Paleoceanography of the eastern equatorial Pacific during the Neogene: Synthesis of Leg 138 drilling results

The primary objective of Leg 138 was to provide detailed information about the ocean\u27s response to global climate change during the Neogene. Two north-south transects were drilled (95° and 110°W) within the region of equatorial divergence-driven upwelling (and thus high accumulation rates and resolution) and spanning the major equatorial ocean current boundaries (and thus recording a high-amplitude signal of the response of the sediment to climatically and/or tectonically driven changes in ocean circulation). The Neogene is marked by a number of well-known climatic and tectonic events (the closing of the Isthmus of Panama, the onset of North Atlantic Deep Water (NADW), the rapid uplift of the Himalayas, the major intensification of Northern Hemisphere glaciation), and the response of the ocean before and after these events was a key focus of Leg 138 drilling. To address these objectives at the highest resolution possible, the Leg 138 scientific staff developed a number of new shipboard strategies and analytical procedures. These included the real-time analysis of the near-continuous gamma ray attenuation porosity evaluator (GRAPE) and susceptibility profiles produced by the multisensor track (MST) on unsplit cores to monitor core recovery and, if necessary, to modify the drilling strategy to ensure proper offset of coring gaps; the collection of near-continuous color reflectance data on split cores; the logging of the first hole drilled at each site to optimize drilling and sampling strategies for subsequent holes; and the use of multiple continuous records to unambiguously construct complete composite sections for each site. The complete, continuous records provided by the GRAPE (with a temporal resolution of often yr), in conjunction with an excellent microfossil stratigraphy and often excellent magnetostratigraphy, allowed for astronomical tuning of the stratigraphic record and resulted in a set of internally consistent, high-resolution age models that provide a secure, absolute time scale for the past 6 m.y. For the period before 6 m.y., the absolute time calibration is less secure, but it is still better than any previously offered. The high-resolution stratigraphic framework of Leg 138 provided new insight into the previously ambiguous tectonic history of the region. By assuming that maximum sedimentation rates along the north-south transect would be expected at the equator, the Leg 138 stratigraphy supports the 1985 work of Cox and Engerbretson, which calls for two different poles of rotation of the Pacific Plate during the interval 0-20 Ma. The Leg 138 plate reconstructions also support several previously hypothesized ridge crest jumps and a slowing of the absolute motion of the Nazca Plate at about 5 Ma. Although Leg 138 data that predates about 13 Ma is limited, the impression that one can gain from these data is that the eastern equatorial Pacific was characterized by relatively high carbonate concentrations and accumulation rates before about 11 Ma. This pattern was interrupted occasionally by rapid massive outpourings of near-monospecific laminated diatom oozes that probably represent the formation of massive mats along strong surface-water fronts. The laminated diatom oozes (LDO) continue to be present in the Leg 138 record (many of them being expressed as seismic reflections) until about 4.4 Ma. Carbonate accumulation rates begin to decline slowly between 11 and 9.8 Ma, when, at about 9.5 Ma, a near-complete loss of carbonate (the carbonate crash ) takes place everywhere in the Leg 138 region (and beyond), except at the westernmost sites close to the equator. The carbonate crash was a time of fundamental change for the eastern equatorial Pacific, and perhaps for most of the ocean basins. Unlike many of the carbonate variations that precede and postdate it, this crash represents a major dissolution event whose effects can be traced seismically in the central and western Pacific. The changes in bottom-water chemistry associated with this event (or series of events) appear to be related to the early phases of the closing of the Panama Gateway. The role of NADW initiation and intensification for controlling carbonate accumulation in the eastern equatorial Pacific is still not resolved; however, ocean modeling demonstrates that the closing of the Panama Gateway may also have a direct influence on NADW production. Therefore, the effects of changes in the Panama Gateway sill depth and the production of NADW may be manifested in the history of eastern equatorial Pacific sedimentation. The carbonate crash was followed by a recovery of the carbonate system (except in the Guatemala and Peru basins, which never recovered) that led up to the late Miocene/early Pliocene sedimentation rate maxima, during which equatorial sedimentation rates are as much as five times greater than those of the late Pliocene or Pleistocene. Examination of modern productivity/preser vation relationships implies that the sedimentation rate maximum was the result of enhanced productivity. The distribution of eolian sediments and isotopic gradients, along with an analysis of the modes of variance in carbonate deposition over the last 6 m.y., suggest a more northerly position of the Intertropical Convergence Zone (ITCZ), a stronger north-south gradient across the equator, and a more zonal circulation focused along the equator during the time of maximum sedimentation. The mechanisms suggested for these changes in circulation patterns include the response of the eastern equatorial Pacific to the closing of the Isthmus of Panama, as well as a global increase in the flux of Ca and Si into the oceans, a possible response to evolution of the Himalayas and the Tibetan Plateau. In an effort to understand the response of the climate system to external (orbital) forcing, 6-m.y.-long, continuous records of carbonate (derived from GRAPE), δ 1 8 and insolation were analyzed and compared. Evolutionary spectral calculations of the variance and coherence among these records indicate that the insolation record is dominated by precessional frequencies, but that the relative importance of the two precessional frequencies has changed significantly over the last 6 m.y. In general, precessional forcing is not found in the carbonate or isotopic records. In the tilt band, however, a linear response is present between solar forcing and the carbonate and isotope records over some intervals. The carbonate record appears to be tightly coupled to the tilt component of insolation before about 1.9 Ma; however, the isotope record does not begin to show sensitivity to orbital tilt until about 4.5 Ma, the time of significant changes in sedimentation patterns in the eastern equatorial Pacific. Only during the last 500,000 yr do all frequencies respond in a similar manner; we also see a marked increase in the response of the isotopic record to orbital forcing (including 100,000- and 400,000-yr periods)

