescence for a range of imposed stress states. To this end, three dimensional finite element calculations of unit cell models with a discrete void embedded in a strain gradient enhanced material matrix are performed. The calculations are carried out for a range of initial inter-void ligament sizes and imposed stress states characterised by fixed values of the stress triaxiality and the Lode parameter. Our results show that in the absence of strain gradient effects on the material response, decreasing the inter-void ligament size results in an increase in the propensity for void coalescence. However, in a strain gradient enhanced material matrix, the strain gradients harden the material in the inter-void ligament and decrease the effect of inter-void ligament size on the propensity for void coalescence
Interaction of Void Spacing and Material Size Effect on Inter-Void Flow Localization
The ductile fracture process in porous metals due to growth and coalescence
of micron scale voids is not only affected by the imposed stress state but also
by the distribution of the voids and the material size effect. The objective of
this work is to understand the interaction of the inter-void spacing (or
ligaments) and the resultant gradient induced material size effect on void
coalescence for a range of imposed stress states. To this end, three
dimensional finite element calculations of unit cell models with a discrete
void embedded in a strain gradient enhanced material matrix are performed. The
calculations are carried out for a range of initial inter-void ligament sizes
and imposed stress states characterised by fixed values of the stress
triaxiality and the Lode parameter. Our results show that in the absence of
strain gradient effects on the material response, decreasing the inter-void
ligament size results in an increase in the propensity for void coalescence.
However, in a strain gradient enhanced material matrix, the strain gradients
harden the material in the inter-void ligament and decrease the effect of
inter-void ligament size on the propensity for void coalescence
A micro-mechanics based extension of the GTN continuum model accounting for random void distributions
Randomness in the void distribution within a ductile metal complicates quantitative modeling of damage following the void growth to coalescence failure process. Though the sequence of micro-mechanisms leading to ductile failure is known from unit cell models, often based on assumptions of a regular distribution of voids, the effect of randomness remains a challenge. In the present work, mesoscale unit cell models, each containing an ensemble of four voids of equal size that are randomly distributed, are used to find statistical effects on the yield surface of the homogenized material. A yield locus is found based on a mean yield surface and a standard deviation of yield points obtained from 15 realizations of the four-void unit cells. It is found that the classical GTN model very closely agrees with the mean of the yield points extracted from the unit cell calculations with random void distributions, while the standard deviation varies with the imposed stress state. It is shown that the standard deviation is nearly zero for stress triaxialities , while it rapidly increases %in the interval for triaxialities above , reaching maximum values of about at . At even higher triaxialities it decreases slightly. The results indicate that the dependence of the standard deviation on the stress state follows from variations in the deformation mechanism since a well-correlated variation is found for the volume fraction of the unit cell that deforms plastically at yield. Thus, the random void distribution activates different complex localization mechanisms at high stress triaxialities that differ from the ligament thinning mechanism forming the basis for the classical GTN model. A method for introducing the effect of randomness into the GTN continuum model is presented, and an excellent comparison to the unit cell yield locus is achieved
Realisation of a programmable two-qubit quantum processor
The universal quantum computer is a device capable of simulating any physical
system and represents a major goal for the field of quantum information
science. Algorithms performed on such a device are predicted to offer
significant gains for some important computational tasks. In the context of
quantum information, "universal" refers to the ability to perform arbitrary
unitary transformations in the system's computational space. The combination of
arbitrary single-quantum-bit (qubit) gates with an entangling two-qubit gate is
a gate set capable of achieving universal control of any number of qubits,
provided that these gates can be performed repeatedly and between arbitrary
pairs of qubits. Although gate sets have been demonstrated in several
technologies, they have as yet been tailored toward specific tasks, forming a
small subset of all unitary operators. Here we demonstrate a programmable
quantum processor that realises arbitrary unitary transformations on two
qubits, which are stored in trapped atomic ions. Using quantum state and
process tomography, we characterise the fidelity of our implementation for 160
randomly chosen operations. This universal control is equivalent to simulating
any pairwise interaction between spin-1/2 systems. A programmable multi-qubit
register could form a core component of a large-scale quantum processor, and
the methods used here are suitable for such a device.Comment: 7 pages, 4 figure
A Factorization Law for Entanglement Decay
We present a simple and general factorization law for quantum systems shared
by two parties, which describes the time evolution of entanglement upon passage
of either component through an arbitrary noisy channel. The robustness of
entanglement-based quantum information processing protocols is thus easily and
fully characterized by a single quantity.Comment: 4 pages, 5 figure
Impact of calcium on salivary α-amylase activity, starch paste apparent viscosity and thickness perception
Thickness perception of starch-thickened products
during eating has been linked to starch viscosity and
salivary amylase activity. Calcium is an essential cofactor
for α-amylase and there is anecdotal evidence that adding
extra calcium affects amylase activity in processes like
mashing of beer. The aims of this paper were to (1) investigate the role of salivary calcium on α-amylase
activity and (2) to measure the effect of calcium concentration on apparent viscosity and thickness perception when interacting with salivary α-amylase in starch-based samples.
α-Amylase activity in saliva samples from 28 people
was assessed using a typical starch pasting cycle (up to 95 °C). The activity of the enzyme (as measured by the change in starch apparent viscosity) was maintained by the presence of calcium, probably by protecting the enzyme from heat denaturation. Enhancement of α-amylase activity by calcium at 37 °C was also observed although to a smaller extent. Sensory analysis showed a general trend of decreased
thickness perception in the presence of calcium, but the result was only significant for one pair of samples, suggesting a limited impact of calcium enhanced enzyme activity on perceived thickness
Local Detection of Quantum Correlations with a Single Trapped Ion
As one of the most striking features of quantum mechanics, quantum
correlations are at the heart of quantum information science. Detection of
correlations usually requires access to all the correlated subsystems. However,
in many realistic scenarios this is not feasible since only some of the
subsystems can be controlled and measured. Such cases can be treated as open
quantum systems interacting with an inaccessible environment. Initial
system-environment correlations play a fundamental role for the dynamics of
open quantum systems. Following a recent proposal, we exploit the impact of the
correlations on the open-system dynamics to detect system-environment quantum
correlations without accessing the environment. We use two degrees of freedom
of a trapped ion to model an open system and its environment. The present
method does not require any assumptions about the environment, the interaction
or the initial state and therefore provides a versatile tool for the study of
quantum systems.Comment: 6 Pages, 5 Figures + 6 Pages, 1 Figure of Supplementary Materia
Spin qubits with electrically gated polyoxometalate molecules
Spin qubits offer one of the most promising routes to the implementation of
quantum computers. Very recent results in semiconductor quantum dots show that
electrically-controlled gating schemes are particularly well-suited for the
realization of a universal set of quantum logical gates. Scalability to a
larger number of qubits, however, remains an issue for such semiconductor
quantum dots. In contrast, a chemical bottom-up approach allows one to produce
identical units in which localized spins represent the qubits. Molecular
magnetism has produced a wide range of systems with tailored properties, but
molecules permitting electrical gating have been lacking. Here we propose to
use the polyoxometalate [PMo12O40(VO)2]q-, where two localized spins-1/2 can be
coupled through the electrons of the central core. Via electrical manipulation
of the molecular redox potential, the charge of the core can be changed. With
this setup, two-qubit gates and qubit readout can be implemented.Comment: 9 pages, 6 figures, to appear in Nature Nanotechnolog
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