Mythology, Knowledge, and Power: An Examination of Social Forces in Brazil and the Emergence of Umbanda

Article

Manipulation of fermentation dynamics of corn silage with selected additives and their effects on silage quality, digestibility and animal performance

Study 1. A laboratory-scale experiment with 75-kg steel drums was conducted using sorbic acid (SA), an amylase-sterilant (AS) or both (SA+AS) as silage additives for whole-plant corn, to determine type of fermentation and change in nutrient composition over time due to treatments. Addition of SA, AS or SA+AS increased concentrations of water-soluble carbohydrates (WSC) by 60.3, 17.4 or 50.1%, respectively. Treatment with SA inhibited formation of butyric acid, and lowered ammonia-N and ethanol concentrations in silage by 6.4 and 34.2% respectively (P\u3c .02). Use of AS reduced butyric acid concentration, but increased ammonia-N and ethanol content in silage by 6.8 and 33.1%, respectively (P\u3c .10). Study 2. Using the aforementioned silages, a digestion and nitrogen balance trial and a rumen fermentation experiment measuring in-vitro gas production and microbial protein synthesis were conducted. In-vitro gas production was increased twofold in sheep fed SA- or AS-treated silages (P\u3c .10). Microbial protein synthesis with SA, AS or SA+AS treatment was increased by 125, 133 (P\u3c .10) and 61%, respectively. Digestibility and nitrogen utilization were not affected by treatments. Study 3. A fermentation time study with 8-kg plastic buckets using α-amylase, α- and β-amylases or α-, β-amylases and sulfur-salts (AS) as silage additives, and a growth trial with beef heifers were conducted to identify the cause for increased animal performance with AS-treated silages. After 28 days of ensiling, all amylase-treated silages retained 41 to 60% higher concentrations of WSC (P\u3c .10), and produced more lactic acid (P\u3c .10) than untreated silage. Presence of fungi was reduced in two of the amylase-treated silages (1.10 to 1.17 log; P\u3c .10). Dry matter recovery of amylase-treated corn silages was markedly increased (6.3 to 10.7%, P\u3c .10). Beef heifers fed amylase-treated corn silages had 5.3 to 12.1% increased ADG. Results suggest that addition of SA and AS shows potential for improving silage quality, nutrient preservation and ultimately, animal productivity

Avoided ferromagnetic quantum critical point in CeRuPO

CeRuPO is a rare example of a ferromagnetic (FM) Kondo-lattice system. External pressure suppresses the ordering temperature to zero at about $p_c\approx3$ GPa. Our ac-susceptibility and electrical-resistivity investigations evidence that the type of magnetic ordering changes from FM to antiferromagnetic (AFM) at about $p^*\approx0.87$ GPa. Studies in applied magnetic fields suggest that ferromagnetic and antiferromagnetic correlations compete for the ground state at $p>p^*$, but finally the AFM correlations win. The change in the magnetic ground-state properties is closely related to the pressure evolution of the crystalline-electric-field level (CEF) scheme and the magnetic Ruderman-Kittel-Kasuya-Yosida (RKKY) exchange interaction. The N\'{e}el temperature disappears abruptly in a first-order-like fashion at $p_c$, hinting at the absence of a quantum critical point. This is consistent with the low-temperature transport properties exhibiting Landau-Fermi-liquid (LFL) behavior in the whole investigated pressure range up to 7.5 GPa.Comment: 12 figure

Competition of local-moment ferromagnetism and superconductivity in Co-substituted EuFe2As2

In contrast to SrFe2As2, where only the iron possesses a magnetic moment, in EuFe2As2 an additional large, local magnetic moment is carried by Eu2+. Like SrFe2As2, EuFe2As2 exhibits a spin-density wave transition at high temperatures, but in addition the magnetic moments of the Eu2+ order at around 20 K. The interplay of pressure-induced superconductivity and the Eu2+ order leads to a behavior which is reminiscent of re-entrant superconductivity as it was observed, for example, in the ternary Chevrel phases or in the rare-earth nickel borocarbides. Here, we study the delicate interplay of the ordering of the Eu2+ moments and superconductivity in EuFe1.9Co0.1As2, where application of external pressure makes it possible to sensitively tune the ratio of the magnetic (T_C) and the superconducting (T_{c,onset}) critical temperatures. We find that superconductivity disappears once T_C > T_{c,onset}.Comment: 4 pages, 4 figures, submitted to the proceedings of SCES201

1995, Spatial and temporal variability of late Neogene equatorial Pacific carbonate

High-resolution, continuous records of GRAPE wet bulk density (a carbonate proxy) from Ocean Drilling Program Leg 138 provide one the opportunity for a detailed study of eastern equatorial Pacific Ocean carbonate sedimentation during the last 6 m.y. The transect of sites drilled spans both latitude and longitude in the eastern equatorial Pacific from 90° to 110°W and from 5°S to 10°N. Two modes of variability are resolved through the use of Empirical Orthogonal Function (EOF) analysis. In the presence of large tectonic and climatic boundary condition changes over the last 6 m.y., the dominant mode of spatial variability in carbonate sedimentation is remarkably constant. The first mode accounts for over 50% of the variance in the data, and is consistent with forcing by equatorial divergence. This mode characterizes both carbonate concentration and carbonate mass accumulation rate time series. Variability in the first mode is highly coherent with insolation, indicating a strong linear relationship between equatorial Pacific car bonate sedimentation and Milankovitch variability. Frequency domain analysis indicates that the coupling to equatorial divergence in carbonate sedimentation is strongest in the precession band (19-23 k.y.) and weakest though present at lower frequencies. The second mode of variability has a consistent spatial pattern of east-west asymmetry over the past 4 m.y. only; prior to 4 Ma, a different mode of spatial variability may have been present, possibly suggesting influence by closure of the Isthmus of Panama or other tectonic changes. The second mode of variability may indicate influence by CaCO3 dissolution. The second mode of variability is not highly coherent with insolation. Comparison of the modes of carbonate variability to a 4 m.y. record of benthic δ 1 8 indicates that although overall correlation between carbonate and δ 1 8 is low, both modes of variability in carbonate sedimentation are coherent with δ 1 8 changes at some frequencies. The first mode of carbonate variability is coherent with Sites 846/849 δ 1 8 at the dominant insolation periods, and the second mode is coherent at 100 k.y. during the last 2 m.y. The coherence between carbonate sedimentation and δ 1 8 in both EOF modes suggests that multiple uncorrelated modes of variability operated within the climate system during the late Neogene

Pauli-Limited Superconductivity with Classical Magnetic Fluctuations

We examine the effect of classical magnetic fluctuations on the phase diagram of paramagneticallylimited two-dimensional superconductors under a Zeeman magnetic field. We derive the free energy expansion in powers of the superconducting order parameter and analyze the character of the normalsuperconducting transition. While the transition is of the second order for all temperatures in the absence of magnetic fluctuations, we find that proximity to magnetism drives both the transition into the uniform state and that into the modulated (Fulde-Ferrell-Larkin-Ovchinnikov, FFLO) state to first order at intermediate temperatures. We compute the thermodynamic signatures of the normal-superconducting transition along the upper critical field.Comment: 16 pages, 9 figure